• Title/Summary/Keyword: WO3

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Sinterability and Microwave Dielectric Properties of xZnWO4-(1-x)TiO2 Ceramics Sintered at Low Temperature (저온 소결용 xZnWO4-(1-x)TiO2 세라믹스의 소결 및 마이크로파 유전 특성)

  • Yoon, Sang-Ok;Kim, Kwan-Soo;Shim, Sang-Heung;Park, Jong-Guk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.9
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    • pp.855-861
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    • 2006
  • Sinterability and microwave dielectric properties of $xZWO_{4}-(1-x)TiO_{2}$ ceramic systems with zinc-borosilicate glass and $TiO_{2}$ contents for LTCC(Low Temperature Co-fired Ceramics) were investigated. The addition of $3{\sim}10\;wt%$ ZBS glass ensured the sinterability below $900^{\circ}C$. In general, increasing ZBS glass content seemed to enhance the sinterability, but the quality factor($Qxf_{0}$) significantly decreased due to the formation of an excessive liquid and second phases. As for the addition of $TiO_{2}$, the dielectric constant(${\varepsilon}_{r}$) and temperature coefficient of resonant frequency(${\tau}_{f}$) showed to increase, while the quality factor($Qxf_{0}$) did not show an apparent change. The composition of $0.7xZnWO_{4}-0.3TiO_{2}$ ceramics sintered at $900^{\circ}C$ with 5 wt% ZBS glass demonstrated 21.6 in dielectric constant(${\varepsilon}_{r}$), 14,800 in quality factor($Qxf_{0}$), and $+5\;ppm/^{\circ}C$ in temperature coefficient of resonant frequency(${\tau}_{f}$).

A Study on the Quality Evaluation of Scholarly Web Databases Focused on NDSL, PubMed, Scopus, and Web of Science (학술 웹 데이터베이스의 품질 비교 평가 : NDSL, P ubMed, Scopus와 Web of Science를 중심으로)

  • Kim, Sang-Jun
    • Journal of Information Management
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    • v.36 no.3
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    • pp.127-165
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    • 2005
  • This study is focused on the quality of the Web databases which has been produced in science. For the quality evaluation of NDSL, PubMed, Scopus, and WoS, 10 evaluating criteria are developed on the basis of literature review. The evaluation results show that NDSL and PubMed are superior in the currentness and cost. Scopus and WoS are superior in the information of citing and the analysis tool. It is needed for purchasing, user training, and library service based on the above evaluation results.

Exploring Information Ethics Issues based on Text Mining using Big Data from Web of Science (Web of Science 빅데이터를 활용한 텍스트 마이닝 기반의 정보윤리 이슈 탐색)

  • Kim, Han Sung
    • The Journal of Korean Association of Computer Education
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    • v.22 no.3
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    • pp.67-78
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    • 2019
  • The purpose of this study is to explore information ethics issues based on academic big data from Web of Science (WoS) and to provide implications for information ethics education in informatics subject. To this end, 318 published papers from WoS related to information ethics were text mined. Specifically, this paper analyzed the frequency of key-words(TF, DF, TF-IDF), information ethics issues using topic modeling, and frequency of appearances by year for each issue. This paper used 'tm', 'topicmodel' package of R for text mining. The main results are as follows. First, this paper confirmed that the words 'digital', 'student', 'software', and 'privacy' were the main key-words through TF-IDF. Second, the topic modeling analysis showed 8 issues such as 'Professional value', 'Cyber-bullying', 'AI and Social Impact' et al., and the proportion of 'Professional value' and 'Cyber-bullying' was relatively high. This study discussed the implications for information ethics education in Korea based on the results of this analysis.

Preparation of WC Powders by SHS Process in the Presence of Alkali Salts (자전연소합성법에서의 알칼리염을 이용한 WC 분말의 제조)

  • Won, Hyung-Il;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.152-156
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    • 2007
  • Tungsten carbide powder was synthesized by SHS (self-propagating high-temperature synthesis). Except $WO_{3}$, each concentration of raw material ($WO_{3},\;Mg,\;NaCl,\;Na_{2}CO_{3},\;C$) was investigated. Final product was characterized by XRD and SEM. X-ray data demonstrated that the $NaCl+Na_{2}CO_{3}$ combined mixture has superiority in the WC formation process. Single phase and submicrometer WC powder was synthesized at the temperature below $1600^{\circ}C$. The role of sodium salts in combustion process was discussed, and chemical mechanism of WC formation was proposed. WC powder prepared by salt-assisted combustion synthesis has a size $0.2{\sim}3\;{\mu}m$ and low agglomeration degree.

Luminescence of $Eu^{3+}$ and $Sm^{3+}$ Doped Potassium Tungstate Phosphors

  • Lee, Gwan-Hyoung;Kang, Shin-Hoo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1510-1513
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    • 2005
  • The luminescent properties of $Eu^{3+}$ and $Sm^{3+}$ doped potassium tungstate phosphor were investigated. The $K_{4-3x}(WO_4)_2:Eu_x$, $Sm_y$ phosphor was produced by firing the mixed precursors, followed by re-firing with a flux. The re-firing process provided the clean surface to the particles. The excitation spectra showed that the strong absorption in the region of ultra violet light occurred due to the high europium doping concentration. The incorporation of europium to potassium tungstate was easier, compared to other host materials. The excitation spectra could be controlled by the small addition of samarium. The increase of energy absorption around 405nm was assigned to the $Sm^{3+}$ ions. The comparison between real x-ray diffraction and simulated one revealed that the crystal structure of $K_{4-3x}(WO_4)_2:Eu_x,Sm_y$ phosphor is monoclinic with a space group, C2/c.

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Fabrication of Microcrystalline NaPbLa(WO4)3:Yb3+/Ho3+ Phosphors and Their Upconversion Photoluminescent Characteristics

  • Lim, Chang Sung;Atuchin, Victor V.;Aleksandrovsky, Aleksandr S.;Denisenko, Yuriy G.;Molokeev, Maxim S.;Oreshonkov, Aleksandr S.
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.741-746
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    • 2019
  • New triple tungstate phosphors NaPbLa(WO4)3:Yb3+/Ho3+ (x = Yb3+/Ho3+ = 7, 8, 9, 10) are successfully fabricated by microwave assisted sol-gel synthesis and their structural and frequency upconversion (UC) characteristics are investigated. The compounds crystallized in the tetragonal space group I41/a and the NaPbLa(WO4)3 host have unit cell parameters a = 5.3927(1) and c = 11.7961(3) Å, V = 343.05(2) Å3, Z = 4. Under excitation at 980 nm, the phosphors have yellowish green emissions, which are derived from the intense 5S2/5F45I8 transitions of Ho3+ ions in the green spectral range and strong 5F55I8 transitions in the red spectral range. The optimal Yb3+:Ho3+ ratio is revealed to be x = 9, which is attributed to the quenching effect of Ho3+ ions, as indicated by the composition dependence. The UC characteristics are evaluated in detail under consideration of the pump power dependence and Commission Internationale de L'Eclairage chromaticity. The spectroscopic features of Raman spectra are discussed in terms of the superposition of Ho3+ luminescence and vibrational lines. The possibility of controlling the spectral distribution of UC luminescence by the chemical content of tungstate hosts is demonstrated.

Microstructure and Dielectric Properties in $30Pb(Mg_{1/3}Nb_{2/3})O_3-20PbTiO_3-50Pb(Mg_{1/2}W_{1/2})O_3$ Ceramics with Excess MgO Addition (MgO가 과잉첨가된 $30Pb(Mg_{1/3}Nb_{2/3})O_3-20PbTiO_3-50Pb(Mg_{1/2}W_{1/2})O_3$계 세라믹스의 미세구조와 유전특성)

  • 길영배;이응상
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.31-36
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    • 1997
  • The effects of 0 to 10mol% excess MgO addition on the microstructure and dielectric properties in 30Pb(Mg1/3Nb2/3)O3-20PbTiO3-50Pb(Mg1/2W1/2)O3 ternary system were investigated. Samples were prepared by mixed oxide and precursor methods to compare the role of excess MgO. Excess MgO enhanced grain growth and increased dielectric constant. The dielectric constant and tesmperature dependence of dielectric constant of the sample sintered at 100$0^{\circ}C$ with 5mol% MgO were above 5,000 and +25% to -50% from - 55$^{\circ}C$ to 1$25^{\circ}C$, respectively. For these specimens the phases percent were mainly perovskite and Pb2WO5, which was confirmed by XRD analysis. Also the amount of cubic pyrochlore Pb3Nb4O13 and PbWO4 were de-creased with sintering temperature and MgO addition. BSE image showed the chemical inhomogeneous dis-tribution. Crystal phase formed at each sintering temperature and the chemical inhomogeneous distribution caused the decrease of the temperature dependence of dielectric constant.

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