• TTA Journal
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• s.33
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• pp.129-136
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• 1994

• The Monthly Technology and Standards
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• s.75
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• pp.45-48
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• 2008

• The Monthly Technology and Standards
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• s.65
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• pp.74-78
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• 2007

• TTA Journal
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• s.102
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• pp.108-116
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• 2005

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.757-760
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• 2009

최근 들어 WGS 반응은 Pt과 같은 귀금속 촉매를 다양한 담체에 담지하여 낮은 온도에서 높은 활성을 지닌 촉매를 제조하기 위한 연구가 활발히 진행되고 있다. WGS 반응에서 귀금속 촉매가 높은 활성을 가지기 위해서 높은 산소저장능력(Oxygen Storage Capacity)과 산화환원능력(Redox)을 지닌 담체 개발이 필요하다. Ce-$ZrO_2$ 담체는 구조적으로 안정하며 높은 산소저장능을 가지고 있는 것으로 알려져 있다. Ce-$ZrO_2$ 구조는 Ce/Zr 비에 따라 다양한 변화가 생긴다. Ce/Zr 비가 6/4, 8/2인 경우 입방구조(Cubic)를 가지며 2/8인 경우 정방입계(Tetragonal)구조를 가진다. 이것은 담체 특성의 변화를 의미한다. 따라서, WGS 반응용 최적 담체를 선정하기 위해 Ce/Zr 비를 제조변수로 하여 담체특성을 분석하였다. 제조된 모든 담체는 공침법(Co-precipitation)을 사용하여 제조하였으며 $500^{\circ}C$에서 6시간 소성하였다. 담체 특성분석은 BET, XRD를 이용하였다. 추가적으로 제조변수를 다양화하여 담체 제조를 마쳤으며 특성분석이 진행 중이다. 분석 결과 $Ce_{0.2}Zr_{0.8}O_2$ 담체가 가장 넓은 표면적을 가지고 있으며 Ce/Zr 비가 높아질수록 표면적이 감소하는 경향을 나타내었다. Ce-$ZrO_2$ 담체의 나노결정크기는 Ce/Zr 비가 작아질수록 결정크기가 감소하는 경향을 나타내었으며 $Ce_{0.2}Zr_{0.8}O_2$가 Ce-$ZrO_2$ 담체 중에서 가장 작은 결정크기를 나타내어 3nm 이하의 나노-담체가 제조되었음을 확인하였다.

• Journal of Astronomy and Space Sciences
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• v.12 no.1
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• pp.90-101
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• 1995

We determined three dimensional precise WGS 84 corrdinates of two points in Bohyunsan Optical Astronomy Observatory using the GPS. One of the two points is the center on the top of pier for 1.8m telescope, and the other one is placed on the hill beside the dome of 1.8m telescope. We performed the simultaneous GPS observation at the KAO GPS station and Bohyunsan Obervatory for 5 days from December 18 to 22, 1993. We employed three Trimble 4000SST receivers for these observations. The observed data were processed by TRIMVEC-PLUS software of Trimble with the MBPS method and the Triple Difference L1/L2 ION free technique. Through this research, we determined WGS 83 latitude, longitude and height of 1.8m telescope in Bohyunsan Optical Astronomy Observatory with the values of $36^{circ}9'53".1943N\pm0."0018,\;128^{circ}58'35".6829E\pm0."0029,\;1162.47m\pm0.04m$, respectively.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.19 no.4
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• pp.415-423
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• 2001

This paper deals with the data processing method relative to reference frames through the calculation of absolute coordinates of permanent GPS site which was established at Sungkyunkwan University. In this paper. we computed the ITRF97 coordinates with high precision (0.0001 ppm) from GPS data analysis. Also, we derived the accurate coordinates referred to WGS84 and Korean Geodetic Datum (KGD) using transformation parameters provided. ITRF97 coordinates were computed by using the GIPSY-OASIS II (GOA II) software and the algorithms for determining the position developed Jet Propulsion Laboratory (JPL). The coordinates referred to WGS84 and KGD were derived from the transformation parameters provided by International Earth Rotation Service (IERS) and National Geography Institute (NGI). The parameters determined by NGI were calculated from the 2000 project of the establishment of geocentric coordinate system. We tested its availability through the comparison of the coordinates obtained from local GPS data analysis.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.16 no.2
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• pp.149-158
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• 1998

The aim of this paper is to propose the technique of the two dimensional geodetic coordinates conversion between WGS84 and Bessel spheroids by the two-dimensional affine transformation modeling based on the UTM plane coordinates without the local geoid model which is essential to three dimensional coordinates conversion. Area of approximately $25\times{11}$ square km in the city of Inchon was selected as the test area. The transformation parameters were determined using the eleven triangulation control points in test area. And then, those paraneters were applied to the fifteen cadastral control points which selected as checking points for precision checking of transformation parameters. The average and standard deviations of the absolute values of the conversion residuals of checking points in latitude/longitude and N/E(UTM) and/or x/y(TM) are $\pm0.006"$$\pm0.013"$ and $\pm{17cm/}\pm{30cm}$ respectively. Also, coefficients for 7-parameters, 3-parameters and UTM model transformation computed according as sizes of transformed area, and then the transformed characteristics of checking points according to transformation methods analyzed synthetically.hetically.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.5
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• pp.528-532
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• 2007

The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. In general, most feasible strategies to generate hydrogen from hydrocarbon fuels consist of a reforming step to generate a mixture of $H_2$, CO, $CO_2$ and $H_2O$(steam) followed by water gas shift(WGS) and CO clean-up steps. The WGS reaction that shifts CO to $CO_2$ and simultaneously produces another mole of $H_2$ was carried out in a two-stage catalytic conversion process involving a high temperature shift(HTS) and a low temperature shift(LTS). In the WGS operation, gas emerges from the reformer is taken through a high temperature shift catalyst to reduce the CO concentration to about $3\sim4%$ followed to about 0.5% via a low temperature shift catalyst. The WGS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to less than 0.5%.

• Journal of Hydrogen and New Energy
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• v.30 no.2
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• pp.95-102
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• 2019

In order to investigate the effect of water treatment on activity of WGS catalyst, $Cu/ZnO/MgO/Al_2O_3$ (CZMA) catalysts were synthesized by co-precipitation method. The prepared catalysts were water-treated at two different temperature (250, $350^{\circ}C$). Synthesized catalysts were characterized by using BET, SEM, $N_2O$ chemisorption, XRD, $H_2-TPR$ and XPS analysis. The catalytic activity tests were carried out at a GHSV of $28,000h^{-1}$ and a temperature range of $180-320^{\circ}C$. The reduction temperature decreased with water treatment and CZMA_250 catalyst showed the lowest reduction temperature and retained a large amount of $Cu^+$. Water-treated catalysts showed increased reactivity compared to untreated catalyst and the CZMA_250 catalyst showed higher catalytic activity on WGS reaction.