• Title/Summary/Keyword: W-doping

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Effect of Doping on the Ionic Conductivity of Li$_2$Po$_{4-x}$N$_{x}$ thin Film (Li$_2$Po$_{4-x}$N$_{x}$ 박막의 이온전도도에 미치는 Ti 첨가)

  • 이재혁;이유기;박종완
    • Journal of Surface Science and Engineering
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    • v.30 no.4
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    • pp.255-261
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    • 1997
  • Thin film batteries can be used as a micro power source for electronic in which minute power is needed. In this study, lithium phosphorous oxynitride(LIPON) thin films were deposited as an eletrolyte for lithium ion batteries using RF magentron sputtering of lithium phosphate in N2. Ti was also added into the LIPON films as a second network former to enhance the ioinc conductivity of the films. The optimum conditions for LIPON film deposition were sought and the electrolyte with the conductivity of $2.5 \times 10^{-6}$S/cm was obtained at the condition of RF power 4.4 W/$\textrm{cm}^2$, process pressure 10 mtorr and pure nitrogen ambience. Furthermore, the conductivity of LIPON films was increased from $2.5 \times 10^{-6}$S/cm to $8.6 \times 10^{-6}$S/cm by the doping of 2.4at.% Ti. It was also found that by adding Ti to LIPON films, Li content was increased and nitrogen content that reported having the cross-linking effect on LIPON films was also increased as confirmed XPS.

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Photocatalytic Degradation of Quinol and Blue FFS Acid Using TiO2 and Doped TiO2

  • Padmini., E.;Prakash, Singh K.;Miranda, Lima Rose
    • Carbon letters
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    • v.11 no.4
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    • pp.332-335
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    • 2010
  • The photodegradation of the model compounds Quinol, an aromatic organic compound and Acid blue FFS, an acid dye of chemical class Triphenylmethane was studied by using illumination with UV lamp of light intensity 250W. $TiO_2$ and $TiO_2$ doped with Boron and Nitrogen was used as catalyst. The sol-gel method was followed with titanium isopropoxide as precursor and doping was done using Boron and Nitrogen. In photocatalytic degradation, $TiO_2$ and doped $TiO_2$ dosage, UV illumination time and initial concentration of the compounds were changed and examined in order to determine the optimal experimental conditions. Operational time was optimized for 360 min. The optimum dosage of $TiO_2$ and BN doped $TiO_2$ was obtained to be 2 $mgL^{-1}$ and 2.5 $mgL^{-1}$ respectively. Maximum degradation % for quinol and Blue FFS acid dye was 78 and 95 respectively, at the optimum dosage of BN-doped $TiO_2$ catalyst. It was 10 and 4% higher than when undoped $TiO_2$ catalyst was used.

Two Wavelength OLED with the Stacked GDI602(691)/GDI602(Rubrene) Fluorescent Layer (Stacked GDI602(691)/GDI602(Rubrene) 형광층을 갖는 2-파장 유기발광소자)

  • Jang, Ji-Geun;Chang, Ho-Jung;Oh, Myung-Hwan;Kang, Jung-Won;Lee, Jun-Young;Gong, Myoung-Seon;Lee, Young-Kwan;Kim, Hee-Won
    • Korean Journal of Materials Research
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    • v.17 no.4
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    • pp.198-202
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    • 2007
  • A new organic light emitting device(OLED) with two peak wavelength(blue and yellow) emission was fabricated using the selective doping in a single fluorescent host , and its electrical and optical characteristics were investigated. The fabricated device showed the luminance and efficiency of 1600 $Cd/m^2$ and 2.4 Im/W under the applied voltage of 10V, respectively. And its electroluminescent spectra had two peak wavelengths of 470nm and 560nm emitting bluish white light. The OLED with dual wavelength emission in this experiment is likely to be developed as a white OLED with simpler fluorescent system than conventional devices.

Hydrothermally synthesized Al-doped BiVO4 as a potential antibacterial agent against methicillin-resistant Staphylococcus aureus

  • Vicas, Charles Sundar;Keerthiraj, Namratha;Byrappa, Nayan;Byrappa, Kullaiah
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.566-571
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    • 2019
  • One-pot hydrothermal route was adopted to synthesize Al:BiVO4, at 4 h and 8 h reaction durations, by adding 1% aluminiumoxide powder (w/v) to the precursors. The products were investigated using several characterization techniques that conform a significant morphological change and a decrease in bandgap energy of the materials upon Al modification of scheelite monoclinic bismuth vanadate matrix at both hydrothermal durations. Antibacterial experiments were performed against methicillin-resistant Staphylococcus aureus in visible light condition to harness the photoxidation property of Al-doped BiVO4 and compare to that of unaltered BiVO4. Minimum inhibitory concentration of the synthesized materials was identified. The results indicate that Al-doping on BiVO4 has a significant effect on its photocatalytic antibacterial performance. Al:BiVO4 synthesized at 8 h hydrothermal treatment parades excellent sunlight-driven photocatalysis compared to the one synthesized at 4 h.

Exciton Dynamics and Device Lifetime of Phosphorescent dye doped Polymer Light Emitting Diodes

  • Kim, Jang-Joo;Jeong, W.I.;An, Cheng-Guo;Kang, J.W.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.166-166
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    • 2006
  • The photoluminescence (PL) efficiency of $Ir(ppy)_{3}$:PVK is lower than $Ir(ppy)_{3}$:CBP for the whole range of doping concentration and this low PL efficiency can be a reason of the lower efficiency of PhPLED than PhOLED. The lower efficiency is originated from the large bi-excitonic quenching such as the triplet-triplet annihilation. The PhPLEDs showed very short lifetime. The short lifetime was found to be originated from the instability of the doubly reduced $Ir(ppy)_{3^{-2}}$. The double reduction takes place because of the low electron mobility of PVK and large energy difference of LUMO level between PVK and $Ir(ppy)_{3}$.

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Fully Substituted Ethylene as a New Class of Highly Efficient Blue Emitting Materials for OLEDs

  • Park, Jong-Wook;Kim, Soo-Kang;Park, Young-Il;Kim, Kyoung-Soo;Choi, Cheol-Kyu;Lee, Sang-Do;Kim, Sang-Wook
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.363-367
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    • 2006
  • We synthesized new blue and bluish green emitting materials by using fully substituted ethylene moieties. Multi-layered EL devices were fabricated with synthesized materials and evaluated in terms of emission color and luminescence efficiency. BPBAPE[EML 4] having high $T_g$ of $155^{\circ}C$ showed luminance and power efficiency of 10.33cd/A and 4.0 lm/W without any doping agent. BTBPPA[EML 5] exhibited 5cd/A and 1.67lm/W efficiency with blue CIE value of (0.165, 0.195).

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Sensitivity Analyses on Breakdown Voltage of Cylindrical PN Junctions to the Doping Concentrations (원통형 PN접합의 항복전압의 농도에 대한 민감도)

  • Seo, Hyun-Seok;Jo, Jung-Yol;Ahn, Hee-Tae;Choi, Yearn-Ik
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.59-60
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    • 2006
  • 원통형 PN접합의 Baliga의 해석적인 항복전압에 대한 근사식을 유도하였다. 근사식은 접합길이, $r_j$와 공핍층 깊이, $W_{pp}$의 비 ($r_i/W_{pp}$)가 0.1보다 작은 경우 Baliga식과 잘 일치하였다. 농도에 대한 원통형 접합의 항복전압의 민감도를 유도하였으며, 근사식을 사용한 경우가 Baliga식의 경우보다 민감도식이 더 간단하기 때문에, 민감도를 고려한 소자 설계 시 활용될 수 있으리라 기대된다. 민감도 식을 이용하여 설계한 결과 항복전압의 편차가 10% 이내로 제어하기 위해서는 도핑농도가 $10^{15}cm^{-3}$이고 접합깊이가 $5{\mu}m$ 인 원통형 접합인 경우 농도 편차가 12.8%이내 이어야한다.

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Application of Al-doped Zinc Oxide for transparent conductive thin film (Al이 첨가된 Zinc Oxide박막의 투명전도막으로서의 응용)

  • 정운조;정용근;유용택
    • Electrical & Electronic Materials
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    • v.8 no.6
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    • pp.693-698
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    • 1995
  • We fabricated Zinc Oxide transparent conductive thin films with 2wt% of A1203 doping using rf magnetron sputtering. And we investigated electrical and optical characteristics of them which were made with conditions ; rf power 60-300W, thickness of film 3000 11000.angs.. Resistivity, carrier concentration and Hall mobility were investigated for electrical characteristics. Transmittance and optical band gap were investigated with Spectrophotometer in the wavelength range between 200-900 nm. As a result, ZnO thin film fabricated with rf power of 180W and thickness of 5000.angs. showed the best properties. At the best condition, the sample has resistivity of 1*10$\^$-4/.ohm.cm and transmittance of 95% in the visible range.

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