• 제목/요약/키워드: W Substituted

검색결과 151건 처리시간 0.026초

Pb[Cd1/2W1/2)0.02Zr0.505Ti0.475]O3조성에서의 MnO2첨가에 대한 영향 (Effect of MnO2 Addition on Electrical Properties and Microstructure in Pb[Cd1/2W1/2)0.02Zr0.505Ti0.475]O3)

  • 김대웅;김병익;김호기
    • 한국세라믹학회지
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    • 제25권6호
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    • pp.571-576
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    • 1988
  • The microstructure and electrical properties of 0.02Pb[Cd1/2W1/2)O3-0.505PbZrO3-0.475PbTiO3 with MnO2 addition have been investigated. The amount of MnO2 addition was 0, 0.2, 0.4, 0.6, 0.8, 1wt%, respectively. When MnO2 is added up to 0.2wt%, Mn3+ which is substituted for Ti4+ site make hole and act as a acceptor. When MnO2 is added over 0.2wt% Mn3+ which is substituted for Cd2+ site create electron and act as a donor. The variation of grain size show that it was rapidly increased by 0.4wt% addition of MnO2, and while that in the range of over 0.6wt% addition of MnO2 it was decreased. The solid solution range of MnO2 that assumed in this composition according to the variations of microstructure and electrical properties was 0.4-0.6wt%.

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Microwave Dielectric Properties of Sr-Substituted Ba(Mg0.5W0.5)O3 Ceramics

  • Yoon, Sang-Ok;Choi, Dong-Kyu;Oh, Jun-Hyuk;Kim, Shin
    • 한국세라믹학회지
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    • 제55권4호
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    • pp.364-367
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    • 2018
  • The phase evolution, microstructure, and microwave dielectric properties of Sr-substituted $Ba(Mg_{0.5}W_{0.5})O_3$ ceramics, i.e., $(Ba_{1-x}Sr_x)(Mg_{0.5}W_{0.5})O_3$ ($0{\leq}x{\leq}0.30$), sintered at $1700^{\circ}C$ for 1 h were investigated. All compositions showed a 1 : 1 ordered perovskite structure. In all the compositions, $BaWO_4$ was detected as the secondary phase. With increasing x in ($Ba_{1-x}Sr_x$) $(Mg_{0.5}W_{0.5})O_3$, the lattice parameter increased linearly, indicating that a substitutional solid solution occurred. All compositions exhibited a dense microstructure. The value of ${\varepsilon}_r$ increased slightly with increasing x. The value of $Q{\times}f_0$ increased with the increase in x up to x = 0.10 and reached a saturated value of about 100,000 GHz. The composition for x = 0.20, i.e., $(Ba_{0.80}Sr_{0.20})(Mg_{0.5}W_{0.5})O_3$, sintered at $1700^{\circ}C$ for 1 h exhibited superior microwave dielectric properties of ${\varepsilon}_r=19.6$, $Q{\times}f_0=99,358GHz$, and ${\tau}_f=0.0ppm/^{\circ}C$, respectively.

텅스텐 중합금에 Mn 첨가에 따른 미세조직 (The Effect of Mn on Microstructural Change in 93W-5.6Ni-1.4Fe Heavy Alloy)

  • 김은표
    • 한국분말재료학회지
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    • 제5권1호
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    • pp.35-41
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    • 1998
  • The effect of Mn on the densification and the microstructural change in W heavy alley was investigated with adopting the improved Mn-adding method. In order to avoid the pore formation problems associated with Mn powder mixing to the other constituent powders, Mn was added afterwards to the sintered heavy alloy; Mn powder was spread homogeneously on the surface of the sintered heavy alloy compact, and this Mn powder contained specimen was resintered at the same sintering temperature. As expected, the resintered specimen showed the pore free microstructure because Mn was reduced separately from the other constituent elements. It was also founded that W grains grew rapidly at the initial stage of resintering treatment due to the activated reprecipitation of the excess W atoms substituted by Mn atoms, but the growth rate of W grains was slowly lowered with the prolonged sintering time, especially, compared to the Mn free heavy alloy. Such a retardation of grain growth should be attributed to the decreased W solubility in the Mn contented matrix phase. Furthermore, Mn addition resulted in the decrease of contiguity by improving the wetting between matrix phase and W grain.

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Strength and Some Durability Properties of Concrete Containing Rice Husk Ash Produced in a Charcoal Incinerator at Low Specific Surface

  • Abalaka, A.E.
    • International Journal of Concrete Structures and Materials
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    • 제7권4호
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    • pp.287-293
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    • 2013
  • Strength and some durability properties of concrete containing rice husk ash (RHA) predominantly composed of amorphous silica at a specific surface of 235 $m^2/kg$ produced using a charcoal incinerator were determined. The maximum ordinary Portland cement (OPC) replacement with the RHA increased with increase in water/binder (w/b) ratio of the concrete mixes. The results show that 15 % OPC could be substituted by the RHAwithout strength loss at w/b ratio of 0.50. The split tensile strength generally increased with increase in RHA content for the mixes.

이규화몰리.텅스텐 복합재료의 합성에 관한 연구 (A Study on Synthesis of (Mo.W)$\textrm{Si}_2$ Composites)

  • 장대규
    • 한국재료학회지
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    • 제9권1호
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    • pp.92-98
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    • 1999
  • (Mo.W)Si$_2$ composites were fabricated by vacuum hot-pressing elemental Mo, W and Si powders at various temperatures. Elemental Mo, W and Si powders were alloyed in the proper proportions to form solid solutions. The microstructure and properties of these materials was characterized by using x-ray diffraction, optical microscopy, energy dispersive x-ray spectroscopy and Vicker's technique. It was found that tungsten was mainly substituted for Mo atoms, and made a completed solid solution of (Mo.W)Si$_2$ over 1$600^{\circ}C$. The lattice parameters and Vickers hardness increased largely with increasing reaction temperature by the most soluble elements, due to the solid-solution hardening.

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New Low-Band Gap 2D-Conjugated Polymer with Alkylthiobithiophene-Substituted Benzodithiophene for Organic Photovoltaic Cells

  • Park, Eun Hye;Ahn, Jong Jun;Kim, Hee Su;Kim, Ji-Hoon;Hwang, Do-Hoon
    • 대한화학회지
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    • 제60권3호
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    • pp.194-202
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    • 2016
  • Two conjugated semiconducting copolymers consisting of 4,7-bis(4-(2-ethylhexyl)-2-thiophene)-2,1,3-benzothiadiazole (DTBT) and benzo[1,2-b:4,5-b']dithiophene with 5-(2-ethylhexyl)-2,2'-bithiophene (BDTBT) or 5-(2-ethylhexylthio)- 2,2'-bithiophene (BDTBT-S) were designed and synthesized as donor materials for organic photovoltaic cells (OPVs). Alkylthio-substituted PBDTBT-S-DTBT showed a higher hole mobility and lower highest occupied molecular orbital (HOMO) energy level (by 0.08 eV) than the corresponding alkyl-substituted PBDTBT-DTBT. An OPV fabricated using PBDTBT-S-DTBT showed higher VOC and JSC values of 0.83 V and 7.56 mA/cm2, respectively, than those of a device fabricated using PBDTBT-DTBT (0.74 V) leading to a power conversion efficiency of 2.05% under AM 1.5G 100 mW/cm2 illumination.

고추씨 기름 대체 향미유 개발에 관한 연구: 치자, 고량을 이용한 유용성 천연 검정색소의 제조 (Study of Research and Development for Seasoning Oil as Red Pepper Seed Oil Substituted: Manufacturing of oil soluble natural black pigment from Gardenia and Kaoliang)

  • 구본순;김덕숙
    • 한국식품저장유통학회지
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    • 제11권1호
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    • pp.42-46
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    • 2004
  • 치자로부터 청색 및 황색색소, 고량으로부터 암갈색 색소를 주정을 이용하여 추출ㆍ농축하여 60$^{\circ}$Brix 농도의 추출물을 회수하였는데, 각각의 수율은 0.68, 1.97, 0.63% (w/w)였다. 이들을 대두유: 물: 유화제: 치자청: 치자황: 고량색소=8: 22: 42: 10: 15: 13 (w/w)의 비율로 혼합하고 균질화하여 유용성 천연 검정색소를 얻었다. 이 색소를 대두유에 용해시킨 결과 대두유의 품온이 30∼4$0^{\circ}C$ 범위에서 가장 높은 용해도를 나타내었다. 대두유에 한 번 용해된 색소물질은 혼합 대두유의 품온을 2$0^{\circ}C$ 이하로 유지하여도 재분리현상이 발생하지 않는 것으로 확인되었다

포졸란계 미분말 및 화학혼화제에 의한 시멘트페이스트의 유동특성에 관한 연구 (A Study on the Mobility Properties of Cement Paste by Fine Fowers of Pozzolan Chemical Adixtures)

  • 김도수;노재성
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1995년도 가을 학술발표회 논문집
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    • pp.25-29
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    • 1995
  • To perform high-strength of concrete, fine powers of pozzolan such as fly ash, silica fume mixed with cement. But mobility of cement and concrete decreased due to using of these powers. To control decrease of this mobility, it is required that mobility is improved by using of chemical admixture such as superplasticizer. We used admixtures -NSF, NM-2, NT-2 etc- in order to improve mobility of cement paste being substituted by 10, 20% of pozzolans respectively. It proved that optimum dosage of NSF, NT-2 was 2.0% for being substituted 10%, 3.0% for 20% so as to increase mobility of cement paste mixed paste mixed with fine powers of pozzolan at W/C=0.40.

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마비성 조음장애의 임상적 양상에 관한 고찰 (Some Clinical Aspects of Dysarthria)

  • 김현기;김완호;서정환;홍기환;신효근;고도흥
    • 음성과학
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    • 제3권
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    • pp.38-49
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    • 1998
  • Dysarthrias are a sort of neuromotor disorders because of the weakness of neuromotor controls. They are classified in six types on the basis of Mayo clinic research: flaccid, spastic, ataxic, hypokinetic, hypekinetic and mixed types. Five dysarthria types are investigated in this study. MRI, EMG, neuropathological tests are essential diagnostic processing. Visi-Pitch and Spectrgraphy, CSL are used for assessing dysarthria speech. Maximum phonation time, diadochokinetic rate, Voice Onset Time and substitution rate are the speech evaluation parameters. Maximum phonation time and diadochokinetic rates are the lowest in case of spastic and ataxic dysarthrias. Spastic dysarthria shows the substituted glottalized consonants. However, flaccid, ataxic and hypokinetic dysarthrias show the substituted aspirated consonants. VOT is the longest for hypokinetic dysarthria and the shortest for ataxic dysarthria. Jitter shows higher percentage in comparison with control group. Speech evaluation using experimental phonetic instruments help create on international standardization of speech evaluation for speech disorders.

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