• The Transactions of the Korean Institute of Electrical Engineers C
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• v.51 no.10
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• pp.465-472
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• 2002

This paper presents a study on the aging and recovery of HTV (high temperature vulcanized) silicone rubber used for outdoor insulators. UV irradiation, corona discharge and water immersion were employed as factors of the artificial aging. The effects of changes derived from these stresses on the tracking and arc resistance of silicone rubber were examined. We have investigated the aging phenomena of HTV silicone rubber by the above stresses using the surface energy calculation with contact angle measurement, solvent-extraction, and surface/volume resistivity and so on. These results showed that UV irradiation and corona discharge lead to nearly the same surface oxidation, but the percentage change of mobile low molecular weight by these stresses was different. Furthermore, the oxidized layer induced under UV irradiation restricted the recovery of hydrophobic surface. Water immersion little lowered hydrophobicity level and leaded to a loss of tracking and arc resistance. The degradation mechanism based on our results was discussed.

• Journal of Electrical Engineering and Technology
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• v.13 no.3
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• pp.1337-1345
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• 2018

The reliability of power transmission and distribution depends up on the consistency of insulation in the high voltage power transformer. In recent times, considering the drawbacks of conventional mineral oils such as poor biodegradability and poor fire safety level, several research works are being carried out on natural ester based nanofluids. Earlier research works show that sunflower oil has similar dielectric characteristics compared with mineral oil. BIOTEMP oil which is now commercially available in the market for transformers is based on sunflower oil. Addition of nanofillers in the base oil improves the dielectric characteristics of liquid insulation. Only few results are available in the literature about the insulation characteristics of nano modified natural esters. Hence understanding the influence of addition of nanofillers in the dielectric properties of sunflower oil and collecting the database is important. Considering these facts, present work contributes to investigate the important characteristics such as partial discharge, lightning impulse, breakdown strength, tandelta, volume resistivity, viscosity and thermal characteristics of $SiO_2$ nano modified sunflower oil with different wt% concentration of nano filler material varied from 0.01wt% to 0.1wt%. From the obtained results, nano modified sunflower oil shows better performance than virgin sunflower oil and hence it may be a suitable candidate for power transformer applications.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.239-240
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• 2008

As semiconductor devices are scaled down for better performance and more functionality, the Cu-based interconnects suffer from the increase of the resistivity of the Cu wires. The resistivity increase, which is attributed to the electron scattering from grain boundaries and interfaces, needs to be addressed in order to further scale down semiconductor devices [1]. The increase in the resistivity of the interconnect can be alleviated by increasing the grain size of electroplating (EP)-Cu or by modifying the Cu surface [1]. Another possible solution is to maximize the portion of the EP-Cu volume in the vias or damascene structures with the conformal diffusion barrier and seed layer by optimizing their deposition processes during Cu interconnect fabrication, which are currently ionized physical vapor deposition (IPVD)-based Ta/TaN bilayer and IPVD-Cu, respectively. The use of in-situ etching, during IPVD of the barrier or the seed layer, has been effective in enlarging the trench volume where the Cu is filled, resulting in improved reliability and performance of the Cu-based interconnect. However, the application of IPVD technology is expected to be limited eventually because of poor sidewall step coverage and the narrow top part of the damascene structures. Recently, Ru has been suggested as a diffusion barrier that is compatible with the direct plating of Cu [2-3]. A single-layer diffusion barrier for the direct plating of Cu is desirable to optimize the resistance of the Cu interconnects because it eliminates the Cu-seed layer. However, previous studies have shown that the Ru by itself is not a suitable diffusion barrier for Cu metallization [4-6]. Thus, the diffusion barrier performance of the Ru film should be improved in order for it to be successfully incorporated as a seed layer/barrier layer for the direct plating of Cu. The improvement of its barrier performance, by modifying the Ru microstructure from columnar to amorphous (by incorporating the N into Ru during PVD), has been previously reported [7]. Another approach for improving the barrier performance of the Ru film is to use Ru as a just seed layer and combine it with superior materials to function as a diffusion barrier against the Cu. A RulTaN bilayer prepared by PVD has recently been suggested as a seed layer/diffusion barrier for Cu. This bilayer was stable between the Cu and Si after annealing at $700^{\circ}C$ for I min [8]. Although these reports dealt with the possible applications of Ru for Cu metallization, cases where the Ru film was prepared by atomic layer deposition (ALD) have not been identified. These are important because of ALD's excellent conformality. In this study, a bilayer diffusion barrier of Ru/TaCN prepared by ALD was investigated. As the addition of the third element into the transition metal nitride disrupts the crystal lattice and leads to the formation of a stable ternary amorphous material, as indicated by Nicolet [9], ALD-TaCN is expected to improve the diffusion barrier performance of the ALD-Ru against Cu. Ru was deposited by a sequential supply of bis(ethylcyclopentadienyl)ruthenium [Ru$(EtCp)_2$] and $NH_3$plasma and TaCN by a sequential supply of $(NEt_2)_3Ta=Nbu^t$ (tert-butylimido-trisdiethylamido-tantalum, TBTDET) and $H_2$ plasma. Sheet resistance measurements, X-ray diffractometry (XRD), and Auger electron spectroscopy (AES) analysis showed that the bilayer diffusion barriers of ALD-Ru (12 nm)/ALD-TaCN (2 nm) and ALD-Ru (4nm)/ALD-TaCN (2 nm) prevented the Cu diffusion up to annealing temperatures of 600 and $550^{\circ}C$ for 30 min, respectively. This is found to be due to the excellent diffusion barrier performance of the ALD-TaCN film against the Cu, due to it having an amorphous structure. A 5-nm-thick ALD-TaCN film was even stable up to annealing at $650^{\circ}C$ between Cu and Si. Transmission electron microscopy (TEM) investigation combined with energy dispersive spectroscopy (EDS) analysis revealed that the ALD-Ru/ALD-TaCN diffusion barrier failed by the Cu diffusion through the bilayer into the Si substrate. This is due to the ALD-TaCN interlayer preventing the interfacial reaction between the Ru and Si.

• Journal of the Korean Geotechnical Society
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• v.34 no.2
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• pp.19-32
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• 2018

During the process of gas hydrate extraction in the deep seabed, fine diatom particle migration occurs, which causes the seabed slope failure and the productivity deterioration of the gas hydrate. Therefore, a study related with the changes of the ground characteristics due to the fine particle migration is required. The objective of this study is to investigate the change of hydraulic properties of sand due to the migration of fine diatom particle in sandy soils. In order to simulate the sediments of the Ulleung basin gas hydrate in the East Sea, fifteen sand-diatom mixtures that have different diatom volume fractions (DVF) are prepared. During the falling head permeability tests, the coefficients of permeability are measured according to the DVF. In addition, for the simulation of the fine diatom particle migration, constant head permeability tests are conducted by applying the hydraulic pressures of 3 kPa, 6kPa, and 9 kPa on a specimen composed of two layers: a specimen with 50% DVF in upper layer and a specimen with 0% DVF in lower layer. Furthermore, the coefficient of permeability and the electrical resistivity of the migration zone are measured during the constant head permeability test. The falling head permeability tests show that the coefficient of permeability decreases as the DVF of the specimen increases. In addition, the gradient of the coefficient of permeability curve decreases in the DVF range of 10%~50% compared with that of 0%~10%, and increases above 50% in DVF. The result of constant head permeability tests shows that the coefficient of permeability decreases and electrical resistivity increases in the migration zone due to the fine diatom particle migration. This study demonstrates that fine diatom particle migration reduces the permeability of the soils and the behavior of the migration zone due to the fine diatom particle migration may be estimated based on the reversal relationship between the coefficient of permeability and the electrical resistivity.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.63 no.3
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• pp.367-370
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• 2014

The accelerated thermal aging of a CSPE were carried out for 0, 80.82, 161.63 days at $100^{\circ}C$, which are equal to 0, 40 and 80 years, respectively. The volume electrical resistivities of the non-accelerated thermally aged CSPE and the accelerated thermally aged CSPE for 40y and 80y were $9.620{\times}10^{12}{\sim}1.246{\times}10^{13}{\Omega}{\cdot}cm$, $5.066{\times}10^{12}{\sim}7.576{\times}10^{12}{\Omega}{\cdot}cm$ and $7.195{\times}10^{12}{\sim}9.208{\times}10^{12}{\Omega}{\cdot}cm$ at room temperature, respectively. The dielectric constant of the non-accelerated thermally aged CSPE and the accelerated thermally aged CSPE for 40y and 80y were 3.355~4.030, 2.996~3.963 and 3.020~4.776 at room temperature, respectively. After seawater and freshwater flooding, the volume electrical resistivity of the CSPE trend slightly upward according to drying day at room temperature. After seawater flooding, the dielectric constant of the accelerated thermally aged CSPE were not measured. After seawater flooding, bright open pores of the accelerated thermally aged CSPE were partly transferred to dark close pores due to salinity. After freshwater flooding, dark close pores of the accelerated thermally aged CSPE were partly transferred to bright open pores because salinity of them is decreased. An insulation property of a cable in NPPs was decreased because of the seawater flooding, and an insulation property of them was recovered through the freshwater flooding. As a result, it is considered that an insulation property of a contaminated cable through Tsunami can be recovered if it is cleaned quickly.

• Geophysics and Geophysical Exploration
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• v.16 no.3
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• pp.180-189
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• 2013

Geophysical exploration is widely used to develop strategic mineral resources in the world because of its efficient method in detecting mineralized zones in the metallic ore deposit. It is important to understand the physical properties of the stratum so that geophysical data can be more accurately interpreted. This paper is to comprehend physical properties of the rock at the Gagok mine, a typical skarn deposit in Korea. Thus, laboratory tests were conducted on specimens of ore and host rocks which were collected from rock outcrops and drill cores at the Gagok mine. Using the measurement system of rock physical property, we investigated the density, magnetic susceptibility, resistivity, and spectral induced polarization. According to the results, all physical properties of specimens had wide differences depending on contents of ore minerals, which are formed by skarnization. Especially, using the chargeability and time constant from the calculated spectral induced polarization data by the Cole-Cole inversion, we could estimate the volume contents as well as the grain size of the sulfide minerals. Therefore, the spectral induced polarization technique may be considered a useful method when exploring metallic ore deposit with sulfide minerals.

• Journal of the Korean Wood Science and Technology
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• v.36 no.6
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• pp.1-12
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• 2008

A series of the studies on the applied physical properties of domestic species have been conducted last three years. Liriodendron tulipifera, Betula costata, Paulownia coreana were examined on sorption property, thermal property, electric property, acoustic property. Because the same apparatus and experimental procedures were used for all species, their results can be easily comparable. The experiments for sorption property were conducted with 80 mesh wood powder and resulted in their EMC's and sorption isotherms. The thermal conductivity and diffusivity, and electric resistance and volumetric electric resistivity were measured with a thermal-wire device and a high electric resistance meter. The differences of the thermal and electric properties between quarter-and flat-sawn specimens were observed, which was partially attributed to their anatomical differences. An acoustic measurement system was used to evaluate dynamic MOE and internal friction. This paper provides the useful fundamental data for designing a wood structure, correcting a portable resistance-type moisture meter, and acoustic properties of wood.

• Journal of the Korean Wood Science and Technology
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• v.36 no.4
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• pp.1-10
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• 2008

A series of the studies on the applied physical properties of domestic species have been conducted last three years. Pinus koraiensis and Larix kaempferi were two of the three species examined for the first year. Because the same apparatus and experimental procedures were used for all species, their results can be easily comparable. The experiments for sorption property were conducted with 20- and 80-mesh wood powder and resulted in their EMCs and sorption isotherms at various RH conditions. The thermal conductivity and diffusivity, and electric resistance and volumetric electric resistivity were measured with a thermal-wire device and a high electric resistance meter. The differences in the thermal and electric properties between quarter- and flat-sawn specimens were observed, which were partially attributed to their anatomical differences. An acoustic measurement system was used to evaluate dynamic MOE and internal friction. This paper provides the useful fundamental data for designing a wood structure, correcting a portable resistance-type moisture meter, and acoustic properties of wood.

• The Journal of Engineering Geology
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• v.21 no.4
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• pp.323-336
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• 2011

The hydro-mechanical behavior of the Earth's crust is strongly dependent on the fractional volume and geometrical structure of effective pore spaces. This study aims to understand the characteristics of pores using electrical impedance. We measured the electric impedance of core samples (diameter, 38-50 mm; length, 70-100 mm) of three types of granite (Hwangdeung, Pocheon, and Yangsan) and two types of sandstone (Boryung and Berea) with different porosities and pore structures, after saturation with saline water of varying salinities. The results show that resistance decreases but capacitance increases with increasing salinity of the pore fluid. For a given salinity, the resistivity and formation factor are reduced with increasing porosity of the rocks, and the capacitance increases. Berea sandstone shows anisotropy in resistance, tortuosity, and cementation factor, with these factors being highest normal to bedding planes. This result indicates that the connectivity of pores is weakest normal to bedding. In conclusion, the electrical characteristics of the tested samples are related not only to their porosity but also to the pore geometry.

• Korean Journal of Materials Research
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• v.8 no.6
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• pp.513-519
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• 1998

Zr-Si binary alloys containing 0.01 to O.lwt.%Si were prepared to investigate the effect of Si on the corrosion behavior of Zr. Corrosion test was performed in pure water at 36$0^{\circ}C$ under a pressure of 2660psi for 100days. The alloys containing 0.01 wt. % and 0.05wt. %Si had the black and uniform oxide film and didn't show the transition of corrosion rate. However. the alloys containing O.lwt.%Si had white oxide film and showed the trasition of corrosion rate at 70 days corrosion test. The weight gain increased with the increasing Si content from 0.01 to 0.1 wt.%. The variation of Si contents had no effect on changing the oxide structure but had significant effect on the electrical resistivity of oxide. The electrical resistivity decreased with increasing Si content. The fraction of precipitates in the Zr-Si binary alloys. identified as tetragonal $Zr_{3}$Si increased with increasing Si content. The increase of the volume fraction of precipitates is thought to be responsible for the increase of weight gain due to short circuit effect of precipitate.