• 제목/요약/키워드: Volume of pores

검색결과 221건 처리시간 0.026초

Modeling of Mechanical Properties of Concrete Mixed with Expansive Additive

  • Choi, Hyeonggil;Noguchi, Takafumi
    • International Journal of Concrete Structures and Materials
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    • 제9권4호
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    • pp.391-399
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    • 2015
  • This study modeled the compressive strength and elastic modulus of hardened cement that had been treated with an expansive additive to reduce shrinkage, in order to determine the mechanical properties of the material. In hardened cement paste with an expansive additive, hydrates are generated as a result of the hydration between the cement and expansive additive. These hydrates then fill up the pores in the hardened cement. Consequently, a dense, compact structure is formed through the contact between the particles of the expansive additive and the cement, which leads to the manifestation of the strength and elastic modulus. Hence, in this study, the compressive strength and elastic modulus were modeled based on the concept of the mutual contact area of the particles, taking into consideration the extent of the cohesion between particles and the structure formation by the particles. The compressive strength of the material was modeled by considering the relationship between the porosity and the distributional probability of the weakest points, i.e., points that could lead to fracture, in the continuum. The approach used for modeling the elastic modulus considered the pore structure between the particles, which are responsible for transmitting the tensile force, along with the state of compaction of the hydration products, as described by the coefficient of the effective radius. The results of an experimental verification of the model showed that the values predicted by the model correlated closely with the experimental values.

Adsorption capability of activated carbon synthesized from coconut shell

  • Islam, Md Shariful;Ang, Bee Chin;Gharehkhani, Samira;Afifi, Amalina Binti Muhammad
    • Carbon letters
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    • 제20권
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    • pp.1-9
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    • 2016
  • Activated carbon was synthesized from coconut shells. The Brunauer, Emmett and Teller surface area of the synthesized activated carbon was found to be 1640 m2/g with a pore volume of 1.032 cm3/g. The average pore diameter of the activated carbon was found to be 2.52 nm. By applying the size-strain plot method to the X-ray diffraction data, the crystallite size and the crystal strain was determined to be 42.46 nm and 0.000489897, respectively, which indicate a perfect crystallite structure. The field emission scanning electron microscopy image showed the presence of well-developed pores on the surface of the activated carbon. The presence of important functional groups was shown by the Fourier transform infrared spectroscopy spectrum. The adsorption of methyl orange onto the activated carbon reached 100% after 12 min. Kinetic analysis indicated that the adsorption of methyl orange solution by the activated carbon followed a pseudo-second-order kinetic mechanism (R2 > 0.995). Therefore, the results show that the produced activated carbon can be used as a proper adsorbent for dye containing effluents.

Surfactant enhanced filtration performances of monochlorophenol isomers through low-pressure membrane

  • Kumar, Yogesh;Brahmbhatt, H.;Trivedi, G.S.;Bhattacharya, A.
    • Membrane and Water Treatment
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    • 제2권3호
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    • pp.137-145
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    • 2011
  • Membrane processes are major breakthrough for the removal of organic pollutants in water remediation. The separations of solutes depend on nature of the membranes and solutes. The separation performance depends on the nature of the solutes (i.e., molecular volume, polarity, and hydrophobicity) for the same membrane. As 4-chlorophenol is of more dipolemoment compared to 2-chlorophenol, the orientation of the molecule enables it pass through the pores of the membrane, which is of negatively charged and thus separation order follows: 2-chlorophenol > 4-chlorophenol. Hydrophobicity factor also supports the order. Addition of sodium dodecyl sulfate (SDS) to chlorophenol solution shows remarkable increase in separation performance of the membrane. The improvement in separation is 1.8 and 1.5 times for 4- and 2- chlorophenol consecutively in case of 0.0082 M SDS (1cmc = 0.0082 M) in the solution. 4-chlorophenol has better attachment tendency with SDS because of its relatively more hydrophobic nature and thus reflects in performance i.e. the separation performance of 4-chlorophenol with SDS through the membrane is better compared to 2-chlorophenol.

Dynamic characteristics of curved inhomogeneous nonlocal porous beams in thermal environment

  • Ebrahimi, Farzad;Daman, Mohsen
    • Structural Engineering and Mechanics
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    • 제64권1호
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    • pp.121-133
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    • 2017
  • This paper proposes an analytical solution method for free vibration of curved functionally graded (FG) nonlocal beam supposed to different thermal loadings, by considering porosity distribution via nonlocal elasticity theory for the first time. Material properties of curved FG beam are assumed to be temperature-dependent. Thermo-mechanical properties of porous FG curved beam are supposed to vary through the thickness direction of beam and are assumed to be temperature-dependent. Since variation of pores along the thickness direction influences the mechanical and physical properties, porosity play a key role in the mechanical response of curved FG structures. The rule of power-law is modified to consider influence of porosity according to even distribution. The governing equations of curved FG porous nanobeam under temperature field are derived via the energy method based on Timoshenko beam theory. An analytical Navier solution procedure is used to achieve the natural frequencies of porous FG curved nanobeam supposed to thermal loadings with simply supported boundary condition. The results for simpler states are confirmed with known data in the literature. The effects of various parameters such as nonlocality, porosity volume fractions, type of temperature rising, gradient index, opening angle and aspect ratio of curved FG porous nanobeam on the natural frequency are successfully discussed. It is concluded that these parameters play key roles on the dynamic behavior of porous FG curved nanobeam. Presented numerical results can serve as benchmarks for future analyses of curve FG nanobeam with porosity phases.

올리고당 종류와 첨가량에 따른 증편의 품질 특성 (Quality Characteristics of Jeung-Pyun(Korean Rice Cake) According to the Type and Amount of the oligosaccharide Added)

  • 이은아;우경자
    • 한국식품조리과학회지
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    • 제17권5호
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    • pp.431-440
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    • 2001
  • This study was carried out to investigate the effects of oligosaccharide addition on Jeung-Pyun fermentation. Fructooligosaccharide (FOS), isomaltooligosaccharide (IMOS), galactooligosaccharide (GOS) were used at the concentration of 15%, 25% or 35% of the rice in Jeung-Pyun ingredients. The physicochemical properties, sensory evaluation and instrumental characteristics were examined. The internal structure of Jeung-Pyun samples was observed by SEM. The pH of Jeung-Pyun batters was decreased as the fermentation progressed. Compared with the control using sucrose, the specific volume of Jeung-Pyun was higher in the 15% and 25% of oligosaccharide-added samples. The degree of gelatinization decreased more slowly than control as the storage time increased both at 20$\^{C}$ and 4$\^{C}$. In sensory evaluation, Jeung-Pyun with FOS and IMOS at the levels of 25∼35% and GOS at the levels of 25% showed the best scores. In instrumental characteristics, springiness, gumminess, hardness and cohesiveness were similar among all samples during storage at 20$\^{C}$ and 4$\^{C}$. In the internal structure of Jeung-Pyun observed by SEM, Jeung-Pyun substituted with oligosaccharide at the levels of 25% for sucrose showed large and regularly distributed air pores. In conclusion, the replacement of sucrose with oligosaccharide in Jeung-Pyun ingredients appeared acceptable in terms of fermentative aspects.

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Carbon Nanotube로 강화된 알루미나 기지 복합재료의 제조 및 파괴특성 (Fabrication and Fracture Properties of Alumina Matrix Composites Reinforced with Carbon Nanotubes)

  • 김성완;정원섭;손기선;손창영;이성학
    • 대한금속재료학회지
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    • 제47권1호
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    • pp.50-58
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    • 2009
  • In this study, alumina matrix composites reinforced with carbon nanotubes (CNTs) were fabricated by ultrasonic dispersion, ball milling, mixing, compaction, and sintering processes, and their relative density, electrical resistance, hardness, flexure strength, and fracture toughness were evaluated. 0~3 vol.% of CNTs were relatively homogeneously dispersed in the composites in spite of the existence of some pores. The three-point bending test results indicated that the flexure strength increased with increasing volume fraction of CNTs, and reached the maximum when the CNT fraction was 1.5 vol.%. The fracture toughness increased as the CNT fraction increased, and the fracture toughness of the composite containing 3 vol.% of CNTs was higher by 40% than that of the monolithic alumina. According to observation of the crack propagation path after the indentation fracture test, a new toughening mechanism of grain interface bridging-induced CNT bridging was suggested to explain the improvement of fracture toughness in the alumina matrix composites reinforced with CNTs.

Deflection and vibration analysis of higher-order shear deformable compositionally graded porous plate

  • Ebrahimi, Farzad;Habibi, Sajjad
    • Steel and Composite Structures
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    • 제20권1호
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    • pp.205-225
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    • 2016
  • In this study the finite element method is utilized to predict the deflection and vibration characteristics of rectangular plates made of saturated porous functionally graded materials (PFGM) within the framework of the third order shear deformation plate theory. Material properties of PFGM plate are supposed to vary continuously along the thickness direction according to the power-law form and the porous plate is assumed of the form where pores are saturated with fluid. Various edge conditions of the plate are analyzed. The governing equations of motion are derived through energy method, using calculus of variations while the finite element model is derived based on the constitutive equation of the porous material. According to the numerical results, it is revealed that the proposed modeling and finite element approach can provide accurate deflection and frequency results of the PFGM plates as compared to the previously published results in literature. The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of the several parameters such as porosity volume fraction, material distribution profile, mode number and boundary conditions on the natural frequencies and deflection of the PFGM plates in detail. It is explicitly shown that the deflection and vibration behaviour of porous FGM plates are significantly influenced by these effects. Numerical results are presented to serve as benchmarks for future analyses of FGM plates with porosity phases.

국산 카올린의 흡착성에 관한 연구(II) - 분체학적 고찰 (Studies on the Adsorptive Properties of Korean Kaolin (II) - Micromeritic Study of Korean Kaolin)

  • 이계주
    • 약학회지
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    • 제29권4호
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    • pp.176-182
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    • 1985
  • As a part of the studies on adsorptive properties of Korean halloysite clays, Hadong white clays of premium grade were examined for geometric pore structured by mercury porosimetry and for specific surface areas by nitrogen adsorption according to the BET procedure. Three size fractions of the native clay sample were derived from passage BS #100, #200 and #325 meshes, respectively. Several parameters lhus observed in relation to the pore structures are shown below: 1. The size fraction of BS #100, #200 and #325 show internal pore volumes of 25.3, 30.2 and $35.0m^2g^{-1}$, respectively. 2. In the distribution curves of the cumulative pore volume against pore diameter, it has been shown that the larticle sizes, the steeper the distribution over the larger ranges of pore diameters. The converse is true the smaller particles. 3. Internal pore areas increase with decrease in pore sizes. It follows that the pores having diameters of $\leq$0.1$\mu\textrm{m}$ are responsible for more than 90% of the total pore area. 4. The behaviour of nitrogen adsorption can be best described by BET type IV isotherm. Further, the hysteresis loops of the adsorptiondesorption curves become narrower with decresing particle sizes. 5. The specific surface areas observed for the fractions of BS #100, BS #200 and BS #325 are 34.6, 35.4 and 43.2m $^2g^{-1}$, respectively. and the calcined clay of BS #325 has a specific surface area near $30.4m^2g^{-1}$.

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고주파방식 충전기 개발을 위한 페라이트 변압기 설계에 관한 연구 (The Study of the Ferrite Transformer Design for the Development of the High-frequency Battery Charger)

  • 안용호;박종광;김상준;윤장완;윤기웅;한병성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.683-686
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    • 2000
  • The chargers for DC power supply of the contro1lers, which have been installed in the relay rooms in 345/154kV substations of KEPCO, lag in both aspects of technique and performance. Moreover, as they are SCR-based, they dont meet the performance requirements of todays digital and automated controllers. Now two controllers are running in pair and one of those is for reservation. There are lots of troubles because the patrol engineering team has to replace them manually whenever they are out of order. So it is expected to bring convenience if the charger replacement is automated. Also, the existing chargers take much space, weight and cost - which have increased the need of development to make them smaller, less expensive, and have high quality. We will develop a charger system which has one fifth of the weight of the existing system by double-integrating the volume. The new system will be ready for a future full unmanned system with integrated pores for remote control, state-of-the-art digital features, and more than 90% efficiency/power factor against 80% efficiency/power factor of the existing system.

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Electrical Characteristics of Solution Processed DAL TFT with Various Mol concentration of Front channel

  • Kim, Hyunki;Choi, Byoungdeog
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.211.2-211.2
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    • 2015
  • In order to investigate the effect of front channel in DAL (dual active layer) TFT (thin film transistor), we successfully fabricated DAL TFT composed of ITZO and IGZO as active layer using the solution process. In this structure, ITZO and IGZO active layer were used as front and back channel, respectively. The front channel was changed from 0.05 to 0.2 M at fixed 0.3 M IGZO of back channel. When the mol concentration of front channel was increased, the threshold voltage (VTH) was increased from 2.0 to -11.9 V and off current also was increased from 10-12 to 10-11. This phenomenon is due to increasing the carrier concentration by increasing the volume of the front channel. The saturation mobility of DAL TFT with 0.05, 0.1, and 0.2 M ITZO were 0.45, 4.3, and $0.65cm2/V{\cdot}s$. Even though 0.2 M ITZO has higher carrier concentration than 0.05 and 0.1 M ITZO, the 0.1 M ITZO/0.3 M IGZO DAL TFT has the highest saturation mobility. This is due to channel defect such as pores and pin-holes. These defect sites were created during deposition process by solvent evaporation. Due to these defect sites, the 0.1 M ITZO/0.3 M IGZO DAL TFT shows the higher saturation mobility than that of DAL TFT with front channel of 0.2 M ITZO.

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