• Title/Summary/Keyword: Volatile chemicals

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Determination of Volatile Chemicals Emitted from Liquid Consumer Products using Head-space Method

  • Gwon, Gi-Dong;Sin, Myeong-Hui;Im, Ho-Jin;Jeong, U-Sik;Jo, Wan-Geun
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2008.11a
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    • pp.92-95
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    • 2008
  • Head-space method를 통하여 세척제에 대한 VOCs의 배출특성에서 1가제 제품을 제외한 모든 제품에서 다양한 VOCs가 검출되었으며, 제품에 따라 다소 차이는 있지만 대부분의 생활용품에서 유해한 물질이 검출되었다. 국내 제조회사에 따라 VOCs의 종류가 유사한 것도 있지만 대부분 제조회사에 따른 배출특성의 차이가 있을 수 있다고 사료되어진다. 외국과 국내의 생활용품의 구성성분 차이와 이에 따른 배출특성 차이가 있는 것으로 사료되어진다. 따라서 소비자가 VOCs노출로부터 보다 안전한 생활용품을 선정할 수 있도록, 생활용품제조회사들이 VOCs를 최소화하는 원자재를 사용하도록 유도해야 할 것이다.

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Desorption Characteristics of Volatile Organics Compounds in Soil by Microwave Heating (마이크로파 가열에 의한 토양 유기오염물질 탈착특성)

  • 문경환;김덕찬
    • Journal of environmental and Sanitary engineering
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    • v.11 no.2
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    • pp.65-73
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    • 1996
  • The objective of this study is to investigate the removal efficiency of volitile organic compounds in soil, and the mechanism of desorption by bench scale microwave heating, Silt soil used for experiment and was impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene and the microwave treatment was conducted in a modified domestic microwave oven : 2450MHz, 700W. According to the results of the research the removal efficiency was improved with increasing water contents and the soil temperature appeared to plateau period extending to 2-3minutes corresponds to the temperature a which steam distillation was expected. The value of removal rate constant (k) were calculated on dry and moisty silt soil, respectively, which showed linear with increasing microwave heating time. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants.

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Removal of Halocarbonanted Volatile Organic Compounds by Adsorption Technology (흡착법을 이용한 염소계 휘발성 유기화합물의 제거)

  • 김승재;조성용;김태영
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.4
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    • pp.355-362
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    • 2001
  • Adsorption isotherms of dichloromethane and 1, 1, 2-trichloro-1,2,2-trifluoroethane on an activated carbon pellet, Norit B4, were studied. For these chemicals, Sips equation gave the best fit for the single component adsorption isotherm. The adsorption affinity on activated carbon was greater for dichloromethane than that of 1, 1, 2-trichloro-1,2,2-trifluoroethane. An experimental and theoretical study was made for the adsorption of dichloromethane and 1, 1,2-trichloro-1,2,2-trifluoroethane in a fixed bed. Experimental results were used to examine the effect of operation variables, such as feed concentration, flow rate and bed height. Intraparticle diffusion was able to be explained by surface diffusion mechanism. An adsorption model baked on the linear driving force approximation (LDFA) was found to be applicable to fit the experimental data.

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Phytotoxic Effects of Naturally Occurring Chemicals from Pinus koraiensis on Experimental Species (잣나무의 天然化學物質이 다른 植物에 미치는 毒性作用)

  • Kil, Bong-Seop;Kim, Doo-Young;Kim, Young-Sik;Lee, Seung-Yeob
    • The Korean Journal of Ecology
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    • v.14 no.2
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    • pp.149-157
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    • 1991
  • To find out allelopathic potential of naturally occurring substances emitted form pinus korairnsis, water extracts and volatile sudstances of the tree materials werw provided and used for tests such as seed germination and seedling growth test. In general, the more was the concentration of the extracts and essential oils, the worse was growth effects of the selected species. The germination an the growth were inversely proportional to the concentration of the extracts and the essential oils of p. koraiensis. in other words, the chemical substances had the biological toxic activity. gc and gc/ms methods were employed for analysis and identification of phytotoxic substances from the tree leaves. Sixteen chemical compounds were identified from water extracts and nineteen from essential oils of p. koraiensis leaves. Through the experiment on germination and seedling growth test, the chemical substances naturally occurring from p. koraiensis seemed to be responsible for the allelopathic potential in this study.

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VOCs Concentrations of Indoor and Outdoor in Solvent Thinner-Using Occupation, and Application of TiO$_2$ Photocatalytic Air Cleaner

  • Wonho Yang;Joon Cho;Busoon Son;Park, Jongan
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2002.04a
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    • pp.1.1-2
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    • 2002
  • Ultimate objective of industrial hygiene is the prevention of health impairment that may result from exposure to chemicals at workplaces. This implies the definition of permissible levels of exposure, that is, levels that according to the present status of knowledge are estimated to cause no adverse health effects during the lifetime of the workers, and the regular assessment of the possible health risk associated with exposure by comparing the current or the integrated exposure with the permissible exposure limits. Workers in solvent thinner-using occupation environment might be highly exposed to VOCs(volatile organic compounds) because solvent thinner has been used extensively such as painting, spraying, degreasing, coating and so on in Korea. The purpose of this study was to recognize, evaluate and propose the alternative control the VOCs from solvent thinner-using workplace.

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LM-BP algorithm application for odour classification and concentration prediction using MOS sensor array (MOS 센서어레이를 이용한 냄새 분류 및 농도추정을 위한 LM-BP 알고리즘 응용)

  • 최찬석;변형기;김정도
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.210-210
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    • 2000
  • In this paper, we have investigated the properties of multi-layer perceptron (MLP) for odour patterns classification and concentration estimation simultaneously. When the MLP may be has a fast convergence speed with small error and excellent mapping ability for classification, it can be possible to use for classification and concentration prediction of volatile chemicals simultaneously. However, the conventional MLP, which is back-Propagation of error based on the steepest descent method, was difficult to use for odour classification and concentration estimation simultaneously, because it is slow to converge and may fall into the local minimum. We adapted the Levenberg-Marquardt(LM) algorithm [4,5] having advantages both the steepest descent method and Gauss-Newton method instead of the conventional steepest descent method for the simultaneous classification and concentration estimation of odours. And, We designed the artificial odour sensing system(Electronic Nose) and applied LM-BP algorithm for classification and concentration prediction of VOC gases.

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Simulated Study on Typical Sources of Volatile Organic Compounds (VOCs) in Indoor Air

  • Dai, Shugui;Bai, Zhipeng;Zhu, Tan;Zhang, Lin
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.745-751
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    • 1995
  • In this paper, several simulated devices were constructed for determining components of organic vapors emitting from decorative materials, daily use chemicals and from common behavior of human beings, such as smoking and cooking. The VOCs were preconcentrated on activated carbon and then desorbed by carbon disulphide. The results were obtained by GC/MS analysis and computer searching. It can be concluded that the categories of the sources and the components of organic vapors in indoor air are very complicated, and different sources of VOCs in indoor air have their own emission characteristics.

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Disturbance in Testosterone Production in Leydig Cells by Polycyclic Aromatic Hydrocarbons

  • Oh, Seunghoon
    • Development and Reproduction
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    • v.18 no.4
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    • pp.187-195
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    • 2014
  • Polycyclic aromatic hydrocarbons (PAHs), which are ubiquitous in the air, are present as volatile and particulate pollutants that result from incomplete combustion. Most PAHs have toxic, mutagenic, and/or carcinogenic properties. Among PAHs, benzo[a]pyrene (B[a]P) and dimethylbenz[a]anthracene (DMBA) are suspected endocrine disruptors. The testis is an important target for PAHs, yet effects on steroidogenesis in Leydig cells are yet to be ascertained. Particularly, disruption of testosterone production by these chemicals can result in serious defects in male reproduction. Exposure to B[a]P reduced serum and intratesticular fluid testosterone levels in rats. Of note, the testosterone level reductions were accompanied by decreased steroidogenic acute regulatory protein (StAR) and $3{\beta}$-hydroxysteroid dehydrogenase isomerase ($3{\beta}$-HSD) expression in Leydig cells. B[a]P exposure can decrease epididymal sperm quality, possibly by disturbing the testosterone level. StAR may be a key steroidogenic protein that is targeted by B[a]P or other PAHs.

Learning of narcotic odors by a parasitoid

  • Bui, Lan Huong;Takasu, Keiji
    • Korean Journal of Agricultural Science
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    • v.36 no.1
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    • pp.51-56
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    • 2009
  • When the parasitic wasp Microplitis croceipes experiences odors while feeding on sugar water, it learns to associate the odors with sugar and thereafter exhibits typical food searching behavior in response to the odors. Previous studies have shown that this wasp can be used for detection of the small amount of explosives or other volatile chemicals. In the present study, we examined if this wasp can learn and report narcotic odors. Males of M. croceipes were trained to link sugar water with pseudo-narcotic scents that have been used for training narcotic detection dogs, and their behavioral response to the trained odors was observed. The males that had been given either an odor or sugar water did not show any positive response to the odors. However, when the wasps were given a combination of sugar water and either the pseudo-Cocaine, Heroin, LSD or Marihuana, they quickly learned to associate the odors with sugar, and thereafter positively responded to those odors. Our results suggest that this wasp can be used for detection of these narcotics.

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Recovery of Toluene in gas by Polydimethylsiloxane/silica hybrid membrane permeation

  • Xu, De-Lin;Chung, Wook-jin;Jung, Bum-Suk;Gun, Eun-Mi;Ariz Lorenzana
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.176-179
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    • 2004
  • Volatile organic compounds (VOCs) are emitted as gases from certain solids or liquids. VOCs include a variety of chemicals, some of which may have short- and long-term adverse health effects. Current technologies for the treatment of VOC contaminated off-gasses are expensive to operate and more cost effective technologies are needed.(omitted)

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