• Proceedings of the IEEK Conference
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• 2008.06a
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• pp.487-488
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• 2008

SiOC films containing alkyl groups have a low dielectric constant because of the interaction between the C-H hydrogen bonds and the oxygen of high electro-negative atom. The Si-$CH_3$ in a void is broken by the $O_2$, therefore the strength of CH bond in Si-O-O-$CH_3$ bond increases. The Si-O-O-$CH_3$ bond is broken by nucleophilic attack due to Si atom, again. The elongation of C-H bond causes the red shift, and the compression of C-H bond causes the blue shift. Among these chemical shifts, the blue shift from $1000\;cm^{-1}$ to $1250\;cm^{-1}$ was related with the formation of pores. If the oxygen is deficient condition, the methylradicals of the electron-rich substitution group terminate easily the Si-O-Si cross-link, and the pore is originated from the cross-link breakdown due to much methyl radicals of Si-$CH_3$. The dielectric constant of the films decreases due to pore generation.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.155-158
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• 2004

In resin transfer molding, the preform similar to product shape is placed into a mold cavity. Rapid flow front without void formation is important for the composites processing. Multi-layered preform of sandwich is selected. Experiments is carried out using redial flow. An analytical modeling is performed and compared with experimental results. Accurate prediction of flow advance in the preform is of use for reducing the time consumption in the process and enhancing product properties of the final part.

• Nuclear Engineering and Technology
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• v.38 no.2
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• pp.119-128
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• 2006

We start to develop a predictable technology for thermal-hydraulic performance of the RMWR core using an advanced numerical simulation technology. As a part of this technology development, we are developing the advanced interface tracking method to improve the conservation of volume of fluid. The present paper describes a part of the development of the twophase flow simulation code TPFIT with the advanced interface tracking method. The numerical results applied to large-scale water-vapor two-phase flow in tight lattice rod bundles are shown and compared with experimental results. In the results of numerical simulation, a tendency of the predicted void fraction distribution in horizontal plane agreed with the measured values obtained by the advanced neutron radiography technique including the bridge formation of the liquid at the position of adjacent fuel rods where an interval is the narrowest.

• Journal of the Korean Society of Safety
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• v.13 no.1
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• pp.47-53
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• 1998

Radiant heater tubes with an inside burner are designed to transfer the heat generated from the burner to the outside of the tube by radiation. Hence, tube metal must suffer high temperature of approximately 900-$1000^{\circ}C$. The radiant tube is usually manufactured by centrifugal casting with high Ni-Cr alloys. In this study, failure analysis results of the radiant tube are reported. Failure mechanism of the tube was investigated by visual observation of the foiled tube, metallographic study of the cracked region and chemical analysis of tube metal and oxide scales. It was argued that the main cause of the cracking is repeated oxidation of the tube metal located beneath the thick oxide scale. Oxidation was caused by abnormally high operating temperature which can be verified by aged microstructure and internal void formation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1994.11a
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• pp.106-108
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• 1994

Electromigration(EM) tests were carried out on Al and Cu films in HV systems to study surface migration. The Al films were made on oxidized silicon wafers by thermal evaporation, in-situ annealed at 300$^{\circ}C$, patterned, and EM tested at 260$^{\circ}C$ and 4.5MA/$\textrm{cm}^2$. SEM observation with back scattered electron mode on the EM tested Al films disclosed that thinning took place under the native Al oxide. In the case of Cu films, tested using in-situ TEM, thinning was also observed at the early stage of void formation even though the thinned areas were much less than those of the Al films.

• Korea-Australia Rheology Journal
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• v.18 no.4
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• pp.217-224
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• 2006

Rapid flow advancement without void formation is essential in the liquid composite molding (LCM) such as resin transfer molding (RTM) and vacuum assisted resin transfer molding (VARTM). A highly permeable layer in multi-layered preform has an important role in improvement of the flow advancement. In this study, a multi-layered preform which consists of three layers is employed. Radial flow experiment is carried out for the multi-layered preform. A new analytic model for advancement of flow front is proposed and effective permeability is defined. The effective permeability for the multi-layered preform is obtained analytically and compared with experimental results. Compaction test is performed to determine the exact fiber volume traction of each layer in the multi-layered preform. Transverse permeability employed in modeling is measured experimentally unlike the previous studies. Accurate prediction of flow advancement is of great use for saving the processing time and enhancing product properties of the final part.

• Journal of Surface Science and Engineering
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• v.30 no.4
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• pp.248-254
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• 1997

The sulfidation behavior of a sputter-deposited amorphous coating of 69.0%Nb-16.9Ni-11.9%Al-2.2%Si (at.%) has been investigated as a funtion of temperature.(973-1173K) in pure sulfur pressure of 0.01atm. The sulfidation kinetics of the casting obyed the parabolic rate low over the whole temperature ranges studied. The stlfidation rate increased with the temperature, as expected. The sulfide scale, the composition of which was $Al_2S_3,\;NbS_2,\;Ni_{3-x}S_2\;and\;FeCrS_4$, formed on the amorphous coating was primarily bilayered. Both the outer fastgrowing non-protective 4Al_2S_3$scale and the inner slowly-growing protective $NbS_2$,/TEX> scale and the inner slowly-growing protective $NbS_2$ scale had some Fe and Cr dissolution, which evidently came from the base substrate alloy of stainless steel type 304. Belows the coating, Kirkendall void formation was noticed. Nevertheless, a dramatic improvement of sulfidation resistance was achieved by sputter-depositing Nb-2 Ni-Al-Si layer on the stainless steel 304.

• The Korean Journal of Ceramics
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• v.3 no.3
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• pp.163-168
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• 1997

Most of heteroepitaxial $\beta$-SiC thin films have been successfully grown on Si(100) adapting a carburizing process, by which a few atomic layers of substrate surface is chemically converted to very thin SiC layer using hydrocarbon gas sources. Using an organo-silicon precursor, bis-trimethylsilymethane (BTMSM, [$C_7H_{20}Si_2$]), heteropitaxial $\beta$-SiC thin films were successfully grown directy on Si substrate without a carburized buffer layer. The defect density of the $\beta$-SiC thin films deposited without a carburized layer was as low as that of $\beta$-SiC films deposited on carburized buffer layer. In addition, void density was also reduced by the formation of self-buffer layer using BTMSM instead of carburized buffer layer. It seems to be mainly due to the characteristic bonding structure of BTMSM, in which Si-C was bonded alternately and tetrahedrally (SiC$_4$).

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2009.05a
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• pp.306-309
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• 2009

The influence of equal-channel angular pressing (ECAP) route on dynamic deformation behavior of ultra-fine grained Al-4.4%Mg alloys was investigated in this study. The 8-pass ECAPed specimens consisted of ultra-fine grains of $0.5{\mu}m$ in size, and contained the considerable amount of second phase particles, which were fragmented and distributed homogeneously in the matrix. The result of dynamic torsional tests indicated that the maximum shear stress and fracture shear strain were lowest in the specimen deformed by ECAP via route A among the 8-pass ECAPed specimens. The formation of adiabatic shear bands was addressed by concepts of critical shear strain, deformation energy required for void initiation, and microstructural homogeneity related to ECAP routes.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.04a
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• pp.292-296
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• 2004

In case of Resin Transfer Molding(RTM) process, 'race-track' effects and non-uniform fiber volume fraction may cause undesirable resin flow pattern and thus result in dry spots, which affect the mechanical properties of the finished parts. In this study, a real time RTM control strategy to prevent these unfavorable effects is proposed. The control strategy consists of two 'stages' depending on the extent the resin front has reached. Through numerical simulations and experiments, the validity of the proposed scheme is demonstrated. The results show that the proposed scheme is effective in reducing the void formation during RTM mold filling.