Epitaxial Growth of $\beta$-SiC Thin Films on Si(100) Substrate without a Carburized Buffer Layer

  • Wook Bahng (School of Materials Science & Engineering, Seoul National University) ;
  • Kim, Hyeong-Joon (School of Materials Science & Engineering, Seoul National University)
  • Published : 1997.09.01

Abstract

Most of heteroepitaxial $\beta$-SiC thin films have been successfully grown on Si(100) adapting a carburizing process, by which a few atomic layers of substrate surface is chemically converted to very thin SiC layer using hydrocarbon gas sources. Using an organo-silicon precursor, bis-trimethylsilymethane (BTMSM, [$C_7H_{20}Si_2$]), heteropitaxial $\beta$-SiC thin films were successfully grown directy on Si substrate without a carburized buffer layer. The defect density of the $\beta$-SiC thin films deposited without a carburized layer was as low as that of $\beta$-SiC films deposited on carburized buffer layer. In addition, void density was also reduced by the formation of self-buffer layer using BTMSM instead of carburized buffer layer. It seems to be mainly due to the characteristic bonding structure of BTMSM, in which Si-C was bonded alternately and tetrahedrally (SiC$_4$).

Keywords

References

  1. Appl. Phys. Lett. v.42 Production of large-area single-crystal wafers of cubic SiC for semiconductor device S. Nishino;J. A. Powell;H. A. Will
  2. J. Cryst. Growth v.70 Epitaxial growth of β-SiC single crystals by successive two-step CVD A. Suzuki;K. Furukawa;Y. Higashigaki;S. Harada;S. Nakajima;T. Inoguchi
  3. J. Electrochem. Soc. v.132 Epitaxial growth and characterization of β-SiC thin film P. Liaw;R. F. Davis
  4. J. Appl. Phys. v.78 Epitaxial growth of 3C-SiC films on 4 in. diam. (100) silicon wafers by atmospheric pressure chemical vapor deposition C. A. Zorman;A. I. Fleischman;A. S. Dewa;M. Mehregany;C. Jacob;S. Nishino;P. Pirouz
  5. Appl. Phys. Lett. v.49 Epitaxial growth of β-SiC thin films on 6H α-SiC substrates via chemical vapor deposition H. S. Kong;J. T. Glass;R. F. Davis
  6. J. Mater. Res. v.8 Low pressure chemical vapor deposition (LPCVD) of β-SiC on Si(100) using MTS in a hot wall reactor C. C. Chiu;S. B. Desu;C. Y. Tsai
  7. Appl. Phys. Lett. v.63 Growth of crystalline 3C-SiC on Si at reduced temperatures by chemical vapor deposition from silacyclobutane A. L. Steckl;C. Yuan;J. P. Li;M. J. Loboda
  8. J. Electrochem. Soc. v.139 Low-temperature deposition using hexamethyldisilane as a source material K. Takahashi;S. Nishino;J. Saraie
  9. J. Electrochem. Soc. v.142 Influence of H₂addition and growth temperature on CVD of SiC using hexamethyldisilane and Ar N. Nordell;S. Nishino;J. -W. Yang;C. Jacob;P. Pirouz
  10. Appl. Phys. Lett. v.60 Single crystalline, epitaxial cubic films grown on (100) Si at 750℃ by chemical vapor deposition I. Golecki;F. Reidinger;J. Marti
  11. Mater. Sci. Eng. v.B29 Structural and electronic characterization of β-SiC films on Si grown from monomethylsilane precursors G. Krotz;W. Legner;G. Muller;H. W. Grueninger;L. Smith;B. Leese;A. Jones;S. Rushworth
  12. Silicon carbide and related materials 1995. The Proceedigs of the 6th International Conference on Silicon Carbide and Related Materials, Kyoto, Japan Heteroepitaxial growth of β-SiC thin films on Si(100) substrates using a new source material; bis-tirmethylsilylmethane W. Bahng;H. J. Kim;S. Nakashima(ed.);H. Matsunami(ed.);S. Yoshida(ed.);H. Harima(ed.)
  13. Appl. Phys. Lett. v.69 no.26 Heteroepitaxial growth of β-SiC thin films on Si using bis-trimethylsilylmethane W. Bahng;H. J. Kim
  14. Thin Solid Films v.290-291 Epitaxial growth of β-SiC thin films on Si(100) with a polycrystalline buffer layer using bis-trimethylsilylmethane W. Bahng;H. J. Kim
  15. J. Electrochem. Soc. v.127 Chemical vapor deposition of single crystalline betaSiC films on silicon substrate with sputtered SiC intermediated layer S. Nishino;Y. Hazuki;H. Matsunami;T. Tanaka
  16. Appl. Phys. Lett. v.44 Buffer-layer technique for the growth of single crystal SiC on Si A. Addamiano;J. A. Sprague
  17. J. Electrochem. Soc. v.142 Nucleation and void formation mechanisms in SiC thin film growth on Si by carbonization J. P. Li;A. J. Steckl
  18. Appl. Phys. Lett. v.67 Carbonization-induced SiC micropipe formation in crystalline Si R. Scholz;U. Gosele;E. Niemann;D. Leidich
  19. J. Cryst. Growth v.115 Suppression of etch pits and hillock formation on carbonization of Si substrate and low temperature growth of SiC H. Nagasawa;Y. -I. Yamaguchi
  20. J. Cryst. Growth v.78 Surface morphology of cubic SiC(100) on Si(100) by chemical vapor deposition K. Shibahara;S. Nishino;H. Matsunami