• Title/Summary/Keyword: Viscosity Effect

Search Result 1,737, Processing Time 0.026 seconds

High Temperature Gas Leak Behavior of Glass-Ceramic Fiber Composite Seals for SOFC Applications (SOFC용 유리-세라믹섬유 복합기밀재의 고온 기체누설 거동)

  • Lee, Jae-Chun;Kwon, Hyuk-Chon;Kwon, Young-Pil;Park, Sung;Jang, Jin-Sik;Lee, Jongho;Kim, Joosun;Lee, Hae-Won
    • Journal of the Korean Ceramic Society
    • /
    • v.42 no.12 s.283
    • /
    • pp.842-845
    • /
    • 2005
  • Glass composites containing ceramic fiber have been developed for Solid Oxide Fuel Cell (SOFC) seals. Effect of glass type, loading pressure and thermal cycle the leak rates of composite seals was investigated. Seal performance of two commercial glasses was compared with that of $SiO_2BaO-B_2O_3$ glass synthesized in this work. The leak rate for seals made of pyrex(R) increases from $\~0.0005\;to\;\~0.004sccm/cm$ as the gas pressure increases from 10 to 50 kPa. The soda lime silicate glass seal shows the leak rate two times higher than the one made of pyrex(R) or $SiO_2BaO-B_2O_3$ glass. The viscosity of glass at the seal test temperature is presumed to affect the leak rate of the glass seal. As the applied loading pressure increases from 0.4 to 0.8 MPa at $750^{\circ}C$, the leak rate decreases from 0.038 to 0.024 sccm/cm for composite seals. It has been found that during 50 thermal cycles between $450^{\circ}C\;to\;700^{\circ}C$ leak rates remained almost constant, ranging from 0.025 to 0.03sccm/cm. The results showed an excellent thermal cycle stability as well as sealability of the glass matrix ceramic fiber composite seals.

Measurement of Polymer Chain Depletion Layer in the Poly(vinyl alcohol)/Dimethyl Sulfoxide/Polystyrene Latex System by Dynamic Light Scattering (동적 광산란법에 의한 폴리(비닐 알코올)/디메틸설폭사이드/폴리스티렌 라텍스 계에서의 고분자 사슬 배제층 측정)

  • Eom, Hyo-Sang;Park, Il-Hyun
    • Polymer(Korea)
    • /
    • v.36 no.5
    • /
    • pp.628-636
    • /
    • 2012
  • The polymer concentration dependence of depletion layer was investigated by means of dynamic light scattering after the very small amount of polystyrene spherical latex particles was added into the matrix solution of poly(vinyl alcohol)(PVA)/dimethyl sulfoxide. At the dilute regime, the magnitude of depletion layer kept constant at the level of $63{\pm}3%$ of the radius of gyration of the corresponding PVA chain. Next, at the early semi-dilute regime of $1.5{\leq}C[{\eta}]{\leq}3$, polymer concentration dependence of the layer thickness ${\delta}$ was obtained as ${\delta}{\sim}C^{-0.8}$, and this experimental value was very close to theoretical one of -0.75. However it was observed above $C[{\eta}]$ >3 that its thickness decreased abruptly, and this was ascribed to aggregation effect of latex particles which was driven by Oosawa type attractive interaction.

Effect of Working Fluids on the Thermal Behavior of a Bi-directional Solar Thermal Diode (작동유체가 양방향성 태양열 열다이오드의 열성능 변화에 미치는 영향 분석)

  • Ko, Yung-Joo;Lee, Heon-Ju;Chun, Won-Gee;Chen, Kuan;Lim, Sang-Hoon
    • Journal of the Korean Solar Energy Society
    • /
    • v.28 no.1
    • /
    • pp.9-17
    • /
    • 2008
  • An experimental investigation has been carried out to study the effects of different working fluids on the behavior and thermal performance of a hi-directional thermodiode. The thermodiode was made up of two rectangular loops mounted between a collector plate and a radiator plate. Rotatable joints between the horizontal and inclined segments of the loops enable easy alteration of the direction of heat transfer. The loops and the tank were filled with a working fluid for effective heat transfer when the thermodiode was forwarded biased. Six different working fluids were tested with thermal conductivity values ranging from 0.1 to $0.56W/m-^{\circ}C$, thermal expansion coefficient values ranging from $1.8\;{\times}10^{-4}$ to $1.3\;{\times}\;10^{-3}\;K^{-1}$, and kinematic viscosity values ranging from $0.65\;{\times}\;10^{-6}$ to $100\;{\times}\;10^{-6}\;m^2/s$. Especially, mixtures of $Al_2O_3$ (30nm Particle) in deionized water have been tested for the volumetric ratios of 0.01, 0.02, 0.03, 0.1, 0.2%. Each experiment was carried out after the loop was filled with a working fluid for effective heat transfer and the thermodiode was forwarded biased. The solar thermodiode was heated by a radiant heater consisting of 20 halogen lamps that generated a heat flux of about $1000\;W/m^2$ on the collector surface. Results are given in terms of temperature development in different parts of the loop as heat is delivered from its hot end to the surrounding atmosphere by the radiator made of copper plates.

Selection of Capillary Tubes for HCFC-22 Alternative Fluids (HCFC-22 대체냉매의 모세관 선정)

  • Jung, D.S.;Kim, C.B.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.7 no.3
    • /
    • pp.435-449
    • /
    • 1995
  • In this paper, pressure drop through a capillary tube is modeled to determine the length of a capillary tube for a given set of conditions. HCFC-22 and its alternatives, HFC-134a, R407B, and R410A are used as working fluids. The conditions on which the model is tested are as follows : condensing temperature; 40.0, 45.0, 50.0, $55.0^{\circ}C$, degree of subcooling;0.0, 2.5, $5.0^{\circ}C$, capillary tube exit condition;choked flow, capillary tube diameter;1.2~2.4mm, mass flow rate;5.0~50.0g/sec. The results justify the use of Stoecker's model which yields the results very close to the values in ASHRAE handbook. While McAdams' method yields much better results than Duckler's in calculating the viscosity of the fluid in 2-phase, the friction factor suggested by Stoecker seems to be the best for capillary tubes of large diameter used in residential air conditioners. For each refrigerant, 372 data with various variables are calculated by the model. The results show that capillary tube length varies very uniformly with changes in condensing temperature and degree of subcooling. Based on this fact, regression analysis is performed to determine the dependence of mass flow rate on the length and diameter of a capillary tube, condensing temperature, and degree of subcooling. Thus determined correlation yields a mean deviation of 2.36% for 1,488 data, showing an excellent agreement.

  • PDF

The Study of Physical Properties for the Organic Compounds and their Binary Mixture according to Molecular Connectivity Method (Molecular Connectivity法을 이용한 有機化合物과 二成分 混合物에 對한 物理化學的 性質에 關한 硏究 (Ⅱ))

  • Ui-Rak Kim;Kyung-Sub Min;Myung-Jae Lee;Sang-Hae Kim;Bong-Jin Jeong
    • Journal of the Korean Chemical Society
    • /
    • v.36 no.4
    • /
    • pp.485-495
    • /
    • 1992
  • The viscosities of organic compounds (alcohols, acetates, alkanes, acids, substituted $NH_2$) in liquid states, gas states and the binary mixtures of n-alkane / 1-chloroalkane were calculated by molecular modeling techniques. The molecular descriptors of molecular modeling technique are Molecular connectivity indices, Wiener indices and ad hoc descriptors, which can encode the information of compound properties about the effect of size, branching, cyclization, unsaturation, heteroatom content, polarizability, and so on. The successful results among method have been Molecular connectivity indices, binary mixtures of n-alkane / 1-chloroalkane, Wiener indices for gas state and ad hoc descriptor for liquid states. Also we obtained the regression equations for viscosities using molecular modeling indices for gas, liquid states and binary mixtures of n-alkane / 1-chloroalkane. The calculated viscosity values for organic compounds are in good agreement with experimental results.

  • PDF

A Study on Drag Reduction Agency for Gas Pipeline

  • Zhang Qibin;Fan Yunpeng;Lin Zhu;Zhang Li;Xu Cuizhu;Han Wenli
    • Corrosion Science and Technology
    • /
    • v.7 no.5
    • /
    • pp.283-287
    • /
    • 2008
  • The drag reduction agency (DRA) for gas pipeline, a novel method used for reducing friction or drag on a gas flowing to increase the transmission efficiency of gas pipeline, is a more flexible and economical technology than internal flow efficient coatings. In this paper, an effective DRA has been developed in Authors' Institute by analyzing the hydrodynamic friction resistance on internal gas pipeline and then studying the work mechanism and molecular structure of DRA. In the meantime, a group of property test for selecting DRA material has been determined, including viscosity, contact angle, volatility, corrosion, slab extending, and flow behavior in horizontal tube. The inhibition efficiency and drag reduction efficiency of the developed DRA have been investigated finally based on the relevant test methods. Results of corrosion test show that the developed DRA has very good inhibition effect on mild steel by brushing a thin layer of DRA on steel specimens, giving inhibition efficiency of 91.2% and 73.1% in 3%NaCl solution and standard salt fog environment respectively. Results of drag-reducing test also show that the Colebrook formula could be used to calculate friction factors on internal pipes with DRA as the Reynolds number is in the range of $0.75\times10^5\sim2.0\times10^5$. By comparing with normal industrial pipes, the friction resistance coefficient of the steel pipe with DRA on internal wall decreases by 13% and the gas flux increases by 7.3% in testing condition with Reynolds number of $2.0\times10^5$.

Comparative Study on Viscous and Inviscid Analysis of Partial Cavitating Flow for Low Noise Propeller Design (저소음 프로펠러 설계를 위한 부분공동 유동의 점성 및 비점성 수치해석 비교 연구)

  • Kim, Ji-Hye;Ahn, Byoung-Kwon;Park, Cheol-Soo;Kim, Gun-Do
    • The Journal of the Acoustical Society of Korea
    • /
    • v.33 no.6
    • /
    • pp.358-365
    • /
    • 2014
  • When a ship propeller having wing type sections rotates at high speed underwater, local pressure on the blade decreases and various types of the cavitation inevitably occur where the local pressure falls below the vapor pressure. Fundamentally characteristics of the cavitation are determined by the shapes of the blade section and their operating conditions. Underwater noise radiated from a ship propeller is directly connected to the occurrence of the cavitation. In order to design low noise propeller, it is preferentially demanded to figure out key features: how the cavity is generated, developed and collapsed and how the effect of viscosity works in the process. In this study, we first perform inviscid analysis of the partial cavity generated on two dimensional hydrofoil. Secondly, viscous analysis using FLUENT with different turbulence and cavitation models are presented. Results from both approaches are also compared and estimated.

Effect of NBR Component on Adhesion Behaviors between NBR and Metal Joints Using Phenol Adhesive (페놀 수지를 이용한 NBR/냉연강판 접착계에 미치는 NBR 조성의 효과)

  • Lee, Dong-Won;Park, Hae-Youn;Yu, Young-Jae;Kang, Dong-Gug;Seo, Kwan-Ho
    • Polymer(Korea)
    • /
    • v.32 no.1
    • /
    • pp.1-6
    • /
    • 2008
  • The adhesion behaviors and processability of NBR as a sealing material were investigated. In order to find the optimum formulation, the adhesive properties and processability were observed as the change of the contents of acrylonitrile (ACN) in NBR. Effects of Mooney viscosity, filler, plasticizer and crosslinking agent on the adhesion behaviors were also studied. The contents of ACN in NBR have great effects on adhesion behaviors and processability in NBR sealing. To know the optimum condition of roll mixing, degree of dispersion was investigated. It was confirmed that degree of dispersion was influenced by various factors such as mixing order, time, and temperature. The crosslinking system was studied as the observation of sulfur system, peroxide system, crosslinking density, and structure. From the variation of the dry condition and hexamine contents, the relation between adhesive and NBR was studied. These results show the adhesion properties and processability are dependent on the contents of ACN and crosslinking system.

Effect of Acid Treatment Process on the Physicochemical Properties of Gelatin Extracted from Pork Skin (산처리 공정에 따라 추출한 돈피 젤라틴의 이화학적 특성에 관한 연구)

  • Yeom Geun-Woong;J Andrieu;Min Sang-Gi
    • Food Science of Animal Resources
    • /
    • v.24 no.3
    • /
    • pp.266-272
    • /
    • 2004
  • The objective of this study was to investigate the physicochemical characteristics of gelatin extracted from pork skin under soaking in various acid solutions (lactic acid, acetic acid, and citric acid). Gelatin sol was extracted at 8$0^{\circ}C$, frozen at -2$0^{\circ}C$ and lyophilized it for 3 days to be completely dried in freeze drying unit. In the evaluation of gelatin quality, gelatin soaked in citric acid showed higher L- and a-values than those of any other gelatin (p<0.05). Gelatin treated by acetic acid showed the highest gel strength, cohesiveness, and brittleness. The content of hydroxyproline amino acid in gelatin treated by acetic acid was larger than one of gelatin treated in lactic and citric acid in order. From the experimental results, the highest quality of gelatin in all of period, which was soaked in acetic acid and lactic acid, has a more good quality than gelatin soaked in citric acid.

Effect of Gaeddongssuk (Artemisia annua L.) Powder on Quality and Shelf Stability of Emulsion Sausages during Refrigerated Storage

  • Ham, Hyoung-Joo;Kang, Geun-Ho;Choi, Yun-Sang;Jeong, Tae-Jun;Hwang, Ko-Eun;Kim, Cheon-Jei
    • Food Science of Animal Resources
    • /
    • v.36 no.5
    • /
    • pp.601-611
    • /
    • 2016
  • The objective of this study was to evaluate effects of Gaeddongssuk powder (GP) on quality characteristics and shelf stability of emulsion sausages during storage. Proximate composition properties showed no significant differences in all treatment (p>0.05). Control showed the highest cooking loss while the treatment with GP showed decreased cooking loss depending on increasing GP content (p<0.05). Apparent viscosity of batter was increased as the amount of GP increased, whereas hardness of emulsion sausages was decreased with increasing GP level. In sensory evaluation, emulsion sausage with 0.1% GP resulted in the highest score in overall acceptability. The pH values of all treatments decreased at the early storage stage, followed by gradual increase. The lightness and redness of treatments were decreased when the level of GP was increased. However, the yellowness of sausages with GP were higher than that of control (p<0.05). The addition of GP inhibited lipid oxidation of emulsion sausages during storage depending on its level. The aerobic bacteria population and VBN was unaffected by addition of GP during the storage (p>0.05). Therefore, Gaeddongssuk powder up to 0.1% has a potential as a natural antioxidant for meat products because it can inhibit lipid oxidation of sausages without decreasing their sensory properties.