• 유변학
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• 제10권3호
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• pp.137-142
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• 1998

유변물성 자료로부터 고분자의 다분산성을 예측하는 방법은 신속한 중합반응 공정 제어를 위해서 중요한 연구분야중 하나이다. 본 연구에서는 다양한 분자량과 분자량 분포를 가진 폴리에틸렌에 대한 Shroff와 macridis 가 제시한 다분산성 매개변수 ER과 ET를 구하 고 겔투과 크로마토그래피에서 얻은 Mw/Mn과의 상관관계를 조상하였다. Mw/Mn과 비례적 인 상관관계를 보여주었으나 ET는 상관성이 없는 것으로 나타났다. ER값에는 분자량 분포 도 외에 LCB의영향도 큰 것으로 나타났다. 또한 분자량 분포중에서 고분자량 부분의 미미 한 변화에도 ER이 크게 변해 GPC보다 다분산성의 변화를 더 민감하게 예측할수 있음을 알 수있었다.

• 유변학
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• 제10권3호
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• pp.160-164
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• 1998

본 연구에서 Doi-Edwards 점탄성 조성방정식의 Hadamard 안정성 분석을 행하였 다. Hadamard 안정성은 방정식의 탄성 성질과 연관되는 특성으로 파장이 짧고 진동수가 큰 파동에 의한 외란 하에서 식의 안정성을 의미한다. 먼저 안정성을 위한 일반 3차원 조건을 수립하고 단순한 1차원과 2차원 외란하에서 필요조건을 구하였다. Doi-Edwards 이론을 따 르는 물질의 단순전단유동을 고려함에 의하여 순간 전단변형률이 1.8786을 넘어설 때 파장 이 짧고 진동수가 큰 외란에 의하여 불안정성이 나타남이 증명되었다. 이 안정성의 임계치 는 실제 고분자공정 뿐 아니라 실험실에서도 쉽게 도달할수 있는 값으로 이와 같은 불안정 유동은 mi-crophase separation과 같은 물리적 현상과는 관련이 있다는 증거가 없으므로 조 성방정식 자체가 지니는 수학적 모순점에 기인한 것이라 할수 있다.

• Journal of the Korean Wood Science and Technology
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• 제12권4호
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• pp.3-10
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• 1984

In hot pressed wood of Pseudotsuga menziesii compressed to 0 - 50 percent at temperature 60 - $180^{\circ}C$, relative humidity conditions affecting dynamic Young's modulus of elasticity and internal friction were investigated. The results obtained are summarized as follows: Moisture absorption of the hot pressed wood decreased with increasing press temperature, but there was no effect on the amount of compression. Thickness swelling dereased with increasing press temperature, and increased with increasing amount of compression. In general, dynamic Young's modulus of elasticity showed a straight line with increasing specific gravity of specimens. Dynamic Young's modulus of elasticity decreased with increasing moisture content, but internal friction increased with increasing amount of moisture content. Dynamic Young's modulus of R specimens pressed in the radial direction showed hight values than T specimens pressed in the tangential direction.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2008년도 추계학술발표논문집
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• pp.107-122
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• 2008

종이의 도공액이 고농도화 됨에 따라 도공액의 유동학적 특성에 대한 연구가 더욱 더 중요시 되고 있다. 기존의 합성 증점제의 경우는 단순히 증점 보수제의 기능을 가지고 있으므로 고농도/고속 도공시 블레이드하에서 점탄성적인 성질 중 팽윤에 의한 탄성의 성질이 더 강하게 남아있게 되어 다양한 도공 트러블의 원인이 될 수 있다. 최근에는 이러한 단점을 개선하기 위한 표면 흡착형 유동성 조절제가 소개되고 있다. 따라서 본 연구에서는 알카리 팽윤형 합성 증점제와 표면 흡착형 유동성 개량제로 업계에 알려진 2종의 유동성 조절제가 고농도 도공액의 점탄성적인 유동특성에 미치는 영향성을 검토하였고, PDA(Penetration Dynamic Analyzer) 모듈을 이용하여 원지에 흡수되는 흡수 거동을 관찰하였다.

• Macromolecular Research
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• 제15권2호
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• pp.109-113
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• 2007

The surface molecular motion of monodisperse polystyrene (PS) films was examined using scanning vis-coelasticity microscopy (SVM) in conjunction with lateral force microscopy (LFM). The dynamic storage modulus, E', and loss tangent, $tan\delta$, at a PS film surface with number-average molecular weights, $M_n$, smaller than 30 k were found to be smaller and larger than those for the bulk sample, even at room temperature, meaning that the PS surface is in a glass-rubber transition or fully rubbery sate at this temperature when the $M_n$ is small. In order to quantitatively elucidate the dynamics of the molecular motion at the PS surface, SVM and LFM measurements were performed at various temperatures. The glass transition temperature, $T_g$, at the surface was found to be markedly lower than the bulk $T_g$, and this discrepancy between the surface and bulk became larger with decreasing $M_n$. Such an intensive activation of the thermal molecular motion at the PS surfaces can be explained in terms of an excess free volume in the vicinity of the film surface induced by the preferential segregation of the chain end groups.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2003년도 춘계학술대회논문집
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• pp.495-500
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• 2003

The vibration of a flexible cantilever tube with nonlinear constraints when it is subjected to flow internally with fluids is examined by experiment and theoretical analysis. These kind of studies have often been performed that finds the existence of chaotic motion. In this paper, the important parameters of the system leading to such a chaotic motion such as Young's modulus and coefficient of viscoelasticity in tube material are discussed. The parameters are investigated by means of a system identification so that comparisons are made between numerical analysis using the parameters of a handbook and the experimental results. The chaotic region led by several period-doubling bifurcations beyond the Hopf bifurcation is also re-established with phase portraits and bifurcation diagram so that one can define optimal parameters for system design.

• 한국전산유체공학회지
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• 제14권4호
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• pp.101-108
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• 2009

We present a new finite-element scheme for direct numerical simulation of particle suspensions in simple shear flow of a viscoelastic fluid in 3D. The sliding tri-periodic representative cell concept has been combined with DEVSS/DG finite element scheme by introducing constraint equations along the domain boundary. Rigid body motion of the freely suspended particle is described by the rigid-shell description and implemented by Lagrangian multipliers on particle boundaries. We present the bulk rheology of suspensions through the numerical examples of single-, two- and many-particle problems, which represent a large number of such systems in simple shear flow. We report the steady bulk viscosity and the first normal stress coefficient, which show shear-thickening behavior for both properties.

• Steel and Composite Structures
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• 제18권5호
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• pp.1161-1176
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• 2015

The connection between a column and a beam is of particular importance to ensure the safety of civil engineering structures, such as high-rise buildings and bridges. While the connector must bear sufficient force for load transmission, increase of its ductility, toughness and damping may greatly enhance the overall safety of the structures. In this work, a composite beam-column connector is proposed and analyzed with the finite element method, including effects of elasticity, linear viscoelasticity, plasticity, as well as geometric nonlinearity. The composite connector consists of three parts: (1) soft steel; (2) polymer; and (3) conventional steel to be connected to beam and column. It is found that even in the linear range, the energy dissipation capacity of the composite connector is largely enhanced by the polymer material. Since the soft steel exhibits low yield stress and high ductility, hence under large deformation the soft steel has the plastic deformation to give rise to unique energy dissipation. With suitable geometric design, the connector may be tuned to exhibit different strengths and energy dissipation capabilities for real-world applications.

• 대한기계학회논문집A
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• 제27권9호
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• pp.1579-1588
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• 2003

In this paper, the finite element equations for the transient linear viscoelastic stress analysis are presented in time domain, whose variational formulation is derived by using the Galerkin's method based on the equations of motion in time integral. Since the inertia terms are not included in the variational formulation, the time integration schemes such as the Newmark's method widely used in the classical dynamic analysis based on the equations of motion in time differential are not required in the development of that formulation, resulting in a computationally simple and stable numerical algorithm. The viscoelastic material is assumed to behave as a standard linear solid in shear and an elastic solid in dilatation. To show the validity of the presented method, two numerical examples are solved nuder plane strain and plane stress conditions and good results are obtained.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.474-478
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• 2004

A bushing is a device used in automotive suspension systems to reduce the load transmitted from the wheel to the frame of the vehicle. A bushing is a hollow cylinder, which is bonded to a solid steel shaft at its inner surface and a steel sleeve at its outer surface. The relation between the force applied to the shaft and the relative deformation of a bushing is nonlinear and exhibits features of viscoelasticity. A force-displacement relation for bushings is important for multibody dynamics numerical simulations. For the nonlinear viscoelastic axial response, Pipkin-Rogers model, the direct relation of force and displacement, has been derived from Lianis model and the sinusoidal input was used for Pipkin-Rogers model, and the affection of displacement with frequency change was studied with Pipkin-Rogers model.