• Journal of Pharmaceutical Investigation
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• 제39권3호
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• pp.185-199
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• 2009

Using a strain-controlled rheometer [Advanced Rheometric Expansion System (ARES)], the steady shear flow properties and the dynamic viscoelastic properties of $Antiphlamine-S^{(R)}$ lotion have been measured at $20^{\circ}C$ (storage temperature) and $37^{\circ}C$ (body temperature). In this article, the temperature dependence of the linear viscoelastic behavior was firstly reported from the experimental data obtained from a temperature-sweep test. The steady shear flow behavior was secondly reported and then the effect of shear rate on this behavior was discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters. The angular frequency dependence of the linear viscoelastic behavior was nextly explained and quantitatively predicted using a fractional derivative model. Finally, the strain amplitude dependence of the dynamic viscoelastic behavior was discussed in full to elucidate a nonlinear rheological behavior in large amplitude oscillatory shear flow fields. Main findings obtained from this study can be summarized as follows : (1) The linear viscoelastic behavior is almostly independent of temperature over a temperature range of $15{\sim}40^{circ}C$. (2) The steady shear viscosity is sharply decreased as an increase in shear rate, demonstrating a pronounced Non-Newtonian shear-thinning flow behavior. (3) The shear stress tends to approach a limiting constant value as a decrease in shear rate, exhibiting an existence of a yield stress. (4) The Herschel-Bulkley, Mizrahi-Berk and Heinz-Casson models are all applicable and have an equivalent validity to quantitatively describe the steady shear flow behavior of $Antiphlamine-S^{(R)}$ lotion whereas both the Bingham and Casson models do not give a good applicability. (5) In small amplitude oscillatory shear flow fields, the storage modulus is always greater than the loss modulus over an entire range of angular frequencies tested and both moduli show a slight dependence on angular frequency. This means that the linear viscoelastic behavior of $Antiphlamine-S^{(R)}$ lotion is dominated by an elastic nature rather than a viscous feature and that a gel-like structure is present in this system. (6) In large amplitude oscillatory shear flow fields, the storage modulus shows a nonlinear strain-thinning behavior at strain amplitude range larger than 10 % while the loss modulus exhibits a weak strain-overshoot behavior up to a strain amplitude of 50 % beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (7) At sufficiently large strain amplitude range (${\gamma}_0$>100 %), the loss modulus is found to be greater than the storage modulus, indicating that a viscous property becomes superior to an elastic character in large shear deformations.

• 한국식품과학회지
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• 제15권2호
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• pp.183-188
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• 1983

한국 재래식 국수류인 밀국수와 냉면국수의 점탄성을 연구하기 위하여 실험실에서 tensile시험기계를 만들고 이것을 이용하여 국수발에 대한 creep test를 실시하였다. 밀국수 및 냉면국수 모두 최초 단시간의 creep에서는 선형점탄성(linear viscoelastic)을 나타내었으나 creep시간이 경과함에 따라 비선형 점탄성을 나타내었다. 변형력 범위가 $4{\times}10^4-14{\times}10^4\;dyn\;cm^{-2}$일때 밀국수는 120초간, 냉면국수는 60초간 선형 점탄성을 나타내었다. 2000초 동안의 creep시험에서 추산된 밀국수의 탄성계수(elastic modulus)는 $7.0{\times}10^5\;dyn\;cm^{-2}$이었으며 냉면국수는 $3.9{\times}10^5\;dyn\;cm^{-2}$이었다. 변형력의 증가에 따른 점성변화를 평가한 결과 밀가루 반죽에서 보고된 결과와는 정반대 현상인 stress-hardening 성질을 나타내었다.

• Journal of Biosystems Engineering
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• 제17권1호
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• pp.79-90
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• 1992

Viscoelastic characteristics of agricultural products may be determined through three basic tests ; stress relaxation, creep, and dynamic test. Considering the changeability of living materials, dynamic test in which information is derived in a relatively short time appears to be highly desirable, in which either cyclic stress or cyclic strain is imposed and the remaining quantity (strain or stress) is measured. The periodically varying stress will also result in periodically varying strain which in a viscoelastic material should theoretically be out of phase with the stress, because part of the energy subjected to sample is stored in the material as potential energy and part is dissipated as heat. This behavior results in a complex frequency-dependent compliance denoted by J($i{\omega}$). The complex compliance and therefore the storage compliance, the loss compliance, the phase angle, and percent energy loss for the sample should be obtainable with a given static viscoelastic property of the material under static load. The complex compliance of the rough rice kernel were computed from the Burger's model describing creep behavior of the material which were obtained in the previous study. Also, the effects of cyclic load and moisture content of grain on the dynamic viscoelastic behavior of the samples were analyized. The results obtained from this study were summarized as follows ; 1. The storage compliance of the rough rice kernel slightly decreased with the frequency applied but at above the frequency of 0.1 Hz it was nearly constant with the frequency, and the loss compliance of the sample very rapidly decreased with increase in the frequency on those frequency ranges. 2. It was shown that the storage compliance and the loss compliance of the sample increased with increase in grain moisture content. Effect of grain moisture content on the storage compliance of the sample was highly significant than effect of the frequency applied, but effect of the frequency on the loss compliance of the sample was more significant than effect of grain moisture content. 3. In low moisture content, the percent energy loss of Japonica-type rough rice was much higher than that of Indica-type rough rice, but, in high moisture content, vice versa.

• 폴리머
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• 제29권4호
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• pp.375-379
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• 2005

생분해성 고분자인 poly(L-lactic acid) (PLLA)에 판상구조의 몬모릴로나이트(montmorillonite, MMT)를 첨가하여 필름형태의 나노복합재료를 제조하고, 무기나노입자의 첨가유무와 가수분해 전후의 열적 특성, 점탄성 특성, 모폴로지 등을 조사하였다. PLLA/MMT 나노복합재료의 XRD 분석결과와 TEM 사진으로부터 MMT 입자가 PLLA에 박리 및 분산되어 있음을 확인하였으며, 가수분해가 진행됨에 따라 U 결정 영역의 상대적인 양이 증가하므로 용융에너지 (${\Delta}H_m$가 더 필요함을 알 수 있었다. MMT를 첨가한 경우에 MMT가 강화제 역할을 하기 때문에 저장탄성률이 더 높은 값을 가졌는데, 이는 PLLA를 나노복합화하였을 때 인장강도, 충격강도 등의 기계적 물성이 증가한다는 이전의 연구와도 잘 일치하였다. 또한. 가수분해 전/후의 SEM사진으로부터, 표면에 스피노달(spinodal) 분해에 의한 거칠고 원형의 구멍들이 생겼음을 관찰할 수 있었으며, 가수분해가 진행됨에 따라 나노복합재료는 원형의 구멍들의 크기가 가수분해전보다 더 커졌을 뿐 원래의 형상을 유지하였다. 본 연구를 통하여 PLLA/MMT나노복합재료의 생분해 속도와 열적, 기계적 특성의 조절 가능성을 제시하였다.

• 마이크로전자및패키징학회지
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• 제31권2호
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• pp.23-27
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• 2024

본 연구에서는 인쇄 회로 기판(printed circuit board; PCB) 내 prepreg의 점탄성 특성에 따라 발생하는 time-dependent warpage 거동 양상을 유한요소해석 시뮬레이션을 통해 분석하였다. 응력 완화 시험(stress relaxation test)을 통해 prepreg의 정확한 점탄성 물성을 측정하였으며, 이를 시뮬레이션에 반영하여 warpage 분석을 진행하였다. PCB에 반복적인 열 사이클이 가해지는 상황에서 prepreg의 탄성 특성만을 반영한 경우에는 PCB의 warpage가 초기 상태로 원복되었지만, prepreg의 점탄성 특성까지 반영하였을 때는 그 warpage가 원복되지 못하고 영구적인 warpage 변화가 발생함을 확인하였다. 각기 다른 3개 종류의 prepreg 원자재에 대한 warpage 해석을 진행하여 그 기계적 신뢰성을 비교 분석하였으며, 그 결과 탄성 특성이 점탄성 특성보다 우세한 재료일수록 warpage가 더욱 적게 발생하여 기계적 신뢰성이 우수하였다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2002년도 금형가공 심포지엄
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• pp.125-131
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• 2002

Surface defects in injection molded parts are due to the unsteady flow of polymer melt which are related to the geometries of cavity and gate, the operational conditions of injection and the rheological properties of polymer. In this study we have examined jetting phenomena in injection molding process for three kinds of PCs which have different molecular weight and structure, PBT and PC/ABS alloy with several injection speeds. We have used various cavity shapes that are tensile, flexural and impact test specimens with various gate and cavity thicknesses. Through this study we have observed that the formation of surface defect associated with jetting during filling stage in injection molding is strongly related to die swell. This means that the jetting is strongly affected by the elastic property rather than the viscous property in viscoelastic characteristics of molten polymer. Large die swell would eliminate jetting however, the retardation of die swell would stimulate jetting. In the point of mold design, reducing the thickness ratio of cavity to gate can reduce or eliminate jetting and associated surface defects regardless of magnitude of elastic property. It also enlarges process window that can produce steady flow of polymer melt in injection molding.

• 폴리머
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• 제34권3호
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• pp.226-236
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• 2010

UV조사에 의한 공중합반응을 통해 PDP의 방열패드용 무용제형 아크릴계 점착제를 제조하고 이때 도입되는 공단량체의 곁사슬의 화학적 구조와 가교제의 종류에 따른 점착제의 젖음성을 온도별로 조사하였다. 또한, 동일 조건에서 점착제의 초기 접착력 및 박리강도와 주파수 변화에 따른 점착제의 점탄성 거동 간의 상관관계를 확인하였다. 공단량체의 곁사슬의 길이가 짧을수록 넓은 온도범위에서 우수한 젖음성과 점착 물성을 보였으며 경화제로는 di(ethylene glycol) dimethylacrylate(DEGDMA)를 사용한 계가 우수한 박리 에너지를 보였는데, 이것은 유리전이온도와 점탄성거동의 차이에 기인하는 것으로 판단된다.

• Elastomers and Composites
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• 제45권2호
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• pp.129-136
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• 2010

본 연구는 이축 압출기를 사용하여 생분해성 고분자인 Poly-L-lactic acid(PLLA)와 충격보강제로 Poly (ethylene-co-glycidyl methacrylate)(EGMA)와 Engage를 각각 PLLA에 대해 100/0, 75/25, 50/50, 25/75, 0/100의 조성으로 블렌드를 제조하였고, 3개의 PLLA/EGMA 블렌드에는 탈크를 첨가하였다. 이를 DMA, FESEM, UTM, Izod 충격시험기를 사용하여 PLLA 블렌드의 모폴로지와 점탄성, 기계적 특성을 측정하였다. DMA와 충격시험기의 측정결과 EGMA와 Engage의 함량이 증가함에 따라 상온에서의 저장탄성률이 감소하였고, 충격강도는 증가하였다. 한편 탈크가 첨가되면 저장탄성률은 증가하고 충격강도는 감소하였다. FESEM 분석으로부터, 매트릭스에 도메인이 잘 분산되어 있음을 알 수 있었고, UTM을 통하여 EGMA와 Engage의 함량이 증가하면 굴곡탄성률과 인장강도가 감소되지만, 탈크를 첨가함으로써 이를 보완할 수 있었다.

• 한국전문물리치료학회지
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• 제28권1호
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• pp.65-71
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• 2021

Background: The hamstring is a muscle that crosses two joints, that is the hip and knee, and its flexibility is an important indicator of physical health in its role in many activities of daily living such as sitting, walking, and running. Limited range of motion (ROM) due to hamstring tightness is strongly related to back pain and malfunction of the hip joint. High-frequency diathermy (HFD) therapy is known to be effective in relaxing the muscle and increasing ROM. Objects: To investigate the effects of HFD on active knee extension ROM and hamstring tone and stiffness in participants with hamstring tightness. Methods: Twenty-four participants with hamstring tightness were recruited, and the operational definition of hamstring tightness in this study was active knee extension ROM of below 160° at 90° hip flexion in the supine position. HFD was applied to the hamstring for 15 minutes using the WINBACK device. All participants were examined before and after the intervention, and the results were analyzed using a paired t-test. The outcome measures included knee extension ROM, the viscoelastic property of the hamstring, and peak torque for passive knee extension. Results: The active knee extension ROM significantly increased from 138.8° ± 9.9° (mean ± standard deviation) to 143.9° ± 10.4° after the intervention (p < 0.05), while viscoelastic property of the hamstring significantly decreased (p < 0.05). Also, the peak torque for knee extension significantly decreased (p < 0.05). Conclusion: Application of HFD for 15 minutes to tight hamstrings immediately improves the active ROM and reduces the tone, stiffness, and elasticity of the muscle. However, further experiments are required to examine the long-term effects of HFD on hamstring tightness including pain reduction, postural improvement around the pelvis and lower extremities, and enhanced functional movement.

• 한국산학기술학회논문지
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• 제13권12호
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• pp.5689-5695
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• 2012

본 연구에서는 차량에 적용되는 시트 재질인 폴리우레탄 폼의 점탄성 특성을 고려하여 시트와 인체의 진동특성을 시험 및 수치해석 방법을 이용하여 분석하였다. 압축 시험을 통해 폴리우레탄 폼의 점탄성 특성인 비선형성과 준-정역학적 특성을 구하였다. 또한 컨벌루션 적분법 및 비선형 강성 모델을 이용하여 폴리우레탄 폼의 점탄성 특성을 수학적으로 모델링하였다. 시트의 승차감 기여도를 분석하기 위하여 시트의 동역학 모델과 ISO5982의 표준 인체 수직진동 모델을 이용하여 수직 진동모델을 구성하고 관련 운동방정식을 유도하였다. 비선형 운동방정식은 Runge-Kutta 적분법을 이용하여 수치해석 시뮬레이션을 수행하였다. 철도차량의 차체 바닥에서 측정한 진동가속도 입력에 대한 시트와 인체의 응답 특성을 분석하고 시트 설계 파라미터에 대한 승차감 지수 값들의 변화를 분석하여 시트 설계에 대한 방법론을 제시하고자 한다.