• Korea-Australia Rheology Journal
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• v.20 no.4
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• pp.235-243
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• 2008

The aim of this study is to explore the possibility of incorporating supercritical carbon dioxide ($scCO_2$) into twin screw extrusion process for the production of polypropylene-clay nanocomposite (PPCN). The $CO_2$ is used as a reversible plasticizer which is expected to rapidly transport polymeric chains into the galleries of clay layers in its supercritical condition inside the extruder barrel and to expand the gallery spacings in its sub-critical state upon emerging from die. The structure and properties of the resulting PPCNs are characterized using wide-angle X-ray diffraction (WAXD), transmission electron microscopy (TEM), rheometry, thermogravimetry and mechanical testing. In the processing of the PPCNs with $scCO_2$, optimum $scCO_2$ concentration and screw speed which maximized the degree of intercalation of clay layers were observed. The WAXD result reveals that the PP/PP-g-MA/clay system treated with $scCO_2$ has more exfoliated structure than that without $scCO_2$ treatment, which is supported by TEM result. $scCO_2$ processing enhanced the thermal stability of PPCN hybrids. From the measurement of linear viscoelastic property, a solid-like behavior at low frequency was observed for the PPCNs with high concentration of PP-g-MA. The use of $scCO_2$ generally increased Young's modulus and tensile strength of PPCN hybrids.

• International Journal of Highway Engineering
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• v.15 no.4
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• pp.117-125
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• 2013

PURPOSES : The purpose of this study is to evaluate of field application and laboratory performance of warm-mix asphalt (WMA) according to the dosage rate of organic-based WMA additive. METHODS: Three asphalt mixtures, i.e., hot mix asphalt (HMA), WMA with the dosage rate of 1.5%, WMA with the dosage rate of 1.0%, were sampled from the asphalt plant when the field trial project were constructed. With these mixtures, the laboratory testings were performed to evaluate the linear viscoelastic characteristics and the resistance to moisture, rutting and fatigue damage. RESULTS : From the laboratory test results, it was found that the WMA with the reduced dosage rate of additive would be comparable to HMA and WMA with the original dosage rate in terms of the dynamic modulus, tensile strength ratio, rutting resistance. However, the fatigue reisistance of WMA with the reduced dosage rate was slightly worse but it should be noted that the fatigue performance is necessarily predicted by combining the material properties and pavement structure. CONCLUSIONS: Through the field construction and laboratory testings, the dosage rate of organic-based WMA additive could be reduced from 1.5% to 1.0% without the significant decrease of compactability and laboratory performance. The long-term performance of the constructed pavement will be periodically monitored to support the findings from this study.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.34-37
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• 2000

The effect of novel N-crotyl-N,N-dimethyl-4-methylanilinium hexafluroantimonate (CMH) curing agent on cure behavior and thermal properties of DGEBA epoxy cationic system was investigated. From DSC measurements of DGEBA/CMH system, it was shown that this system exhibits an excellent thermal latent characteristic in a given temperature and reveals complex cure behavior as indicated by multiple exotherms. The conversion and conversion rate of DGEBA/CMH system increased with increasing the concentration of initiator due to high activity of CMH. Viscoelastic properties during gel formation of DGEBA with CMH were investigated by rheological techniques under isothermal condition. The gel time obtained from the modulus crossover. point t(G')=G", was affected by high curing temperature and concentration of CMH, resulting in high degree of network formation in cationic polymerization. The thermal stabilities were discussed in terms of the activation energy for decomposition and thermal factors determined from TGA measurements.ents.

• Journal of the Semiconductor & Display Technology
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• v.18 no.3
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• pp.52-59
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• 2019

Styrene-butadiene rubber (SBR) composites, incorporated with graphene, molybdenum disulfide and their hybrid in different filling ratio, were fabricated by a two roll-mill. The dispersion states of all the samples' matrix were employed by carbon black dispersion tester. The curing properties of the pre-vulcanized rubber composites were investigated, after molding by heating press machine, the tensile strength, storage modulus, friction coefficient, the swelling property had also been tested according to ASTM. The composite G1M10 (filling with 1 phr graphene and 10 phr molybdenum) showed the best mechanical properties and viscoelastic properties in this research with a better filler dispersion state and more compact matrix structure.

• Food Science and Biotechnology
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• v.16 no.1
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• pp.146-149
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• 2007

Dynamic rheological properties of hot pepper-soybean paste (HPSP) mixed with xanthan gum were evaluated at different gum concentrations (0.3, 0.6, and 0.9%) and fermentation times (12 and 24 week). Magnitudes of storage (G') and loss moduli (G") in the HPSP-xanthan gum mixture systems increased with an increase in frequency ($\omega$), while complex viscosity (${\eta}^*$) decreased. G' values were higher than the G" values over most of the frequency range (0.63-63 rad/sec), and were frequency-dependent. The dynamic moduli (G', G", and ${\eta}^*$) of the HPSP-xathan mixtures were lower than those of the control (0% gum). The differences between the dynamic moduli values at 12-week and 24-week fermentation decreased with increasing gum concentration, showing that xanthan gum can be used to stabilize and improve the viscoelastic rheological properties of HPSP. The G' value of the HPSP-xathan mixtures increased with an increase in gum concentration from 0.3 to 0.9%, whereas the G" decreased. The ability of xanthan gum to increase the elastic properties in the HPSP-xanthan mixture systems seemed to be the result of the incompatibility phenomena existing between xanthan gum and glutinous rice starch.

• Journal of Biosystems Engineering
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• v.14 no.3
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• pp.181-187
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• 1989

The mechanical and rheological properties of agricultural materials which influence the machine design or handling are not completely understood. Agricultural materials do not react in a purely elastic manner, and their responses when subjected to stress and strain appear a combination of elastic and viscous behavior. Many researchers have studied the mechanical and rheological properties of the various agricultural materials, but those properties are available mostly for foreign varieties of agricultural products. Rheological properties of rice seedlings become important to formulate the principles governing their mechanical behavior. The objectives of this study were to experimentally determine the creep and recovery behavior of rice seedlings of one japonica-type and one Indica x japonica hybrid in the transplanting age. The results of this study are summarized as follows; 1. The compression creep and recovery behavior of mat-type seedlings could be described by 4-element Burger's model. 2. The steady-state creep appeared at the stress larger than 0.8 MPa and the logarithmic creep appeared at the stress smaller than 0.8 MPa. 3. In the compression creep test of the rice seedlings, the instantaneous elastic modulus of Burger's model showed the range from 20 to 40 MPa. The higher value of absolute viscosity for the rice seedling explained that the rice seedlings were viscoelastic materials. 4. In the recovery test of the rice seedlings, there was a tendency that the higher permanent strain of all samples was observed under the smaller stress being appeared, and the larger permanent strain in Dongjin was observed than in Samkang.

• Korea-Australia Rheology Journal
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• v.17 no.4
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• pp.181-190
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• 2005

Rheological characterisation of flocculated kaolinite pulps has been undertaken to elucidate particle interactions underpinning the dewatering behaviour induced by flocculation with polyethylene oxide (PEO), anionic polyacrylamide (PAM A) and their blends. Shear yield stress $(\tau_y)$ analysis indicated that polymer mediated particle interactions were markedly amplified upon shear of PEG based pulps. In contrast, PAM A based pulps showed a significant decrease in yield values upon shear. Steady stress measurements analysed using a modified Ellis model indicated subtle differences between the respective linear viscoelastic plateaus of the pulps. Furthermore, modified shear thinning behaviour was evident in PEG based pulps. Estimation of elastic and viscous moduli (G', G') was made using dynamic stress analysis for comparison with values determined from vane measurements. Despite a noticeable difference in the magnitude of G' between the two methods, similar trends indicating sheared PEG-based pulps to be more elastic than PAM based pulps, were observed. Floc microstructural observations obtained in support of rheological properties indicate that PEG flocculant induces significantly more compact particle aggregation within the clay pulps under shear consistent with the yield stress data, in contrast to PAM A, or indeed unsheared PEG based pulps. Consequentially, sheared PEG based pulps show significantly improved dewatering behaviour. The implications of the results, potential benefits and drawbacks of flocculation with PEG and PAM A are discussed with respect to improvements in current dewatering processes used in the minerals industry.

• International Journal of Reliability and Applications
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• v.17 no.2
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• pp.137-147
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• 2016

The engine mount of a car subjected to a pre-load related to the weight of the engine, and acts to insulate the vibration coming from the engine by moving on large or small displacement depending on the driving condition of the car. The vibration insulation of the engine mount is an effect obtained by dissipating the mechanical energy into heat by the viscosity characteristic of the rubber and the microscopic behavior of the additive carbon black. Therefore, dynamic stiffness from the intrinsic properties of rubber filled with carbon black at the design stage is an important design consideration. In this paper, we introduced a hyper-elastic, visco-elastic and elasto-plastic model to predict the dynamic characteristics of rubber, and developed a fitting program to determine the material model parameters using MATLAB. The dynamic characteristics analysis of the rubber insulator of the ACTIVE MOUNT was carried out by using MSC.MARC nonlinear structural analysis software, which provides the dynamic characteristics material model. The analysis results were compared with the dynamic characteristics test results of the rubber insulator, which is one of the active mount components, and the analysis results were confirmed to be valid.

• Structural Engineering and Mechanics
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• v.87 no.2
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• pp.173-189
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• 2023

For a given structural geometry, the stiffness and damping parameters of the soil and the dynamic response of the structure may change in the face of an equivalent linear soil behavior caused by a strong earthquake. Therefore, the influence of equivalent linear soil behavior on the impedance functions form and the seismic response of the soil-structure system has been investigated. Through the substructure method, the seismic response of the selected structure was obtained by an analytical formulation based on the dynamic equilibrium of the soil-structure system modeled by an analog model with three degrees of freedom. Also, the dynamic response of the soil-structure system for a nonlinear soil behavior and for the two types of impedance function forms was also analyzed by 2D finite element modeling using ABAQUS software. The numerical results were compared with those of the analytical solution. After the investigation, the effect of soil nonlinearity clearly showed the critical role of soil stiffness loss under strong shaking, which is more complex than the linear elastic soil behavior, where the energy dissipation depends on the seismic motion amplitude and its frequency, the impedance function types, the shear modulus reduction and the damping increase. Excellent agreement between finite element analysis and analytical results has been obtained due to the reasonable representation of the model.

• Journal of the Korean Society of Food Science and Nutrition
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• v.15 no.3
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• pp.286-293
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• 1986

The purpose of this study was to investigate the effect of withering on mechanical properties for optimizing the condition of transportation and storage of fresh leafy vegetables which they would be easily able to be suffered the physical damage. Experimental material used were spinaches and leeks which were easily apt to be withered. The breaking stress, elastic modulus and viscosity were measured in the range of temperature $3{\sim}37^{\circ}C$ and water content $70{\sim}95%$ by the four element model, being used the creep tester made by author. As a result of this study, while water content was decreased, breaking stress was increased. The elastic modulus and viscosity of the specimens were not influenced on temperature, but on water content. In reversibility test of the withering, the appearance, water content and elastic modulus of the specimens were completely recovered to the initial freshness, but the viscosity was not.