• Composites Research
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• 제36권3호
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• pp.141-153
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• 2023

본 리뷰 논문에서는 일반 접촉 역학 이론과 더불어 유기탄성체 마찰에 관한 이론 및 배경을 소개한다. 특히 Greenwood & Williamson 접촉 역학 이론을 확장하여 거친 표면을 자기-아핀(self-affine) 특성으로 고려한 접촉 역학 및 마찰의 수학적 모델을 제시한 Klüppel & Heinrich 이론을 중심으로 유기탄성체 복합재료의 마찰 거동에 대해 살펴본다. 자기-아핀 특성에 의한 노면의 멀티스케일 거칠기로 인해 미끄러짐 마찰 시 유기탄성체 복합재료는 다양한 주파수에 따른 동적 변형이 가해지며 이때 재료가 나타내는 점탄성이 마찰 거동에 주요한 영향을 미친다. 따라서 유기탄성체 복합재료의 비선형 점탄성을 고려하여 광범위한 주파수 영역에서의 점탄성 거동인 마스터커브를 구축하는 원리 및 방법을 제시하였다. 마지막으로 유기탄성체 복합재료 마찰 이론을 타이어 트레드 컴파운드와 노면 간의 마찰에 응용한 실험적 결과와 그 물리적 의미를 이론과 접목하여 설명하였다.

• 마이크로전자및패키징학회지
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• 제28권2호
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• pp.51-57
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• 2021

이 연구에서는 에폭시 수지에 포함된 나노 실리카 입자의 농도가 재료의 열/기계적 물성에 미치는 영향에 대해 알아보았다. 약 12 nm 크기의 나노 입자를 에폭시 수지에 다섯가지 무게비로 섞은 나노복합소재를 제작하였다. DMA와 TMA 방법을 이용하여 유리전이온도, 응력이완, 열팽창 거동을 측정하였다. 이를 통해 나노입자가 재료의 점탄성 거동에 어떠한 영향을 미치는지 보였다. 실리카 입자의 함량이 증가할수록 순수 에폭시 재료 대비 탄성 물성은 증가하였고, 유리전이온도는 감소하였다. FTIR 결과는 분자구조의 관점에서 충진제 함량에 따른 물성변화의 원인을 찾고 나노입자가 에폭시 분자 구조에 어떠한 영향을 미치는지를 규명하는데 중요한 역할을 하였다.

• 공업화학
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• 제9권1호
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• pp.44-51
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• 1998

본 실험에서 QCA를 사용하여 $NaClO_4$, $LiClO_4$, $KClO_4$전해질 용액에서 전기중합한 폴리피롤 박막의 점탄성 특성을 in situ 분석하였다. 수정진동자를 특수 제작한 전기화학 분석셀에 넣어 수정진동자의 한쪽 전극을 작용전극으로 사용하였다. 공진주파수와 공진저항 상관도 (F-R)도를 이용하여 폴리피롤 박막의 점탄성을 해석하였고 AFM 사진과 비교 검토하였다. 피롤을 정전류에서 중합하여 피막한 수정진동자를 이용하여 순환전위주사하면서 공진주파수, 공진저항, 전류를 측정하여 폴리피롤 박막의 산화-환원 반응 거동을 분석하였다. 본 실험 결과, 전기중합 초기에는 피롤 박막이 탄성적으로 거동하다가 중합되어 감에 따라 점차 점탄성막으로 변하여 감을 알 수 있었다. 동시에 박막 사이로 전해질 용액이 침투됨에 따라 박막의 두께가 증가하면서 표면 형상도 변화하였다. 이와 같은 현상은 중합할 때의 전해질과 전위주사할 때의 전해질 용액을 변화시키면서 순환전위주사하여도 발생하였다.

• Computers and Concrete
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• 제7권4호
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• pp.365-386
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• 2010

This paper presents the physical formulation of a 1D material model suitable for seismic applications. It is written within the framework of thermodynamics with internal variables that is, especially, very efficient for the phenomenological representation of material behaviors at macroscale: those of the representative elementary volume. The model can reproduce the main characteristics observed for concrete, that is nonsymetric loading rate-dependent (viscoelasticity) behavior with appearance of permanent deformations and local hysteresis (continuum plasticity), stiffness degradation (continuum damage), cracking due to displacement localization (discrete plasticity or damage). The parameters have a clear physical meaning and can thus be easily identified. Although this point is not detailed in the paper, this material model is developed to be implemented in a finite element computer program. Therefore, for the benefit of the robustness of the numerical implementation, (i) linear state equations (no local iteration required) are defined whenever possible and (ii) the conditions in which the presented model can enter the generalized standard materials class - whose elements benefit from good global and local stability properties - are clearly established. To illustrate the capabilities of this model - among them for Earthquake Engineering applications - results of some numerical applications are presented.

• Journal of Biosystems Engineering
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• 제18권3호
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• pp.262-269
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• 1993

Stress relaxation behaviors of the cucumber under bending moment were tested with UTM at three levels of loading rate and initial deflection ratio. Sample cucumber was selected from three cultivars of cucumber, Cheongjangmadi, Baekdadagi, and Gyeousalicheongjang, because these cultivars are the most popular grown cultivars in Korea. When the bending moment was applied to the cucumber sample, the effective span between simple supports was held a constant value of 116mm with consideration of the selected sample length. The objectives of this study were to develop the rheological models such as linear and nonlinear models of the stress relaxation for the cucumber samples, and to investigate the effects of loading rate and initial deflection ratio on the stress relaxation behavior of the cucumber. The results of this study may be summarized as follows : 1. Stress relaxation behavior of the cucumber could be well described by the generalized Maxwell model for each level of deflection ratio. But the stress relaxation behavior of the sample was found to be initial deflection ratio and time dependent, and it was represented the nonlinear viscoelastic model as a function of initial deflection ratio and time. 2. Stress relaxation behavior of the cucumber samples was very highly affected by the loading rate and the initial deflection ratio. The more loading rate and initial deflection ratio resulted in the more initial bending stress and after stress relaxation progressed more rapidly. 3. At the same test conditions, it was found that the stress relaxation rate of Cheongjangmadi was faster than that of other cultivars.

• 한국염색가공학회지
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• 제15권2호
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• pp.59-67
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• 2003

PTT[poly(trimethylene terephthalate)] fiber was annealed by passing on the plate heater to illuminate the effects of annealing on the mechanical properties and dyeability with varying the treatment temperature for 0.5 second. The apparent crystal sizes and crystallinity were increased with increases in temperature. With the increases of the temperature, the dynamic viscoelastic behaviors were analyzed to be reduction in $T_{max} (tan{\delta})$. The initial modulus were observed to be a small enhanced. The shrinkage in hot water were reduced. The dyeability for disperse dye enhanced dramatically, for example, a satisfactory degree of exhaustion was obtained by dyeing at $95^\circ{C}$ for 30 min with the PTT fibers heat treated at $180^\circ{C}$.

• Macromolecular Research
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• 제13권3호
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• pp.243-252
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• 2005

The effect of the vinyl acetate (VA) content on the thermal, viscoelastic, rheological, morphological and mechanical behaviors in various blends of ethylene-vinyl acetate (EVA)/ethylene-$\alpha$-olefin copolymers was investigated using 28, 22 and $15 mol\%$ of VA in EVA. In the DSC melting and crystallization thermograms of all of the EVA systems blended with ethylene-$\alpha$-olefin copolymers, discrete peaks were observed which were related to the constituents. In the dynamic mechanical thermal analysis, the storage modulus increased with increasing content of ethylene-$\alpha$-olefin copolymers. In addition, the transition regions relating to the tan bpeaks varied with the VA content. The crossover point between G' and G" varied depending on the VA contents, and shear-thinning was more prominent in the EVA/EtBC system. In the SEM investigation, a discrete phase morphology was observed in both the EVA/EtBC and EVA/EtOC blends, but the contrast improved with decreasing VA content. However, the tensile strength and modulus improved, but the elongation at break reduced with decreasing VA content, implying that the ethylene-$\alpha$-olefin copolymers play the role of reinforcing materials. Thus, the EVA and ethylene-$\alpha$-olefin components in the copolymers are immiscible in the molten and solid states, but are nevertheless mechanically compatible.

• 한국정밀공학회지
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• 제22권7호
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• pp.62-70
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• 2005

The nanoindenter and AFM have been used for nanofabrication, such as nanolithography, nanowriting, and nanopatterning, as well as measurement of mechanical properties and surface topology. Nanoscale indents can be used as cells for molecular electronics and drug delivery, slots for integration into nanodevices, and defects for tailoring the structure and properties. Therefore, it is very important to make indents of desired morphology (shape, size and depth). Indents of different shapes can be obtained by using indenters of different geometries such as a cube comer and conical and spherical tips. The depth and size of indents can be controlled by making indentations at different indentation loads. However, in case of viscoplastic viscoelastic materials such as polymethylmethacrylate (PMMA) the time dependent deformation (TDD) should also be considered. In this study, the effect of process parameters such as loading rate and hold-time at peak load on the indent morphology (maximum penetration depth, elastic recovery, transient creep recovery, residual depth pile-up height) of PMMA were studied for hyperfine pattern fabrication.

• 한국정밀공학회지
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• 제22권2호
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• pp.180-187
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• 2005

This paper is focused on the development of the flexible electrode for disc-type polymer actuators using Segmented Polyurethane(SPU). This paper consists of two parts. The one is about the mechanical property such as elastic modulus. these parameters mainly affect behaviors of polymer actuators and the other is about the electro-chemical property such as the surface resistance of the composite electrode affects the strength of electrostatic force, results in the deformation of polymer actuators. The Young's modulus was measured by UTM. As result, by increasing the modulus of a body of polymer actuators, the maximum displacement of polymer actuators are decreased. The surface resistance of the electrode was measured by 4 point probe system. Compared with the conductive silver grease, the displacement of polymer actuators using carbon black(CB) composite electrodes is comparably small but CB composite electrode should be the practical approach for the improvement of the performance of all-solid actuators, compared with another types of electrode materials.

• 한국염색가공학회지
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• 제15권3호
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• pp.132-139
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• 2003

PTT[Poly(trimethylene terephthalate)] fibers was annealed by passing on the plate heater to illuminate the effects of annealing on the alkaline hydrolysis behavior properties with varying the treatment temperature for 0.5 second. The L010 and crystallinity were increased with increases in temperature. With the increases of the temperature, the dynamic viscoelastic behaviors were analyzed to be reduction in $T_{max}(tan\;\delta)$. The weight loss in alkaline solution was two times more rapid for the PTT annealed at $200^\circ{C}$ than the control samples. The kinetics of hydrolysis was confirmed that the hydrolysis of the PTT fibers in the alkaline solution was started from the surface of the fibers and selective to the amorphous region in continuation, on the basis of the results of the increase in crystallinity and the decrease in dye uptake at the initial stage of the hydrolysis.