• Journal of the korean academy of Pediatric Dentistry
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• v.36 no.1
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• pp.38-45
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• 2009

The aim of this study was to examine efficacy of the commercially available 10% CPP-ACP cream (Tooth mousse, GC Co., Japan) and/or 0.05% NaF solution on the remineralization of artifical caries-like lesion in the bovine teeth enamel. Sixty bovine teeth were embedded in orthodontic resin and flattened. The enamel surface in 3 mm diameter was exposed with nail varnish. Specimens were stored in demineralizing solution and divided 5 groups; Group 1 (No treatment), 2 (0.05% NaF solution 1 min), 3 (Tooth mousse 3 min), 4 (After 0.05% NaF solution, Tooth mousse treatment), and 5 (After Tooth mousse treatment, soaking in 0.05% NaF solution during 1 min). After treatment by groups, all specimens was stored in artificial saliva for 30 min. After the process described as above was performed during 10 days without pH cycling, surface hardness (Vickers Hardness Number, VHN) was tested and analyzed by paired t-test and one-way ANOVA test with SPSS 14.0. In intragroup comparison between surface hardness of pre and post-treatment, group 3, 4, 5 showed statistically significant increase (P < 0.05). In intergroup comparison among surface hardness increase of all groups, difference of group 5 between pre and post-treatment ($15.80{\pm}12.21$) was the highest, and followed by group 4 ($14.27{\pm}11.73$), 3 ($4.05{\pm}5.18$), 2 ($1.15{\pm}6.83$), 1 ($0.78{\pm}6.21$). Tooth mousse can be a good alternative agent for the fluoride, and the combination use with fluoride might have the additional anticariogenic effect.

• Journal of dental hygiene science
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• v.22 no.1
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• pp.20-29
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• 2022

Background: The purpose of this study is to investigate the effect of liquefied digestive medicines on the composite resin surface. Methods: Three types of liquefied digestive medicines (Gashwalmyeongsu, Wicheongsu, and Saengrokcheon) were selected as experimental groups, Samdasoo and Chamisul as negative controls, and Trevi as positive controls were selected to measure pH and titratable acidity. The samples filled with resin at acrylic were made total 300, 50 per group. To evaluate the erosion risk of the composite resin, the specimens were immersed in a liquefied medicine for 1, 3, 5, 15, and 30 minutes, and then the surface microhardness was measured using the Vickers Hardness Number, and the surface change was observed with scanning electron microscope (SEM). Results: The average pH of the three liquefied medicine was 3.75±0.30, the Saengrokcheon was the lowest at 3.45±0.01, and the Trevi was 4.66 and Samdasoo and Chamisul were 7.40 and 8.58, respectively. The amount of NaOH reaching pH 5.5 and 7.0 was the lowest in the order of Trevi, Gashwalmyeongsu, Wicheongsu, and Saengrokcheon. The largest surface hardness reduction value was shown in Gashwalmyeongsu (-11.85±3.73), followed by Saengrokcheon (-9.79±3.11) and Wicheongsu (-8.28±2.83), and Samdasoo (-0.84±1.56) and Chamisul (-6.24±0.42) had relatively low surface hardness reduction values. However, Trevi (-16.67±5.41), a positive control group containing carbonic acid, showed a higher decrease in surface hardness than the experimental group. As a result of observation with SEM, experimental group and positive control group, showed rough surfaces and irregular cracks, and negative control groups showed smooth patterns similar to before immersion. Conclusion: The liquefied digestive medicine with low pH could weaken the composite resin surface, and the carbonic acid component could more effect on the physical properties of the composite resin than pH.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.3
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• pp.518-523
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• 1998

The fracture toughness and hardness of 62 %$SiO_2-19%ZrO_2-9%Na_2O-10%B_2O_3$(wt%) glass ceramics system were investigated. As a result of DTA study to find crystallization temperature, an exothermic peak near $820^{\circ}C$ was observed. The optimum nucleation temperature and the optimum crystal growth temperature were determined by XRD and SEM analysis, and were approximately $650^{\circ}C$, $840^{\circ}C$ respectively. The fracture toughness of this zirconia glass ceramics was determined by Vickers Indentation Method. The hardness value was not changed with increasing of the heat treatment temperature, but fracture toughness value was increased up to $1.8 MPa{\cdot}m^{1/2}$ at $840^{\circ}C$, with increasing of heat treatment temperature.

• The Journal of Advanced Prosthodontics
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• v.9 no.2
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• pp.104-109
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• 2017

PURPOSE. The purpose of this study was to evaluate the influence of acid etching treatment on surface characteristics and biological response of glass-infiltrated zirconia. MATERIALS AND METHODS. A hundred zirconia specimens were divided into four groups depending on surface treatments: untreated zirconia (group Z); acid-etched zirconia (group ZE); glass-infiltrated zirconia (group ZG); and glass-infiltrated and acid-etched zirconia (group ZGE). Surface roughness, surface topography, surface morphology, and Vickers hardness of specimens were evaluated. For biological response test, MC3T3-E1 cell attachment and proliferation on surface of the specimens were examined. The data were statistically analyzed using one-way ANOVA and Tukey's HSD test at a significance level of 0.05. RESULTS. Group ZGE showed the highest surface roughness ($Ra=1.54{\mu}m$) compared with other groups (P < .05). Meanwhile, the hardness of group Z was significantly higher than those of other groups (P < .05). Cell attachment and cell proliferation were significantly higher in group ZGE (P < .05). CONCLUSION. We concluded that effective surface roughness on zirconia could be made by acid etching treatment after glass infiltration. This surface showed significantly enhanced osteoblast cell response.

• Journal of Advanced Marine Engineering and Technology
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• v.33 no.1
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• pp.104-111
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• 2009

This paper shows the behaviors of macro- and micro-structures and mechanical properties for specimen's welding region welded by FSW. according to welding conditions with 5mm thickness aluminum 5083O alloy plate. It apparently results in defect-free weld zone in case traverse speed was changed to 32 mm/min under conditions of anti-clockwise direction and tool rotation speed such as 800 and 1250 rpm with tool's pin diameter of 5 ${\Phi}mm$ and shoulder diameter of 20 ${\Phi}mm$, pin length of 4.5 mm and tilting angle of $2^{\circ}$. The ultimate stress of ${\sigma}_T=331$ MPa and the yield point of 147 MPa are obtained at the condition of the travel speed of 32 mm/min with the tool rotation speed of 1250 rpm. There is neither voids nor cracks on bended surface of $180^{\circ}$ after bending test. The improvement of toughness after impact test was found. The lower rotating and traverse speed became, the higher were yield point, maximum stress and elongation(%) with the stresses and the elongation(%) versus the traverse speed diagram. Vickers hardness for cross section of welding zone were also presented. The typical macro-structures such as dynamically recrystallized zone, thermo-mechanically affected zone and heat affected zone and the micro-structures of the transverse cross-section were also showed. However, the author found out that the region of 6mm far away from shoulder circumference was affected by friction heat comprehensively, that is, hardness softened and that part of micro-structures were re-solid-solution or recrystallized, the author also knew that there is no mechanically deformation on heat affected zone but there are the flow of plastic deformation of $45^{\circ}$ direction on thermo-mechanically affected zone and the segregation of Al-Mg on nugget. The solid solution wt(%) of parent material as compared against of friction stir welded zone was comprehensively changed.

• The Journal of Korean Academy of Prosthodontics
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• v.42 no.2
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• pp.210-225
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• 2004

Statement of problem: Implant screw loosening has been remained problem in restorative practices. Surface treatment of screw plays a role of preventing screw from loosening in implant screw mechanism. Purpose : The purpose of this study was to investigate surface characteristics of TiN and ZrN film ion plated screw with titanium and gold alloy screw and to evaluate wear resistance, surface roughness, and film adhesion on screw surface using various instruments. Material and methods : GoldTite screws and titanium screws provided by 3i (Implant Innovation, USA) and TorqTite screws or titanium screws by Steri-Oss (Nobel Biocare, USA) and gold screws and titanium screws by AVANA (Osstem Implant, korea) were selected. Ion plating which is much superior to other surface modification techniques was carried out for gold screws and titanium screws using Ti and Zr coating materials with nitrogen gas. Ion nitrided surface of each abutment screw was observed with field emission scanning electron microscopy (FE-SEM, micro-diamond scratch tester, vickers hardness tester, and surface roughness tester. Results : 1) The surface of gold screw and GoldTite is more smooth than ones of other kinds of non coated screw. 2) The ZrN and TiN coated surface is the more smooth than ones of other kinds of screw. 3) The hardness of TiN and ZrN coated surface showed higher than that of non coated surface. 4) The TiN coated titanium screw and ZrN coated gold screw have a good wear resistance and adhesion on the surface. 5) The surface of ZrN coated screw showed low surface roughness compared with the surface of TiN coated screw. Conclusion : It is considered that the TiN and ZrN coated screw which would prevent a screw from loosening can be applicable to implant system and confirmed that TiN and ZrN film act as lubricant on surface of screw due to decrease of friction for recycled tightening and loosening.

• Tribology and Lubricants
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• v.36 no.4
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• pp.199-206
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• 2020

CoCr-based alloys have been developed as wear-resistant materials owing to their excellent mechanical properties and strong wear resistance. The purpose of this study is to experimentally assess the frictional and wear characteristics of CoCr-based alloys slid against two different counter materials subjected to various normal forces to determine the expansion applicability of CoCr-based alloys. CoCrMo and CoCr alloys were selected as the target materials and NiCr and NiCrB alloys as counter materials. Experimental tests were performed using a pin-on-reciprocating plate tribo-tester under dry lubrication. Before performing the tests, the surface of the specimens was observed through confocal microscopy and the hardness was measured using a micro-Vickers hardness tester. The wear volume of the plate was calculated at the end of the tests using confocal microscope data, and the wear rate was quantitatively obtained based on Archard's wear law. From the results, the wear rates of the CoCrMo specimens that slid against NiCr and NiCrB are 7.69 × 10^-6 ㎣/Nm and 5.26 × 10^-6 ㎣/Nm, respectively. The wear rates of the CoCr specimens that slid against NiCr and NiCrB were higher than those of the CoCrMo specimens by factors of approximately 4 and 8, respectively. The CoCrMo specimens further exhibited lower friction characteristics than the CoCr specimens. The findings of this study will be useful for expanded applications of CoCr-based alloys as wear-resistant materials for various mechanical parts.

• Transactions of Materials Processing
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• v.23 no.6
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• pp.345-350
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• 2014

The current study elucidates the effects of cementite spheroidization and pro-eutectoid ferrite on the sliding wear resistance in medium carbon (0.45wt%C) and high carbon (1wt%C) steels. Both steels were initially heat treated to obtain a fully pearlite or ferrite + pearlite microstructure. Spheroidizing heat treatments were performed on both steels to spheroidize the pearlitic cementite. Sliding wear tests were conducted using a pin-on-disk wear tester with the steel specimens as the disk and an alumina ($Al_2O_3$) ball as the pin. The sliding wear tests were carried out at room temperature in air with humidity of $40{\pm}2%$. Adapted sliding distance and applied load was 300m and 100N, respectively. Sliding speed was 0.1m/s and the wear-track radius was 9 mm. Worn surfaces and cross-sections of the wear track were examined using an SEM. Micro Vickers hardness of the wear-track subsurface was measured as a function of depth from the worn surface. Hardness and sliding-wear resistance of both steel decreased with increased spheroidization of the cementite. The decrease was more significant in the fully pearlitic steel (1wt%C steel). The steel with the pro-eutectoid ferrite showed relatively higher wear resistance compared to the spheroidized pearlitic steel.

• Korean Journal of Materials Research
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• v.22 no.3
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• pp.150-154
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• 2012

Ti-6Al-4V ELI (Extra Low Interstitial) alloy have been widely used as alternative to bone due to its excellent biocompatibility, although it still has many problems such as high elastic modulus and toxicity. Therefore, biomaterials with low elastic modulus and non toxic characteristics have to be developed. A novel ${\beta}$ Ti-35wt%Nb-7wt%Zr-Calcium pyrophosphate (CPP) composite that is a biocompatible alloy without elemental Al or V was fabricated by spark plasma sintering (SPS) at $1000^{\circ}C$ under 70 MPa using high energy mechanical milled (HEMM) powder. The microstructure and phases of the milled powders and the sintered specimens were studied using SEM, TEM, and XRD. Ti-35wt%Nb-7wt%Zr alloy was transformed from ${\alpha}$ phase to ${\beta}$ phase in the 4h-milled powder by sintering. The sintered specimen using the 4h-milled powder showed that all the elements were distributed very homogeneously and had higher density and hardness. ${\beta}$ Ti alloy-CPP composite, which has nanometer particles, was fabricated by SPS using HEMMed powder. During the sintering process, $CaTiO_3$, TixOy, and CaO were formed because of the reaction between Ti and CPP. The Vickers hardness of the composites increases with the increase of the milling time and the addition of CPP. The biocompatibility of the Ti-Nb-Zr alloys was improved by addition of CPP.

• Journal of Powder Materials
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• v.10 no.1
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• pp.26-33
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• 2003

Al-l4wt.%Ni-l4wt.% Mm(Mm=misch metal) alloy powders rapidly solidified by the gas atomization method were subjected to mechanical milling(MM). The morphology, microstructure and hardness of the powders were investigated as a function of milling time using scanning electron microscopy(SEM), transmission electron microscopy(TEM) and Vickers microhardness tester. Microstructural evolution in gas-atomized Al-l4wt.%Ni-l4wt.% Mm(Mm=misch metal) alloy powders was studied during mechanical milling. It was noted that the as-solidified particle size of $200\mutextrm{m}$ decreases during the first 48 hours and then increases up to 72 hours of milling due to cold bonding and subsequently there was continuous refinement to $20\mutextrm{m}$ on milling to 200 hours. Two microstructurally different zones, Zone A, which is fine microstructure area and Zone B, which has the structure of the as-solidified powder, were observed. The average thickness of the Zone A layer increased from about 10 to $15\mutextrm{m}$ in the powder milled for 24 hours. Increasing the milling time to 72 hours resulted in the formation of a thicker and more uniform Zone A layer, whose thickness increased to about $30~50\mutextrm{m}$. The TEM micrograph of ball milled powder for 200 hours shows formation of nano-particles, less than 20 nm in size, embedded in an Al matrix.