• 통합자연과학논문집
• /
• 제3권3호
• /
• pp.157-161
• /
• 2010

New low temperature synthesis of germanium nanoparticles obtained from the reaction of germanium tetrachloride and sodium/benzophenonewere developed. These germanium nanoparticles terminated with chloride group were oxidized in air to give hydroxy-terminated germanium nanoparticles. Germanium nanoparticle containing 20(S)-camptothecin (CPT) for a noble drug delivery system were developed. FT-IR spectroscopy was used for the characterization of vibrational absorption for the germanium nanoparticle and oxidized germanium nanoparticles containing camptothecin. Electronic absorption and fluorescence properties were measured with UV-Vis and fluorescence spectrometer. The morphology of oxidized germanium nanoparticles containing camptothecin was investigated by using TEM.

• Rapid Communication in Photoscience
• /
• 제4권2호
• /
• pp.34-36
• /
• 2015

New spectroscopic characteristics of amorphous ferric hydroxide ($Fe(OH)_3$), interestingly in the near infrared (NIR) region, are presented in this study. The absorption spectrum of ferric hydroxide covers wide spectral regions from ultraviolet to NIR (200~900 nm). Unique emission bands were newly observed in the NIR regions (800~1400 nm). Several bands of this NIR emission are quiet well overlapped with the combinational vibrational absorption bands of water. From photothermal conversion study, very interestingly, temperature of aqueous mixture solution including the amorphous ferric hydroxide was significantly increased from ambient temperature to $38^{\circ}C$ for 30 minutes under irradiation of a standard helium lamp.

• 대한기계학회논문집A
• /
• 제25권4호
• /
• pp.555-563
• /
• 2001

Support dynamics are often important in rotordynamic analyses. It may well happen in real situation of machines such as centrifugal pumps or turbines operating on flexible structure. This paper presents the applications of the impedance coupling method and the improved rotor model for including the support effects on the interaction with the rotor. The impedance coupling techniques are based on the FRFs of each substructure. Its dynamic stiffness matrix can be assembled to generate the system matrix, which satisfy the constraint conditions in the connection coordinates. And, the improved rotor uses the simplified spring-mass models as support properties. The equivalent support models are directly incorporated into the finite element rotor model. To verify the suggested analytical procedures, the results are compared to those of the pump system.

• Bulletin of the Korean Chemical Society
• /
• 제25권5호
• /
• pp.620-624
• /
• 2004

Optical emission studies were performed to investigate thermal and dynamical properties of a plume produced by laser ablation of a graphite target in a nitrogen atmosphere. Experimental spectra of $C_2(d^3{\Pi}_g{\to}a^3{\Pi}_u$, ${\Delta}_V$=1) and CN ($B^2{\Sigma}^+{\to}X^2{\Sigma}^+,{\Delta}_V=0)$ were simulated to obtain the vibrational and rotational temperatures of the electronically excited species at various laser fluences and distances from the target. The spectroscopic temperatures of both molecules were found to be nearly independent of the laser fluence. The temperature of CN molecules was peaked in the middle of the plume while that of $C_2$decreased with increase in the distance. At a given distance, the temperature of CN molecules was clearly higher than that of $C_2$.

• Structural Engineering and Mechanics
• /
• 제60권4호
• /
• pp.707-727
• /
• 2016

In this paper, thermal vibration of a nonlocal functionally graded (FG) plates with arbitrary boundary conditions under linear and non-linear temperature fields is explored by developing a refined shear deformation plate theory with an inverse cotangential function in which shear deformation effect was involved without the need for shear correction factors. The material properties of FG nanoplate are considered to be temperature-dependent and graded in the thickness direction according to the Mori-Tanaka model. On the basis of non-classical higher order plate model and Eringen's nonlocal elasticity theory, the small size influence was captured. Numerical examples show the importance of non-uniform thermal loadings, boundary conditions, gradient index, nonlocal parameter and aspect and side-to-thickness ratio on vibrational responses of size-dependent FG nanoplates.

• Journal of Photoscience
• /
• 제4권3호
• /
• pp.121-125
• /
• 1997

The 77 K emission and excitation, and room-temperature visible spectra of cis[Cr(cyclam)Br$_2$]Br (cyclam=1,4,8,11-tetraazacyclotetradecane) are reported. The mid- and far-infrared spectra at room-temperature are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. It is found that nitrogen atoms of the cyclam ligand have strong $\sigma$-donor characters, but bromide ligand has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion. The zerophonon line in the excitation spectrum splits into two components by 172 cm$^{2-}$, and the large $^2E_g$ splitting can be reproduced by the ligand field theory.

• Advances in nano research
• /
• 제8권4호
• /
• pp.283-292
• /
• 2020

In the present research, differential quadrature (DQ) method has been utilized for investigating free vibrations of porous functionally graded (FG) micro/nano beams in thermal environments. The exact location of neutral axis in FG material has been assumed where the material properties are described via porosity-dependent power-law functions. A scale factor related to couple stresses has been employed for describing size effect. The formulation of scale-dependent beam has been presented based upon a refined beam theory needless of shear correction factors. The governing equations and the associated boundary conditions have been established via Hamilton's rule and then they are solved implementing DQ method. Several graphs are provided which emphasis on the role of porosity dispersion type, porosity volume, temperature variation, scale factor and FG material index on free vibrational behavior of small scale beams.

• 대한화학회지
• /
• 제58권1호
• /
• pp.100-104
• /
• 2014

Magnetite nanoparticles were prepared by co-precipitation method and then silica was coated onto the surface of $Fe_3O_4$ by hydrolysis of TEOS. The silica coated magnetite nanoparticles were characterized for its structural, microstructural, optical, vibrational and magnetic properties by X-ray diffraction analysis, Scanning electron microscopy, UV-visible spectroscopy, Infrared spectroscopy and Vibration sample magnetometer, respectively. XRD study confirmed the presence of $SiO_2$ on the surface of magnetite nanoparticles. SEM study indicated that with increase in TEOS content the particles become bigger and mono-disperse. It was also found that the silica coating prevents magnetic particles from aggregation and imparts excellent stability.

• 대한화학회지
• /
• 제20권6호
• /
• pp.460-468
• /
• 1976

액체분자는 고체 및 기체와 같은 자유도를 갖는다는 가정하에 물에 관한 이론을 얻었다. 고체와 같은 분자의 진동수를 알아내는 데에 분광학적인 데이타를 이용하였다. 몰부피, 증기압, 엔트로피, 증발 엔트로피, 팽찰률, 압축률, 일정한 부피 및 일정한 압력하에서의 열용량, 표면장력, 임계점등을 계산한 결과 모두가 실험치와 아주 잘 일치하였다.

• 한국전기전자재료학회논문지
• /
• 제17권2호
• /
• pp.196-200
• /
• 2004

Using polyimide Langmuir-Blodgett(LB) films as a tunneling harrier, we fabricated Au/Polyimide/1-layer arachidic acid/Pb structure in order to investigate electron transport properties through a junction. It was found that 9-layer polyimide LB films function as a good tunneling harrier in a study of current-voltage(I-V) chararteristics. And several peaks originating in the vibrational modes of the constituent molecules of 1-layer arachidic acid LB films were clearly observed in d$^2$V/dI$^2$- V corves.