• Bulletin of the Korean Chemical Society
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• v.33 no.3
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• pp.885-892
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• 2012

Energy transfer dynamics of excited vibrational energy of OH stretching bonds in liquid water is theoretically studied. With time-dependent vibrational Hamiltonian obtained from a mixed quantum/classical calculation, we construct a master equation describing the energy transfer dynamics. Survival probability predicted by the master equation is compared with numerically exact one and we found that incoherent picture of energy transfer is reasonably valid for long-time population dynamics. Within the incoherent picture, we assess the validity of independent pair approximation (IPA) often introduced in the theoretical models utilized in the analysis of experimental data. Our results support that the IPA is almost perfectly valid as applied for the vibrational energy transfer in liquid water. However, proper incorporation of radial and orientational correlations between two OH bonds is found to be critical for a theory to be quantitatively valid. Consequently, it is suggested that the Forster model should be generalized by including the effects of the pair correlations in order to be applied for vibrational energy transfer in liquid water.

• Bulletin of the Korean Chemical Society
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• v.24 no.8
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• pp.1091-1096
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• 2003

The effects of different polarization conditions on vibrational echo signals are systematically explored for the rigid cyclic dipeptide 2,5-diazabicyclo[2,2,2]octane-3,6-dione. An anharmonic vibrational Hamiltonian is constructed by computing energy derivatives to fourth order using density functional theory. Molecular frame transition dipole orientations are then used to calculate polarization dependent orientational factors corresponding to various Liouville space pathways. Enhancement and elimination of specific peaks in twodimensional correlation plots is accomplished by identifying appropriate pulse configurations.

• International Journal of Aeronautical and Space Sciences
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• v.18 no.1
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• pp.28-37
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• 2017

Recent modeling of thermal nonequilibrium processes in simple molecules like hydrogen and nitrogen has indicated that rotational nonequilibrium becomes as important as vibrational nonequilibrium at high temperatures. In the present work, in order to analyze rovibrational nonequilibrium, the rotational mode is separated from the translational-rotational mode that is usually considered as an equilibrium mode in two- and multi-temperature models. Then, the translational, rotational, and electron-electronic-vibrational modes are considered separately in describing the thermochemical nonequilibrium of nitrogen behind a strong normal shock wave. The energy transfer for each energy mode is described by recently evaluated relaxation time parameters including the rotational-to-vibrational energy transfer. One-dimensional post-normal shock flow equations are constructed with these thermochemical models, and post-normal shock flow calculations are performed for the conditions of existing shock-tube experiments. In comparisons with the experimental measurements, it is shown that the present thermochemical model is able to describe the rotational and electron-electronic-vibrational relaxation processes of nitrogen behind a strong shock wave.

• Journal of Astronomy and Space Sciences
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• v.6 no.2
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• pp.75-89
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• 1989

The Spacelab 1 data represented the first multiband spectral measuremets of the ${N_2}^{+}$ first negative ion bands system in the thermospheric dayglow, and the first opportunity to make a detailed comparison of the vibrational and rotational distributions over bands out to v'=5. The main purpose of this study was to decuced the excitation processes of ${N_2}^{+}$(1N) bands by determining vibrational population distributions for the upper states of ${N_2}^{+}$(1N). The vibrational population distributions to achieve a best fit to the measured Spacelab 1 data were summarized and also compared with those theoretically derived.

• Journal of KSNVE
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• v.9 no.3
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• pp.517-524
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• 1999

Mathematical formulas for multi-dimensional isolation analysis via vibrational power transmission can be derived in a rather simple form when the wave effects of the isolators are completely neglected. With increase of frequency range of interest, however, the wave effects play a very important role and hence cannot be neglected. The formulas get involved accordingly. In this study, a method of equivalent stiffness modeling of the isolators to include the wave effects is proposed in such a way that not only the complexity of the mathematical expressions but also that of experiments of necessity can be reduced. This method is illustratively applied to a two-dimensional vibration isolation system with nonrigid source and base structures.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.12 no.1
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• pp.65-72
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• 2002

Generally, there are laser operating equipments( aligner, stepper) and electronic microscope( SEM, TEM) as a high precision manufacturing and inspection equipment in semiconductor production companies, precision examination and measuring laboratories. Mostly, these equipments are characterized by projection and target part. The relative displacements between projection and target part are dominant roles in vibrational problem in these precision equipments. These relative displacements are determined by the position of incoming vibration and the difference of vibration response in projection and target part. In this study, the allowable vibrational limits are suggested and the vibrational reduction plans are proposed by measurement and analysis of vibration phenomenon in the Clean Room in PDP(plasma display panel) production building. The vibration performance is evaluated by comparison relative displacements between projection and target part before/after the vibration isolation plan.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.948-954
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• 2008

In this study, vibrational characteristics of two nano-imprinting stages is analyzed and compared with respect to the methodology to support the upper-plate of the stage. The first type of the stage has three supporters at each corners of the stage and one thrust bearing at the center of the stage. The other type of the stage has four supporter in each corner of the stage without a thrust bearing. The FEM software with flexible modeling is used for the normal mode analysis. The result depicts the difference of vibrational characteristics caused by the difference of support methods. The design criteria for the precision nano-imprinting stage is also discussed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.12
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• pp.1494-1500
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• 2004

A zero-dimensional direct simulation Monte Carlo(DSMC) model is developed for simulating diatomic gas including vibrational kinetics. The method is applied to the simulation of two systems: vibrational relaxation of a simple harmonic oscillator and translational-rotational-vibrational energy exchange process under heating and cooling. In the present DSMC method, the variable hard sphere molecular model and no time counter technique are used to simulate the molecular collision kinetics. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1997.04a
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• pp.229-234
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• 1997

The dynamic behavior of underground structures is complex due to the effects of vibrational characteristics of the structure and the rock. In this study, dynamic displacement responses at the structure surface by the elastic stress waves are considered as the vibrational characteristics, and evaluated by the form of the frequency spectrum. The variation of the vibrational characteristic is simulated by numerical analysis at the case of the structure has internal defections. The results reveals the possibility of the experimental detection of void existence and size. Furthermore, the verification of the dynamic response can be used for rating the stability of a tunnel.

• Steel and Composite Structures
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• v.35 no.4
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• pp.545-554
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• 2020

The present paper explores nonlinear dynamical properties of piezo-magnetic beams based on a nonlocal refined higher-order beam formulation and piezoelectric phase effect. The piezoelectric phase increment may lead to improved vibrational behaviors for the smart beams subjected to magnetic fields and external harmonic excitation. Nonlinear governing equations of a nonlocal intelligent beam have been achieved based upon the refined beam model and a numerical provided has been introduced to calculate nonlinear vibrational curves. The present study indicates that variation in the volume fraction of piezoelectric ingredient has a substantial impact on vibrational behaviors of intelligent nanobeam under electrical and magnetic fields. Also, it can be seen that nonlinear free/forced vibrational behaviors of intelligent nanobeam have dependency on the magnitudes of induced electrical voltages, magnetic potential, stiffening elastic substrate and shear deformation.