• 한국소음진동공학회논문집
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• 제11권4호
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• pp.22-30
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• 2001

In this paper, active control of vibrational intensity at a reference point in an infinite, elastic plate was discussed. The plate is excised harmonically by a vibrating source, which has a vertical point force. The optimal condition of controller was investigated to minimize the vibrational intensity being transmitted from the vibrating source to a reference point. Hence the method of feedforward control was employed for the control strategy and then the cost function was evaluated to find the optimal control force. Three types of control force (Vertical force, Moment, and Coupling force (a set of vertical force and moment) ) and controller's positions were examined to define the optimal condition of the controller. The vibrational intensity at a reference point was found to be reduced down to a zero level, compared with the uncontrolled case. Especially maximum reduction of vibrational intensity was achieved when the controller was collinearly positioned between a vibrating source and a reference point.

• Bulletin of the Korean Chemical Society
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• 제15권2호
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• pp.118-122
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• 1994

Molecular dynamics simulation was carried out to study density effects on vibrational dephasing. Because of difficulty due to large time scale difference between vibrational motion and vibrational relaxation, we adopt adiabatic approximation in which the vibrational motion is assumed to be much faster than translational and rotational motion. As a result, we are able to study vibrational dephasing by simulating motion of rigid molecules. It is shown that the dephasing time is decreased as density increases and the contribution to this result is mainly due to the mean-squared frequency fluctuation.

• 대한화학회지
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• 제62권5호
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• pp.412-416
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• 2018

• 대한화학회지
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• 제42권1호
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• pp.9-15
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• 1998

Dimethyldioxirane$[(CH_3)_2CO_2]$의 분자구조, vibrational frequencies 그리고 infrared(IR) 스펙트럼의 세기(intensity)등에 대한 이론적 연구를 high level ab initio 양자역학적 방법(CISD,CCSD, CCDS(T))을 사용하여 수행하였다. 분자구조의 경우 C-O와 O-O에 대한 결합길이는 parent dixoirane$(CH_2O_2)$과 유사한 결과를 보여주었으며, electron correlation effect의 영향이 C-C나 C-H결합길이 보다 더 크게 작용하였다. 사용된 basis sets(DZ,DZP, TZP, 그리고 TZ2P)에 대해서는 polarization function의 역할이 매우 중요한 것으로 나타났으며 triple zeta(TZ)에 의한 효과는 상대적으로 나타났다. 한편 계산된 harmonic vibrational frequency들을 실험결과 및 다른 이론 계산결과와 비교, 분석하였으며 IR intencity에 근거하여 각 vibrational mode를 assign하였다.

• Genomics & Informatics
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• 제10권2호
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• pp.128-132
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• 2012

To learn the differences between the structure-activity relationship and molecular vibration-activity relationship in the ligand-receptor interaction of the histamine receptor, 47 ligands of the histamine receptor were analyzed by structural similarity and molecular vibrational frequency patterns. The radial tree that was produced by clustering analysis of molecular vibrational frequency patterns shows its potential for the functional classification of histamine receptor ligands.

• Bulletin of the Korean Chemical Society
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• 제19권1호
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• pp.93-98
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• 1998

The molecular geometries and harmonic vibrational frequencies of biphenyl in the ground and the first excited triplet states have been calculated using the Hartree-Fock and Becke-3-Lee-Yang-Parr (B3LYP) density functional methods with 6-31G* basis set. Structural change occurs from a twisted benzene-like to a planar quinone-like form upon the excitation to the first excited state. Scaled harmonic vibrational frequencies for the ground state obtained from the B3LYP calculation show good agreement with the available experimental data. A few vibrational fundamentals for both states are newly assigned based on the B3LYP results.

• 대한화학회지
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• 제50권6호
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• pp.429-439
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• 2006

분광법의 하나인 합 진동수 발생 진동 분광법 (SFG-VS, sum frequency generation vibrational spectroscopy)은 표면의 분자에 대하여 선택적으로 높은 감도의 진동 스펙트럼을 제공한다. 이로 인해 SFG-VS 는 다양한 표면 연구에 이용되고 있다. 본 총설에서는 SFG-VS의 연구 대상, 실험 방법, 이론적 배경, 상업적 분광기로서의 가능성 등에 관하여 살펴보았다.

• 한국생산제조학회지
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• 제21권2호
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• pp.337-343
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• 2012

This work investigates the vibrational characteristics of the underground gas pipelines. Experiments were conducted to analyze the effects of various parameters on the vibrational characteristics from the emergency detection point of view. Influences of the various types of impact exerted on the pipe, height of free fall and measuring locations were analyzed. Especially, the difference between the vibrational signal generated by the direct impact on the pipe and the ambient noise was successfully identified. To validate the experimental observation, computer simulation was also performed with constant properties(elasticity, fluid velocity and internal pressure) which are directly conjectured from the accompanying experiment with a real pipe system.

• 한국정밀공학회지
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• 제19권6호
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• pp.109-118
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• 2002

The vibrational intensity and the dynamic response of a compound vibratory system had been controlled actively by means of a feedforward control method. A compound vibratory system consists of a flexible beam and two discrete systems - a vibrating source and a dynamic absorber. By considering the interactive motions between discrete systems and a flexible beam, the equations of motion for a compound vibratory system were derived using a method of variation of parameters. To define the optimal conditions of a controller the cost function, which denotes a time averaged power flow, was evaluated numerically. The possibility of reductions of both of vibrational intensity and dynamic response at a control point located at a distance from a source were fecund to depend on the positions of a source, a control point and a controller. Especially the presence of a dynamic absorber gives the more reduction on the dynamic response but the less on the vibrational intensity than those without a dynamic absorber.

• 소음진동
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• 제8권2호
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• pp.306-312
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• 1998

This paper proposes a method for estimating the vibrational power supplied by a machine that generates excitation force to its supporting structure via the coupling points. The basis of the method is that the vibrational power can be calculated using the mechanical impedance and the velocity at the coupling points on the supporting structure. First, a method is described to estimate the mobilities at the coupling points when the machine is not separable from the supporting structure, then the vibrational power is calculated using the estimated mobilities and measured velocities at the coupling points. The mobilities are estimated from the result of impulsive testing of the coupled structure. The method is investigated using an experimental model. The estimated and measured values of the mobilities and the vibrational power are compared. It is shown that the estimated values agree well with the measured values.