• Journal of Korean Society for Atmospheric Environment
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• v.25 no.1
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• pp.57-74
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• 2009

In order to clarify the vertical ozone distribution in planetary boundary layer of coastal area with complex terrain, an observation campaign was carried out around Gwangyang Bay with dense pollutant emission sources during two days from June, 4 2007. For this observation are Radiosonde, SODAR(SOnic Detection And Ranging) and Tethered ozone sonde were employed. The surface meteorological and photochemical observation data provided by AWS (Automatic Weather System) and AQMS (Air Quality Monitoring System) were also applied for analysis. Synoptic condition is strongly associated with lower level ozone distribution in complex terrain coastal area. Since mesoscale circulation induced by difference of characteristics of land and sea and orographic forcing is predominant under calm synoptic condition, vertical distribution of ozone is complicate and vertical ozone concentration greatly fluctuated. However in second day when synoptic influence become strong, ozone concentration in lower levels is vertically uniform regardless of observation level. This results in vertical observation indicates that vertical ozone distribution is often determined by synoptic condition and also affects surface ozone concentration.

• Journal of Environmental Science International
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• v.10 no.6
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• pp.417-422
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• 2001

The vertical structure of atmosphere was observed In investigate the variation of surface ozone concentration by vertical downward mixing of residual ozone in the atmospheric boundary layer at the Busan coastal area. Airsonde and pilot balloon measurements were made at Gamcheondong and the Kimhae airport for April 26~27, 1996. The vertical potential of potential temperature showed a residual layer between 510m and 1800m from 2100LST April 26 to 0900LST April 27. The downward mixing of ozone in the residual layer of the atmospheric boundary layer was confirmed from vertical profile of mixing ratio near 600m in the morning. The thickness of the sea breeze layer was 900m at 1500LST April 26. Thereafter, it become to be lowered with time A low level jet was measured near 900m at 0300LST on April 27 from a pibal measurement. Early morning sharp increase of surface ozone concentration at the Busan coastal area was caused by vertical downward mixing of ozone concentration rather than by photochemical reaction In the atmospheric boundary layer.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.3
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• pp.271-285
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• 2006

A two-dimensional photochemical transport model (2D PTM) is simulated to describe the transport and chemical reaction of ozone related to aerosols in the troposphere and stratosphere. The vertical profiles and total amounts of ozone, which are advected by both residual Eulerian circulation and the adiabatic circulation under certain circumstance, have been compared with the observation data such as ozonesondes, Brewer spectrometer, the Upper Atmosphere Research Satellite (UARS), and the Total Ozone Mapping Spectrophotometer (TOMS). As a result, we find that the observed distribution of ozone Is adequately reproduced in the model at middle and high latitude in the Northern Hemisphere as well as at Phang ($36^{\circ}\;02'N,\;129^{\circ}\;23'E$) in South Korea. In particular, the 2D PTM is well simulated in the ozone decrease due to the Pinatubo volcanic eruption in 1991. However, ozone mixing ratio are more underestimated than those of UARS and ozonesondes, because are very sensitive to the latitude of transport across the tropopause associated with both Rummukainen errors and off-line model. Relative mean bias errors and relative root mean square errors of ozone calculations using the 2D PTM are shown within${\pm}10%$, respectively.

• Atmosphere
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• v.30 no.1
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• pp.91-102
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• 2020

MERRA-2 ozone and atmospheric data are utilized to test the usefulness of reanalysis-based tracer transport analysis for ozone in the tropical tropopause layer (TTL). Transport and mixing processes related to the seasonal variation of TTL ozone are examined using the tracer transport equation based on the transformed Eulerian mean, and the results are compared to previously proposed values from model analyses. The analysis shows that the seasonal variability of TTL ozone is mainly determined by two processes: vertical mean transport and horizontal eddy mixing of ozone, with different contributions in the Northern and Southern Hemispheres. The horizontal eddy mixing process explains the major portion of the seasonal cycle in the northern TTL, while the vertical mean transport dominates in the southern TTL. The Asian summer monsoon likely contributes to this observed difference. The ozone variability and related processes in MERRA-2 reanalysis show qualitatively similar features with satellite- and model-based analyses, and it provides advantages of fine-scale analyses. However, it still shows significant quantitative biases in ozone budget analysis.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.59-60
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• 2003

In this study, we present the analysis of vertical ozone sounding data observed over Pohang, Korea, and investigate to understand the governing mechanisms for seasonal ozone maximum in June. The vertical ozone profiles in June show that the ozone enhancement is clearly shown in the middle and upper troposphere. We have found that the June maximum is associated with the transport of ozone rich air from the stratosphere and polluted continental air mass. This is different from the previous studies shown that the regionally polluted continental air mass, influenced by the intense anthropogenic activities m northeast Asia during transport, is responsible for the ozone maximum in spring.

• Journal of Environmental Science International
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• v.12 no.4
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• pp.419-426
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• 2003

This study was performed to research ozone concentration related to airmass thunderstorm using 12 years meteorological data(1990~2001) at Busan. The occurrence frequency of thunderstorm during 12 years was 156 days(annual mean 13days). The airmass thunderstorm frequency was 14 days, most of those occurrence at summertime(59%). In case August 4, 1996, increase of ozone concentration was simultaneous with the decrease of temperature and increase of relative humidity, In case July 23, 1997, ozone concentration of western site at Busan increased, while its of eastern site decreased as airmass thunderstorm occurred(about 1500LST). It is supposed that these ozone increases are the effect of ozone rich air that is brought down by cumulus downdrafts from height levels where the ozone mixing ratio is larger. Thunderstorms can cause downward transport of ozone from the reservoir layer in the upper troposphere into planeta교 boundary layer(PBL). This complex interaction of source and sink processes can result in large variability fer vertical and horizontal ozone distributions. Thus a variety of meteorological precesses can act to enhance vertical mixing between the earth's surface and the atmospheric in the manner described fer thunderstorm.

• Atmosphere
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• v.32 no.3
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• pp.247-261
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• 2022

The importance of ozone monitoring has been growing due to the polar ozone depletion and increasing tropospheric ozone concentration over many Asian countries, including South Korea. In-situ measurement of the vertical ozone structure has advantages for ozone research, but observations are not sufficient. In this study, ozonesonde measurements were performed from October to November in Yongin during the GMAP (The GEMS Map of Air Pollution) 2021 campaign. The procedure for ozonesonde preparation and initial analysis of the observed ozone profile are documented. The observed ozone concentrations are in good agreement with previous studies in the troposphere, and they capture the stratospheric ozone distribution as well, including stratosphere-troposphere exchange event. These balloon-borne in situ measurements can contribute to the evaluation of remote sensing measurements such as Geostationary Environment Monitoring Spectrometer (GEMS). This document focuses on providing essential information of ozonesonde preparation and measurement for domestic researchers.

• Journal of the Korean earth science society
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• v.29 no.5
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• pp.428-436
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• 2008

This study observed the upper tropospheric ozone enhancement in the northern Atlantic for the Aerosols99 campaign in January-February 1999. To find the origin of this air, we have analyzed the horizontal and vertical fields of Isentropic Potential Vorticity (IPV) and Relative Humidity (RH). The arch-shaped IPV is greater than 1.5 pvus indicating stratospheric air stretches equatorward. These arch-shaped regions are connected with regions of RH less than 20%. The vertical fields of IPV and RH show the folding layer penetrating into the upper troposphere. These features support the idea that the upper tropospheric ozone enhancement originated from the stratosphere. Additionally, we have investigated the climatological frequency of stratospheric intrusion over the tropical north Atlantic using IPV and RH. The total frequency between the equator and $30^{\circ}N$ over the tropical north Atlantic exhibits a maximum in northern winter. It suggests that the stratospheric intrusion plays an important role in enhancing ozone in the upper troposphere over the tropical north Atlantic in winter and early spring. Although the tropospheric ozone residual method assumed zonally invariant stratospheric ozone, stratospheric zonal ozone variance could be caused by stratospheric intrusions. This implies that stratospheric intrusion influences ozone variance over the Atlantic in boreal winter and spring, and the intrusion is a possible source for the tropical north Atlantic paradox.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.65-68
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• 2003

A quantitative study of the amount of air transported between the boundary layer and the free atmosphere is important for understanding air quality and upper tropospheric ozone, which is a greenhouse gas. Frontal systems are known to be an effective mechanism for the vertical transport of pollutants. Numerical experiments have been performed with a simple two-dimensional front model to simulate vertical transport of trace gases within developing cold fronts. Three different trace gases experiments have been done numerically according to the different initial fields of trace gases such as aerosol, ozone and $H_2O_2$. Trace gas field tilts to the east while the front tilts to the west. Aerosol simulation shows that pollutants can be transported out of the boundary to altitudes of about 10 km. The stratospheric ozone is brought downwards in a tropopause fold behind of the frontal surface. The meridional gradient in trace gas ($H_2O_2$) can cause a complicate structure in the trace field by the meridional advection.

• Journal of Astronomy and Space Sciences
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• v.15 no.1
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• pp.119-138
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• 1998

Recently measurements of atmospheric trace gases from satellite are vigorous. So the development of its data processing algorithm is important. In this study, retrievalof vertical ozone profile from the atmospheric transmittance measured by satellite solar occultation method and its sensitivity to temperature and pressure are investigated. The measured transmittance from satellite is assumed to be given by the limb path transmittance simulated using annual averaged Umkehr data for Seoul. The limb path transmittance between wavelengths $9.89{\mu}m$ and $10.2{\mu}m$ is simulated with respect to tangent heights using the ozone data of HALOE SIDS(Hallogen Occultation Experiment Simulated Instrument Data Set) as an initial profile. Other input data such as pressure and temperature are also from HALOE SIDS. Vertical ozone profile is correctly retrieved from the measured transmittance by onion-peeling method from 50km to 11km tangent heights with the vertical resolution of 3km. The bias error of $\pm0.001$ in measured transmittance, the forced error of $\pm3K$ in each layer temperature, and the forced $\pm3%$ error in each layer pressure are assumed for sensitivity tests. These errors are based on the ADEOS/ILAS error limitation. The error in ozone amount ranges from -6.5% to +6.9% due to transmittance error, from -9.5% to +10.5% due to temperature error, and from -5.1% to +5.4% due to pressure error, respectively. The present study suggests that accurate vertical ozone profile can be retrieved from satellite solar occultation method. Accuracy of vertical temperature profile is especially important in the retrieval of vertical ozone profile.