• 한국화재소방학회논문지
• /
• 제23권6호
• /
• pp.10-15
• /
• 2009

산불에서의 화염높이 산정은 복사열전달에 의한 수평 또는 수직적 화염확산을 예측하는데 있어 매우 중요한 부분이다. 화염특성 중 화염높이는 빛을 수반하는 화염(the luminous flame)의 평균높이로 확인할 수 있다. 본 연구에서는 외부 풍속과 경사 등으로 인한 화염 높이가 변화될 수 있는 조건을 제외한 산림내 지표연소물질(surface fuel)인 소나무 낙엽층(fuel bed)에 대한 화염높이 관측실험과 열량분석계을 이용하여 발열량(Heat Release Rate) 측정실험과 수치해석을 통해 지표연소물질에 대한 화염높이 산출식 $H_f=0.027(\dot{Q'})^{2/3}$을 도출하였다. 실험값과 개발 산정식, 기존 Heskestad 식과의 적용값 비교 결과, 소나무 낙엽의 경우, 실험값과 개발 산정식 적용값의 표준오차는 0.08, 실험값과 기존 Heskestad 식의 표준오차는 0.23으로 개발 산정식의 정확성이 높은 것으로 나타났다.

• 한국응용과학기술학회지
• /
• 제21권1호
• /
• pp.62-68
• /
• 2004

PU flame-retardant coatings (APHD) containing phosphorous were prepared by blending of hexamethylene diisocyanate-trimer, white pigment, dispersing agent, flowing agent, and previously prepared benzoic acid modified polyester (APTB) that contains phosphorous. Physical properties of the prepared APHD were examined. With the introduction of BZA (contained in APTB), the film viscosity and film hardness of APHD decreased. With the introduction of caprolactone group, the flexibility, impact resistance, accelerated weathering resistance of APTBs increased. Flame retardancy of the coatings was tested. In a vertical burning method, APHD shows 210${\sim}$313 seconds, and in a $45^{\circ}$ Meckel burner method, shows 1.3${\sim}$4.0$cm^2$ of char length, which indicates that the coatings are good flame-retardant coatings. Moreover, the amount of afterglow and flame retardancy of the coatings are decreased with increasing BZA content.

• 한국응용과학기술학회지
• /
• 제20권2호
• /
• pp.87-93
• /
• 2003

Two-component polyurethane flame retardant coatings (ATTBC) were prepared by blending polyisocyanate (TDI-adduct) with ATTBs mentioned at the previous paper. Most of the physical properties of the flame retardant coatings were comparable to those of non-flame retardant coatings. Especially, the hardness, impact resistance, and accelerated weathering resistance were remarkably improved with the increase of the content of 1,4-butanediol. Coatings containing 10 and 15 wt% 1,4-butanediol, ATTBC-10C and ATTBC-15C, were not flammable in vertical flame-retardancy test. Their char area recorded 1.1${\sim}$11.6 $cm^2$ in 45$^{\circ}$ eckel burner method.

• 설비공학논문집
• /
• 제6권3호
• /
• pp.267-281
• /
• 1994

The Combustion gas behavior induced by fire in a building is numerically investigated. The typical building for this analysis is partially divided by a vertical baffle projecting from the ceiling. The solution procedure includes the low Reynolds number ${\kappa}-{\varepsilon}$ model for the turbulent flow and the discrete ordinates method is used for the calculation of radiative heat transfer equation. The effects of the location and size of fire source and baffle length on velocity and temperature distributions, species mass fraction and flame location are analyzed. As the results of this study, it is found that the case when the fire source is located at the vertical wall is more dangerous than at the bottom wall in view of the combustion products and flame location. It is also found that the radiation effect cannot be neglected in analyzing the building in fire.

• 한국화재소방학회:학술대회논문집
• /
• 한국화재소방학회 1998년도 추계학술발표회 논문 초록집
• /
• pp.41-46
• /
• 1998

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
• /
• pp.208-212
• /
• 2001

In this paper, characteristics of the ac and do flashover voltages in the vertical air gap of a needle-plane, sphere-plane and rod-plane electrode system were investigated when the combustion flames were present near the high-voltage electrode. As the results of an experimental we found that the reduction of flashover voltages characteristics with the vertical distance caused, in comparison with the no-flame case were about 1/3 times when a short sap d=1[cm] and 2[cm] of the ac voltages were applied. Also, flashover voltages characteristics of the do negative polarity under sphere-plane and rod-plane electrode system with the combustion flame were increased about two times than those of the do positive polarity.

• 한국화재소방학회논문지
• /
• 제26권1호
• /
• pp.102-112
• /
• 2012

본 연구에서는 건축물 외장재 화재 시 수직화재에 대해 화염의 수직확산 방지 및 지연을 위한 외벽방호 스프링클러 설비 구성에 관하여 연구하였다. 본 연구에 앞서 관련 수직확산 방지용 스프링클러 헤드의 개발이 이루어졌으며, 적용된 스프링클러시스템은 NFPA13의 연소확대방지시스템에 명기된 방사압 0.05 MPa와 유량 60 l/min를 도입하여 적용하였다. 시스템 설계를 통하여 소방대상물에 적용하였으며 본 시스템은 감지시스템과 연동하여 자동과 수동으로 작동하도록 하였다. 또한 외벽방호 스프링클러 설비의 유용성 평가를 위해 실물실험을 실시하여 외벽의 냉각효과와 화재의 지연을 확인할 수 있었다.

• 한국응용과학기술학회지
• /
• 제23권4호
• /
• pp.328-339
• /
• 2006

The PU flame-retardant coatings (TTBAH, ATBAH-10C, -20C, and -30C) were prepared using the synthesized ATBAs and HDI-trimer as curing agent at room temperature. The physical properties of PU flame-retardant coatings with chlorine and phosphorus were inferior to those with phosphorus only and the properties were getting worse with increasing chlorine content. Flame retardancy was tested with three methods. With the vertical method, complete combustion time of ATBAHs were $259^{\sim}347$ seconds, which means that the prepared coatings are good flame-retardant. With the $45^{\circ}$ Meckel burner method, char lengths of the three prepared coatings were less than 2.9 cm, which indicates that the prepared coatings are first grade. With the limiting oxygen index (LOI) method, the LOI values of the three prepared coatings were in the range of $30^{\sim}35%$, which proves good flame retardancy of the prepared coatings. from the result of flame retardancy tests of the specimens that contain the same amounts of flame retarding compounds. it was found that the coatings containing both phosphorus and chlorine show higher flame retardancy than the coatings containing only phosphorus. This indicates that there exists, some synergy effect between coexisting phosphorus and chlorine.

• 폴리머
• /
• 제26권2호
• /
• pp.200-208
• /
• 2002

난연성분인 트리클로로벤조산(TBA)의 함량을 10, 20, 30 wt%로 변화시키면서 아디프산, 1,4-부탄디올 및 트리메틸올프로판과 축중합을 하여 트리클로로 락톤 변성폴리에스테르(TAPTs)를 합성한 후에, TAPT류와 이소시아네이트인 Desmodur IL을 블렌드하여 2성분계 폴리우레탄 난연 도료를 제조하였다. 제조된 난연도료의 도막물성을 측정한 결과, 결코 비난연도료보다 물성이 떨어지지 않음을 알았다. 또한 난연도료의 3종류 난연성 시험결과, 수직법에서 TBA 함량 20 wt% 이상에서 불꽃에 타지 않았고, LOI 연소성 시험에서 TBA 함량 20, 30 wt%시 25%와 27%의 LOI값을 나타내었으며, $45^{\circ}$ Meckel burner법에서는 탄화길이가 3.6-5.2 cm로서 난연 1급에 해당되었으므로 이를 미루어 난연효과가 좋은 난연도료임을 알 수 있었다.

• 한국전기전자재료학회논문지
• /
• 제28권1호
• /
• pp.51-56
• /
• 2015

The object of this study is to obtain the optimum mix proportion of halogen free compound with flame resistance and, for the purpose, thermal/electrical characteristics test are conducted using compatibilizing agents, flame resistance agents, hydroxide aluminum, sunscreen, antioxidant and silicon oil on the base resin of linear low density polyethylene (LLDPE), Ethylene vinyl acetate copolymer (EVA). Existing compound method accompanies many requirements to be satisfied including a lot of addition of flame resistance agents, prohibition of impact on mixing capability with base and property and etc. In this study, different from the existing method, the optimum mix proportion is determined and experimented by adding nano clay. Oxygen index test shows no difference between specimens while T-6, T-9 shows oxygen index of 29[%] and 26[%], respectively. This is concluded that hydroxide aluminum, which is a flame resistance agent, leads low oxygen index. From UL94-V vertical flame resistance test, the combustion behavior is determined as V-0, Fail based on UL94-V decision criteria. Viscometry shows low measurements in specimens with separate addition of compatibilizing agents or nano clay. Volume resistivity test shows low measurement mainly in specimens without compatibilizing agents. Therefore, with the flame resistance compound shows better performance for thermal/electrical property and the optimum mix proportion are achieved among many existing materials.