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Preparation of Reactive Flame Retardant Coatings Containing Phosphorus II. Preparation and Characterization of Polyurethane Coatings

반응형 인계 난연도료의 제조 II. 폴리우레탄 도료의 제조 및 도막특성

  • Kim, Sung-Rae (Div. of Ceramic and Chemical Engineering, Myongji University) ;
  • Park, Hyong-Jin (Div. of Ceramic and Chemical Engineering, Myongji University) ;
  • Jung, Choong-Ho (Korea Institute of Ceramic Engineering and Technology) ;
  • Park, Hong-Soo (Div. of Ceramic and Chemical Engineering, Myongji University) ;
  • Im, Wan-Bin (Agency for Technology and Standards)
  • 김성래 (명지대학교 공과대학 화학공학과) ;
  • 박형진 (명지대학교 공과대학 화학공학과) ;
  • 정충호 (요업기술원) ;
  • 박홍수 (명지대학교 공과대학 화학공학과) ;
  • 임완빈 (기술표준원)
  • Published : 2003.06.30

Abstract

Two-component polyurethane flame retardant coatings (ATTBC) were prepared by blending polyisocyanate (TDI-adduct) with ATTBs mentioned at the previous paper. Most of the physical properties of the flame retardant coatings were comparable to those of non-flame retardant coatings. Especially, the hardness, impact resistance, and accelerated weathering resistance were remarkably improved with the increase of the content of 1,4-butanediol. Coatings containing 10 and 15 wt% 1,4-butanediol, ATTBC-10C and ATTBC-15C, were not flammable in vertical flame-retardancy test. Their char area recorded 1.1${\sim}$11.6 $cm^2$ in 45$^{\circ}$ eckel burner method.

Keywords

References

  1. R. S. Williams, Brit. Patent, 2280634 Al (1995)
  2. Y. Tajima, Jpn, Patent, 07008899 A2 (1995)
  3. V. M. Bhatnagar and J. M. Vergnaud, Fire &if j., 4, 163 (1981)
  4. J. R. Brown, Z. Mathys, S. Z. Riddell, and L. V. Wake, Fire Mater., 19, 109 (1995) https://doi.org/10.1002/fam.810190303
  5. K. Hotsuta, Y. Shibuya, and H. Hachitani, Jpn. Patent, 06071802 A2 (1994)
  6. R. S. Rose, J. Coated Fabr., 23, 254 (1994) https://doi.org/10.1177/152808379402300402
  7. K. Nagao, J. Sawa, and R. Ito, Jpn. Patent, 06264398 A2 (1994)
  8. C. Manas and K. R. Salil, 'Plastics Technology Handbook', 2nd ed., pp.493-506, Marcel Dekker Inc., New York (1993)
  9. W. C. Kuryla and A. J. Papa, 'Flame Retardancy of Polymeric Materials' , vol.3, pp. 1-61, Marcel Dekker, Inc., New York (1980)
  10. Y. W. Chen, J. R. Chuang, Y. C. Yang, C. Y. Li, and Y. S. Chiu, J. Appl. Polym. Sci., 69, 115 (1998) https://doi.org/10.1002/(SICI)1097-4628(19980705)69:1<115::AID-APP13>3.0.CO;2-Z
  11. Z. L. Ma, W. G. Zhao, Y. F. Liu, and J. R. Shi, J. Appl. Polym. Sci., 66, 471(1997) https://doi.org/10.1002/(SICI)1097-4628(19971017)66:3<471::AID-APP6>3.0.CO;2-M
  12. Y. Okano, S. Oosuga, and K. Oomori, Jpn. Patent, 07109377 A2 (1995)
  13. P. I. Kordomenos, K. C. Frisch, H. X. Xiao, and N. Sabbah, J. Coat Technol., 57(723), 23 (1985)
  14. D. J. Chung, C. H. Jung, H. S. Park, T. O. Kim, and S. J. Park, J. Kor. Oil Chem. Soc., 20, in press
  15. P. K. T. Oldring and G. Hayward, 'Resins for Surface Coatings' , vol. lll, pp. 27-31, Selective Industrial Training Associates, London (1987)
  16. C. P. Fenimore and F. J. Martin, Mod. Plast., 44, 141 (1966)
  17. W. B. Im and H. S. Park, J. Kor. Oil Chem. Soc., 15, 77 (1998)