• 제목/요약/키워드: Vapor transport

검색결과 312건 처리시간 0.025초

PVT 법으로 성장된 AlN 단결정의 결정상에 관한 연구 (A study on the crystalline phases of AlN single crystals grown by PVT method)

  • 강승민
    • 한국결정성장학회지
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    • 제24권2호
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    • pp.54-58
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    • 2014
  • PVT(물리 기상 이동법, Physical Vapor Transport) 법을 적용하여 질화알루미늄(AlN, Aluminum Nitride) 단결정을 성장하였으며, 성장된 결정의 결정성과 성장 온도에 따른 상에 대하여 고찰하였다. 성장된 단결정은 광학현미경을 이용하여 결정의 상을 관찰하였고, 관찰된 결과를 비교 분석하여 본 실험에 적용된 성장 장치에서의 최적의 성장 온도 조건을 설정할 수 있었다. 본 연구에서는 AlN 단결정 성장 결과를 비교 고찰하여 보고하고자 한다.

직경 3인치의 AlN 단결정 성장에 관한 연구 (A study on the growth of 3 inch grade AlN crystal)

  • 강승민
    • 한국결정성장학회지
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    • 제29권3호
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    • pp.140-142
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    • 2019
  • 자외선 LED용 기판소재로 응용가능한 AlN(질화알루미늄) 단결정을 물리기상이동법(Physical Vapor Transport Method)으로 성장하기 위해 성장 거동을 조사하였다. 다결정의 종자결정을 사용하였으며, 직경은 3인치급이었고, 120시간 동안 성장공정을 수행하여 길이 약 4 mm의 다결정상을 얻었다. 본 연구에서는 성장 조건과 대형의 도가니를 사용하였을 경우의 성장 거동에 대하여 고찰하여 보고자 하였다.

고감성 의류용 복합사 직물의 수분증기 및 열이동 특성 -실험방법에 따른 수분증기 및 열이동- (Water Vapor and Thermal Transmission Properties of Hybrid Yarns Fabrics for High Emotional Garments -Water Vapor and Heat Transport according to Experimental-Method-)

  • 김승진;김현아
    • 한국의류학회지
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    • 제41권1호
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    • pp.84-97
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    • 2017
  • Water vapor and thermal transmission properties of high emotional garments are important to evaluate wear comfort; in addition, the measuring methods of these properties are also critical for breathable and warm suit fabrics. In this study, the water vapor and thermal properties of composite yarn fabrics made of CoolMax, Tencel, and Bamboo fibers with filaments were measured and compared according to the measuring method. Water Vapor Transmittance (WVT) of the fabric woven by the sheath/core composite yarn in the warp direction was the highest due to the small staple fiber volume in the sheath/core yarn structure and high air voids in the sheath/core yarn fabrics. This property was also the highest in fabrics woven by bamboo staple yarns in the weft direction, and was the lowest on hi-multi filament fabrics. However, water vapor resistance ($R_{ef}$) of these fabrics by KSK ISO 11092 showed the opposite results to the water vapor transmittance method ($CaCl_2$ method); in addition, its correlation coefficient was low. The correlation coefficient between $R_{ef}$ and the drying rate was 0.719; therefore, the measurement mechanism of $R_{ef}$ is analogous to the drying property measurement. The thermal conductivity of the fabrics woven with compact staple yarn showed a high value; however, the hi-multi filament fabric showed low thermal conductivity. Therefore, fiber characteristics affect thermal properties more than yarn structure. The correlation between thermal property and moisture transport was also low. This study showed that: water vapor transmittance was active at the loose yarn structure, dry heat transport was vigorous at the compact yarn structure, and heat transport was affected more by fiber characteristics than yarn structure. In conclusion, sheath/core composite yarns were relevant to the high absorptive cool suit along with siro-fil and CoolMax/Bamboo staple yarns that were relevant to the heat diffusive cool suit.

편성물의 섬유의 종류, 실의 굵기 및 니트타입에 따른 투습완충능력 (Effect of Fiber Content, Yarn Size and Construction of Knit Fabrics on the Buffering Capacity against Water Vapor)

  • 유화숙;허윤숙;김은애
    • 한국의류학회지
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    • 제20권1호
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    • pp.228-238
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    • 1996
  • The purpose of this study was to evaluate the effect of chacteristics of knit fabrics on the microclimate of the skin simulating system. To determine the effect of characteristics of knit fabrics, vapor state of sweat pulse was simulated in the closed system. Different contents of fibers such as cotton, wool and polyester with different yarn size and knit types were chosen for specimens. The changes of humidity and temperature of air layer in the simulated systems were measured. Buffering indices, $K_d$ and $\beta_r$, were determined by considering $\alpha_p, \DeltaP_{max}, t_{max}, and tan\beta$. Physical properties of knit fabrics such as thickness, porosity, air resistance and moisture vapor transport were measured. Results showed that vapor pressure of wool was lower than cotton or polyester This was attributed to the hydrophilicity of wool which absorbed moisture rather quickly and retained in the knit fabric. The time to decrease vapor pressure was faster for polyester than cotton or wool. As a result, $K_d$ was in the order of wool> polye, item> cotton. $\beta_r$ of wool was rower than cotton or polyester due to its lowers porosity and slower desorption rate. For the yarn size, $K_d$ was in the order of 80's> 60's> 30's; thinner and lighter yarn showed better water vapor transport property. For knit type, buffering capacity of single jersey was better than interlock knit fabric. Statistical analysis showed that the air permeability was the most influential factor far the water vapor transport properties.

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Effects of impurity (N2) on thermo-solutal convection during the physical vapor transport processes of mercurous chloride

  • Kim, Geug-Tae;Kim, Young-Joo
    • 한국결정성장학회지
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    • 제20권3호
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    • pp.117-124
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    • 2010
  • For Ar=5, Pr=1.18, Le=0.15, Pe=2.89, Cv=1.06, $P_B$=20 Torr, the effects of impurity $(N_2)$ on thermally and solutally buoyancy-driven convection ($Gr_t=3.46{\times}10^4$ and $Gr_s=6.02{\times}10^5$, respectively) are theoretically investigated for further understanding and insight into an essence of thermo-solutal convection occurring in the vapor phase during the physical vapor transport. For $10K{\leq}{\Delta}T{\leq}50K$, the crystal growth rates are intimately related and linearly proportional to a temperature difference between the source and crystal region which is a driving force for thermally buoyancy-driven convection. Moreover, both the dimensionless Peclet number (Pe) and dimensional maximum velocity magnitudes are directly and linearly proportional to ${\Delta}T$. The growth rate is second order-exponentially decayed for $2{\leq}Ar{\leq}5$. This is related to a finding that the effects of side walls tend to stabilize the thermo-solutal convection in the growth reactor. Finally, the growth rate is found to be first order exponentially decayed for $10{\leq}P_B{\leq}200$ Torr.

Influence of thermo-physical properties on solutal convection by physical vapor transport of Hg2Cl2-N2 system: Part I - solutal convection

  • Kim, Geug-Tae;Kim, Young-Joo
    • 한국결정성장학회지
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    • 제20권3호
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    • pp.125-132
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    • 2010
  • For typical governing dimensionless parameters of Ar = 5, Pr = 1.16, Le = 0.14, Pe = 3.57, Cv = 1.02, $Gr_s=2.65{\times}10^6$, the effects of thermo physical properties such as a molecular weight, a binary diffusivity coefficient, a partial pressure of component B on solutally buoyancy-driven convection (solutal Grashof number $Gr_s=2.65{\times}10^6$) are theoretically investigated for further understanding and insight into an essence of solutal convection occurring in the vapor phase during the physical vapor transport of a $Hg_2Cl_2-N_2$ system. The solutally buoyancy-driven convection is significantly affected by any significant disparity in the molecular weight of the crystal components and the impurity gas of nitrogen. The solutal convection in a vertical orientation is found to be more suppressed than a tenth reduction of gravitational accelerations in a horizontal orientation. For crystal growth parameters under consideration, the greater uniformity in the growth rate is obtained for either solutal convection mode in a vertical orientation or thermal convection mode in horizontal geometry. The growth rate is also found to be first order exponentially decayed for $10{\leq}P_B{\leq}200$ Torr.

시판 내의류소재의 수분특성 및 착용감에 관한 연구 (I) -시판 내의류 소재의 수분특성- (A Study on Moisture Related Properties and Human Sensations of Underwear (1) -A Study on Water and Water Vapor Transport characteristics of Underwear Fabrics-)

  • 이순원
    • 대한가정학회지
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    • 제26권4호
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    • pp.1-13
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    • 1988
  • The purpose of this study is to investigate water and after vapor transport characteristics of underwear fabrics. Experimental materials were cotton woven fabric and cotton knitted fabric, nylon tricot (untreated and hydrophilic finished) and cotton/polyester/cotton triple layer. Cotton knitted fabric have three types of knit structure (interlock, rib, plain stitch) and knit with either 38's or 60's combed yarn. And cotton woven fabric have plain weave with 60's combed yarn. As experimental methods, vapor cup test, dynamic method, vertical wicking test and transplanar uptake test were used. The results are as follows. 1) In cotton specimens, the order of water vapor transpiration (wvt) was plain > rib > interlock in the same yarn diameter. The knit fabric of thinner yarn showed the better wvt among the same knit structure. 2) In cotton specimens, the order of water absorbency was interlock > rib > plain in the same yarn diameter. the knit fabric of thicker yarn showed the better absorbency among the same knit structure. 3) When knit fabric (60's plain) is compared with woven fabric 960's plain), knit fabric showed faster rate of wvt, more amount of uptake and slower rate of water uptake than woven fabric did. 4) When compared untreated nylon with hydrophilic finished nylon, hydrophilic finished nylon showed much more water absorbency than untreated nylon did, but showed same rate of wvt. 5) The water transport characteristics of triple layer underwear fabric showed that the thinner and the lighter one, the better wvt and absorbency did.

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Heat transfer study of double diffusive natural convection in a two-dimensional enclosure at different aspect ratios and thermal Grashof number during the physical vapor transport of mercurous bromide (Hg2Br2): Part I. Heat transfer

  • Ha, Sung Ho;Kim, Geug Tae
    • 한국결정성장학회지
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    • 제32권1호
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    • pp.16-24
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    • 2022
  • A computational study of combined thermal and solutal convection (double diffusive convection) in a sealed crystal growth reactor is presented, based on a two-dimensional numerical analysis of the nonlinear and strongly coupled partial differential equations and their associated boundary conditions. The average Nusselt numbers for the source regions are greater than those at the crystal regions for 9.73 × 103 ≤ Grt ≤ 6.22 × 105. The average Nusselt numbers for the source regions varies linearly and increases directly with the thermal Grashof number form 9.73 × 103 ≤ Grt ≤ 6.22 × 105 for aspect ratio, Ar (transport length-to-width) = 1 and 2. Additionally, the average Nusselt numbers for the crystal regions at Ar = 1 are much greater than those at Ar = 2. Also, the occurrence of one unicellular flow structure is caused by both the thermal and solutal convection, which is inherent during the physical vapor transport of Hg2Br2. When the aspect ratio of the enclosure increases, the fluid movement is hindered and results in the decrease of thermal buoyancy force.

ZnSe 단결정 성장과 결정결함 (Growth and defects of ZnSe crystal)

  • 이성국;박성수;김준홍;한재용;이상학
    • 한국결정성장학회지
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    • 제7권1호
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    • pp.76-80
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    • 1997
  • 직경 55 mm의 ZnSe 단결정을 수소분위기에서 seeded chemical vapor transport법에 의해 성장하였고, 성장 parameter들이 결정 결함에 미치는 영향을 조사하였다. Chemical etching에 의한 EPD 측정, X-ray rocking curve 측정, photolumlnescence 측정으로 성장된 단결정의 특성을 평가하였다.

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수증기안정동위원소를 이용한 해안지역 수분의 이동경로에 관한 연구 (Moisture Transport Observed by Water Vapor Isotopes in the Vicinity of Coastal Area, Incheon, Korea)

  • 이정훈;최희진;오진만;나운성;곽호제;허순도
    • 자원환경지질
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    • 제46권4호
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    • pp.339-344
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    • 2013
  • 물의 순환의 복잡한 기작을 이해하는 데 수증기동위원소는 중요한 단서를 제공할 수 있으며 지구과학의 다양한 영역(고기후학, 수리지질학, 대기학, 해양학 및 생태학)에 적용될 수 있다. 수분의 전지구적 또는 지역적 이동에 대한 연구는 물의 순환 및 대기에서의 에너지이동을 좀 더 잘 이해하는 데 도움을 줄 것이다. 본 연구에서는 해안근처에서의 수분의 이동을 파악하기 위해서 태풍 볼라벤이 한반도를 통과하는 기간동안(2012년 8월 27일부터 8월 29일까지) 수증기의 안정동위원소를 극지연구소에 설치된 동위원소분석기를 이용하여 측정하였다. 수분동위원소의 두 동위원소의 선형관계식($D=7.8x^{18}O+10.1$)으로부터 해양 기원의 수증기가 증발에 의해 이동되어 측정되었음을 알 수 있었다. 날씨가 맑을 때는 해양으로부터 증발되어 다른 물리적인 변동없이 직접 이동된 수증기의 동위원소 조성(산소동위원소, ${\delta}^{18}O$=-14‰)을 보여 주었으며, 태풍이 통과하면서 수분동위원소의 값은 10‰ 정도 낮은 값을 보였다. 태풍의 통과로 인해 상대습도는 증가하였으며 수분동위원소값은 감소하는 소위 "우량효과(amount effect)"를 보여주었다.