• Title/Summary/Keyword: Vapor pressure of water

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Phase Equilibrium of the Carbon Dioxide and Methane Hydrate in Silica Gel Pores and Thermodynamic Prediction (실리카겔 공극에서의 이산화탄소 및 메탄 하이드레이트 상평형 측정 및 열역학적 예측)

  • Kang, Seong-Pil
    • New & Renewable Energy
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    • v.3 no.2 s.10
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    • pp.47-52
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    • 2007
  • Hydrate phase equilibrium for the binary $CO_{2}$+water and $CH_{4}$+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal nm pore size were nearly identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

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Hygroscopic Properties of Light-Frame Wall with Different Assemblies

  • Kim, Se-Jong;Park, Chun-Young;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.2
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    • pp.22-29
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    • 2006
  • On purpose to reduce accumulated moisture and to prevent moisture condensation in a light-frame wall, thermal characteristics and moisture behaviors were investigated for four different wall assemblies; a) typical wall, b) addition of vapor retarder between the insulation and the gypsum board, c) addition of air gap for natural ventilation behind the siding, d) composition with b) and c). Each wall was tested under two climate conditions; 1) $20^{\circ}C$, 50% RH (indoor) and $30^{\circ}C$, 85% RH (outdoor), 2) $30^{\circ}C$, 85% RH (indoor) and $20^{\circ}C$, 50% RH (outdoor).The results showed that the typical wall assembly had poor resistance against moisture intrusion from the inside of building. Outdoor and indoor humidity caused the moisture condensations on the inside of the siding and the back surface of the sheathing respectively. The addition of a vapor retarder did not give significant improvement in preventing the moisture intrusion.

PWR Hot Leg Natural Circulation Modeling with MELCOR Code

  • Park, Jae-Hong;Lee, Jong-In;Randall. K. Cole;Randall. O. Gauntt
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.10a
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    • pp.772-777
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    • 1997
  • Previous MELCOR and SCDAP/RELAP5 nodalizations for simulating the counter-current, natural circulation behavior of vapor flow within the RCS hot legs and SG U-tubes when core damage progress can not be applied to the steady state and water-filled conditions during the initial period of accident progression because of the artificially high loss coefficients in the hot legs and SG U-tubes which were chosen from results of COMMIX calculation and the Westinghouse natural circulation experiments in a 1/7-scale facility for simulating steam natural circulation behavior in the vessel and in the hot leg and SG during the TMLB' scenrio. The objective of this study is to develop a natural circulation modeling which can be used both for the liquid flow condition at steady state and for the vapor flow condition at the later period of in-vessel core damage. For this, the drag forces resulting from the momentum exchange effects between the two vapor streams in the hot leg was modeled as a pressure drop by pump model. This hot leg natural circulation modeling of MELCOR was able to reproduce similar mass flow rates with those predicted by previous models.

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Analysis of Heat and Mass Transfer on Helical Absorber (헬리컬 흡수기의 흡수 열물질전달 해석)

  • Gwon, O-Gyeong;Im, Jong-Geuk;Yun, Jeong-In;Kim, Seon-Chang;Yun, Jae-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.11
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    • pp.1428-1436
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    • 2000
  • The absorption of vapor involves simultaneous heat and mass transfer in the vapor/liquid system. In this paper, a numerical study for vapor absorption process into LIBr-H$_2$O solution film flowing over helical absorber has been carried out. Axisymmetric cylindrical coordinate system was adopted to model the helical tube and the transport equations were solved by the finite volume method. The effects of operating conditions, such as the cooling water temperature. the system pressure, the film Reynolds number and the solution inlet concentration have been investigated in view of the absorption mass flux and the total absorption mass flux and the total absorption rate. The results for the temperature and concentration profiles, as well as the local absorption mass flux at the helical absorber are presented. It is shown that solution inlet concentration affected other than operation conditions for a mass flux.

Effeet of Al2O3, MgO and SiO2 on Sintering and Hydration Behaviors of CaO Ceramics

  • Kim, Do-Kyung;Cho, Churl-Hee;Goo, Bong-Jin;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.39 no.6
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    • pp.528-534
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    • 2002
  • CaO ceramics were prepared by conventional sintering process and their hydration behaviors were evaluated by measuring weight increment on saturated water vapor pressure at ambient temperature. CaCO$_3$ and limestone were used as CaO source materials and $Al_2$O$_3$, MgO and SiO$_2$ were added as sintering agents. $Al_2$O$_3$ was a liquid phase sintering agent to increase densification and grain growth rates, whereas MgO and SiO$_2$, densification and grain growth inhibitors. Regardless of composition, all of the prepared CaO ceramics showed the improved hydration resistance as bulk density increased. Especially, when bulk density was more than 3.0 g/㎤, there was no weight increment after 120 h of hydration. Therefore, to decrease contact area between CaO and water vapor by increasing bulk density with the $Al_2$O$_3$ sintering additive was effective for the improvement of CaO hydration resistance.

Studies on Food Preservation by Controlling Water Activity 1. Measurement of Sorption Isotherm of Dried Filefish Muscle by Equilibration in Dynamic Stream of Conditioned Air (식품보장과 수분활성에 관한 연구 1. 조절기류에 의한 건조말쥐치육의 등온흡습곡선의 측정)

  • HAN Bong-Ho;CHOI Soo-Il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.189-193
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    • 1981
  • An apparatus for continuous measurements of sorption isotherm of dried food was manufactured to shorten the time required for equilibration. The apparatus was so designed that the temperature, air velocity and relative humidity in the experimental chamber could be controlled. The use of dynamic stream of conditioned air with a velocity of 0.2m/sec, instead of static atmosphere, allowed a faster equilibration of dried filefish muscle at $25^{\circ}C$. The mean time necessary for the equilibration of dried filefish muscle at the water activity of a given state to a higher water activity was about 45 hours. The monolayer moisture content of dried filefish muscle calculated from BET-equation was 0.092 kg water /kg dry matter at $25^{\circ}C$.

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Effect of membrane deformation on performance of vacuum assisted air gap membrane distillation (V-AGMD)

  • Kim, Yusik;Choi, Jihyeok;Choi, Yongjun;Lee, Sangho
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.51-62
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    • 2022
  • Vacuum-assisted air gap membrane distillation (V-AGMD) has the potential to achieve higher flux and productivity than conventional air gap membrane distillation (AGMD). Nevertheless, there is not much information on technical aspects of V-AGMD operation. Accordingly, this study aims to analyze the effect of membrane deformation on flux in V-AGMD operation. Experiments were carried out using a bench-scale V-AGMD system. Statistical models were applied to understand the flux behaviors. Statistical models based on MLR, GNN, and MLFNN techniques were developed to describe the experimental data. Results showed that the flux increased by up to 4 times with the application of vacuum in V-AGMD compared with conventional AGMD. The flux in both AGMD and V-AGMD is affected by the difference between the air gap pressure and the saturation pressure of water vapor, but their dependences were different. In V-AGMD, the membranes were found to be deformed due to the vacuum pressure because they were not fully supported by the spacer. As a result, the deformation reduced the effective air gap width. Nevertheless, the rejection and LEP were not changed even if the deformation occurred. The flux behaviors in V-AGMD were successfully interpreted by the GNN and MLFNN models. According to the model calculations, the relative impact of the membrane deformation ranges from 10.3% to 16.1%.

Multi-phase Flow Modeling of Vapor Explosion Propagation (증기폭발 전파과정 해석을 위한 다상유동 모델 개발)

  • Park, I. K.;Park, G. C.;K. H. Bang
    • Nuclear Engineering and Technology
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    • v.28 no.2
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    • pp.103-117
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    • 1996
  • A mathematical model of vapor explosion propagation is presented. The model predict two-dimensional, transient flow fields and energies of the four fluid phases of melt drop, fragmented debris, liquid coolant and vapor coolant by solving a set of governing equations with the relevant constitutive relations. These relations include melt fragmentation, coolant-phase-change, and heat and momentum exchange models. To allow thermodynamic non-equilibrium between the coolant liquid and vapor, an equation of state for oater is uniquely formulated. A multiphase code, TRACER, has been developed based on this mathematical formulation. A set of base calculations for tin/water explosions show that the model predicts the explosion propagation speed and peak pressure in a reasonable degree although the quantitative agreement relies strongly on the parameters in the constitutive relations. A set of calculations for sensitivity studies on these parameters have identified the important initial conditions and relations. These are melt fragmentation rate, momentum exchange function, heat transfer function and coolant phase change model as well as local vapor fractions and fuel fractions.

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AN EXPERIMENTAL STUDY ON POST-CHF HEAT TRANSFER FOR LOW FLOW OF WATER IN A $3\times3$ ROD BUNDLE

  • MOON SANG-KI;CHUN SE-YOUNG;CHO SEOK;KIM SE-YUN;BAEK WON-PIL
    • Nuclear Engineering and Technology
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    • v.37 no.5
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    • pp.457-468
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    • 2005
  • An experimental study on post-CHF heat transfer has been performed with a $3\times3$ rod bundle using a vertical steam-water two-phase flow at low flow conditions. The effects of various parameters on the post-CHF heat transfer are investigated and the reasons for the parametric effects are discussed. As the heat transfer regime changes from CHF to post-CHF, the radial wall temperature distribution is changed depending on the pressure and the mass flux conditions. The superheat of the fluid increases considerably with an increase of the wall temperature (or heat flux) and with a decrease of the mass flux. This implies, indirectly, a strong thermal non-equilibrium at high wall temperature and low mass flux conditions. In order to improve the prediction accuracy of the existing post-CHF correlations, it is necessary to perform more experiments, particularly direct measurement of the vapor superheat, and to modify the correlation by considering a strong thermal non-equilibrium at low flow and low pressure conditions.

A Research on the Conception Change Process of Secondary School Chemistry Major Teachers Related to the Evaporation Phenomena in the Air (대기 중의 증발 현상에 대한 중등학교 화학전공 교사들의 개념 변화 과정에 대한 연구)

  • Yang, Gee-Chang;Paik, Seoung-Hey
    • Journal of the Korean Chemical Society
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    • v.52 no.1
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    • pp.84-95
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    • 2008
  • In this study, preconceptions held by chemistry major secondary school science teachers were searched in relation to explanations of water evaporation phenomena with phase equilibrium diagrams. 25 chemistry major science teachers were selected to complete questionnaires developed in this study and 6 among of them were selected to participate in follow-up interviews. Among these, 10 participants were selected for an evaluation of the change of their preconceptions through lessons developed in this study. From the results, it was found that many teachers believed that the phase equilibrium diagram could not explain water evaporation phenomena. They also thought that there was no relation between vapor pressure and the vertical axis of the phase equilibrium diagram. However, after the lessons in earth science, they recognized that the vapor pressure curve of the phase equilibrium diagram could be explained by adopting a saturated vapor curve. Because they had known the process of application the conceptions of saturated situation, nonsaturated situation, process of equilibrium movement in saturated vapor curve. They could understand natural phenomena such as evaporation with the phase equilibrium diagram through a change in their conceptions as guided from science lessons integrating earth science and chemistry.