• Title/Summary/Keyword: Van der Waals Forces

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Estimation of Surface Forces in Micro Rough Surface Contacts

  • Kim, Doo-In;Ahn, Hyo-Sok;Choi, Dong-Hoon
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.63-64
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    • 2002
  • In a micro-scale contact, surface forces such as capillary force and van der Waals Interaction significantly Influence the contact between asperities of rough surfaces. Little is, however, known about the variation of these surface forces as a function of chemical property of the surface (hydrophilicity), relative humidity and deformation of asperities In the real area of contact. A better understanding of these surface forces is of great necessity in order to find an optimal solution for reducing friction and adhesion of micro surfaces. We proposed an effective method to analyze capillary and van der Waals forces In nano-scale contact. In this method, Winklerian foundation model was employed to analyze the contact of rough surfaces that were obtained from atomic force microscopy (AFM) height Images. Self-mated contact of diamond-like-carbon (DLC) coatings was analyzed, as an example, by the proposed model. It was shown that the capillary force was significantly influenced by relative humidify and wet angle of the DLC surface. The deformation of asperities to a critical magnitude by external loading led to a considerable increase of both capillary and van der Waals forces.

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Analysis of Surface Forces in Micro Contacts between Rough Surfaces (거친 표면간의 미세 접촉에서의 표면력 해석)

  • Kim, Doo-In;Ahn, Hyo-Sok;Choi, Dong-Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.10
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    • pp.2180-2186
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    • 2002
  • In a micro-scale contact, capillary force and van der Waals interaction significantly influence the contact between asperities of rough surfaces. Little is, however, known about the variation of these surface forces as a function of chemical property of the surface (wet angle), relative humidity and deformation of asperities in the real area of contact. A better understanding of these surface forces is of great necessity in order to find a solution for reducing friction and adhesion of micro surfaces. The objective of this study is to investigate the surface forces in micro-scale rough surface contact. We proposed an effective method to analyze capillary and van der Waals forces in micro-scale contact. In this method, Winkler spring model was employed to analyze the contact of rough surfaces that were obtained from atomic force microscopy (AFM) height images. Self-mated contact of DLC(diamond like carbon) coatings was analyzed, as an example, by the proposed model. It was shown that the capillary force was significantly influenced by relative humidity and wet angle of the DLC surface. The deformation of asperities to a critical magnitude by external loading led to a considerable increase of both capillary and van der Waals forces.

Surface energy assisted gecko-inspired dry adhesives

  • Rahmawan, Yudi;Kim, Tae-Il;Kim, Seong-Jin;Lee, Kwang-Ryeol;Moon, Myoung-Woon;Suh, Kahp-Yang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.449-449
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    • 2011
  • We reported the direct effect of intrinsic surface energy of dry adhesive material to the Van der Waals and capillary forces contributions of the total adhesion force in an artificial gecko-inspired adhesion system. To mimic the gecko foot we fabricated tilted nanohairy structures using both lithography and ion beam treatment. The nanohairy structures were replicated from Si wafer mold using UV curable polymeric materials. The control of nanohairs slanting angles was based on the uniform linear argon ion irradiation to the nanohairy polymeric surface. The surface energy was studied utilizing subsequent conventional oxygen ion treatment on the nanohairy structures which resulted in gradient surface energy. Our shear adhesion test results were found in good agreement with the accepted Van der Waals and capillary forces theory in the gecko adhesion system. Surface energy would give a direct impact to the effective Hamaker constant in Van der Waals force and the filling angle (${\varphi}$) of water meniscus in capillary force contributions of gecko inspired adhesion system. With the increasing surface energy, the effective Hamaker constant also increased but the filling angle decreased, resulting in a competition between the two forces. Using a simple mathematical model, we compared our experimental results to show the quantitative contributions of Van der Waals and capillary forces in a single adhesion system on both hydrophobic and hydrophilic surfaces. We found that the Van der Waals force contributes about 82.75% and 89.97% to the total adhesion force on hydrophilic and hydrophobic test surfaces, respectively, while the remaining contribution was occupied by capillary force. We also showed that it is possible to design ultrahigh dry adhesive with adhesion strength of more than 10 times higher than apparent gecko adhesion force by controlling the surface energy and the slanting angle induced-contact line of dry adhesive the materials.

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Flow-induced Instability of Multi-wall Carbon Nanotubes for Various Boundary Conditions (경계조건에 따른 다중벽 탄소나노튜브의 유체유발 불안정성 변화)

  • Yun, Kyung-Jae;Song, Oh-Seop
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.20 no.9
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    • pp.805-815
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    • 2010
  • This paper studies the influence of internal moving fluid and flow-induced structural instability of multi-wall carbon nanotubes conveying fluid. Detailed results are demonstrated for the variation of natural frequencies with flow velocity, and the flow-induced divergence and flutter instability characteristics of multi-wall carbon nanotubes conveying fluid and modelled as a thin-walled beam are investigated. Effects of various boundary conditions, Van der Waals forces, and non-classical transverse shear and rotary inertia are incorporated in this study. The governing equations and three different boundary conditions are derived through Hamilton's principle. Numerical analysis is performed by using extended Galerkin's method which enables us to obtain more exact solutions compared with conventional Galerkin's method. This paper also presents the comparison between the characteristics of single-wall and multi-wall carbon nanotubes considering the effect of van der Waals forces. Variations of critical flow velocity for different boundary conditions of two-wall carbon nanotubes are investigated and pertinent conclusion is outlined.

Field-effect Transistors Based on a Van der Waals Vertical Heterostructure Using CVD-grown Graphene and MoSe2 (화학기상증착법을 통해 합성된 그래핀 및 MoSe2를 이용한 반데르발스 수직이종접합 전계효과 트랜지스터)

  • Seon Yeon Choi;Eun Bee Ko;Seong Kyun Kwon;Min Hee Kim;Seol Ah Kim;Ga Eun Lee;Min Cheol Choi;Hyun Ho Kim
    • Journal of Adhesion and Interface
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    • v.24 no.3
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    • pp.100-104
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    • 2023
  • Van der Waals heterostructures have garnered significant attention in recent research due to their excellent electronic characteristics arising from the absence of dangling bonds and the exclusive reliance on Van der Waals forces for interlayer coupling. However, most studies have been confined to fundamental research employing the Scotch tape (mechanical exfoliation) method. We fabricated Van der Waals vertical heterojunction transistors to advance this field using materials exclusively grown via chemical vapor deposition (CVD). CVDgrown graphene was patterned through photolithography to serve as electrodes, while CVD-grown MoSe2 was employed as the pickup/transfer material, resulting in the realization of Van der Waals heterojunction transistors with interlayer charge transfer effects. The electrical characteristics of the fabricated devices were thoroughly examined. Additionally, we observed variations in the transistor's performance based on the presence of defects in MoSe2 layer.

Analysis of Nano-contact Between Nano-asperities Using Atomic Force Microscopy (나노스케일 표면돌기 간의 미세접촉에 대한 해석)

  • Ahn, Hyo-Sok;Jang, Dong-Young
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.18 no.4
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    • pp.369-374
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    • 2009
  • In micro/nano-scale contacts in MEMS and NEMS, capillary and van der Waals forces generated around contacting micro-asperities significantly influence the performance of concerning device as they are closely related to adhesion and stiction of interacting surfaces. In this regard, it is of prime importance to accurately estimate the magnitude of surface forces so that an optimal solution for reducing friction and adhesion of micro/nano-surfaces may be obtained We introduced an effective method to calculate these surface forces based on topography information obtained from an atomic force microscope. This method was used to calculate surface forces generated in the contact interface formed between diamond-like carbon coating and $Si_3N_4$ ball. This method is shown to effectively demonstrate the influence of capillary force in the contact area, especially in humid atmosphere.

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Study on the Influence of Applied Forces Acting on Small Scale Cantilever Beams (미소 외팔보의 동적해석 시 작용하는 힘들의 영향도에 관한 연구)

  • Kim, Kwan-Yong;Yoo, Hong-hee
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11a
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    • pp.702-707
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    • 2005
  • The equations of motion of the structure, which is a small scale cantilever beam considering electrostatic force, squeeze film damping and van der Waals force are obtained employing Galerkin's method based on Euler beam theory. The influence of each force is investigated fur changing the size of a small scale cantilever beam which assumed uniform shape. Also the forces which are affected by the required size of a small scale cantilever beam for manufacturing are forecasted.

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The Crystal Structure of 2-Methyl-3-(N-trimethyl ammonium)phenol Iodide (2-Methyl-3-(N-trimethyl ammonium)phenol Iodide의 결정 구조)

  • 조성일;윤혜숙;구정회
    • YAKHAK HOEJI
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    • v.24 no.2
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    • pp.135-141
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    • 1980
  • The crystal and molecular structure of 2-methyl-3-(N-trimethyl ammonium)phenol iodide, $C_{10}H_{16}NOI, was determined by X-ray diffraction method. The compound crystallizes in the orthorhombic space group $P_{na2}_{1}$ with a=13.327(3), b=12.496(3), C=7.227(2)A and Z=4. A total of 489 independent observed reflections were collected by the automated Four-circle diffractometer and was solved by heavy atom method and refined by anisotropic block-diagonal least-squares method to the R value of 0.04. The benzene ring is slightly distorted from regular hexagon. The I atom and 2-methyl-3-(N-trimethyl ammonium)phenol group is held together by van der Waals forces in the crystal. Intermolecular hydrogen bond is of the type O-H....I with the length 3.35.angs.. Apart from the hydrogen bonding system the molecules are held together by van der Waals forces in the crystal.

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Investigation on mechanical vibration of double-walled carbon nanotubes with inter-tube Van der waals forces

  • Kumar, B. Ravi
    • Advances in nano research
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    • v.6 no.2
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    • pp.135-145
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    • 2018
  • This work represents the study of the vibration response of the double walled carbon nanotubes (DWCNT) for various boundary conditions. The inner and outer carbon nanotubes are modeled as two individual Euler-Bernoulli's elastic beams interacting each other by Van der waals force. Differential transform method (DTM) is used as a numerical method to solve the governing differential equations and associated boundary conditions. The influence of Winkler elastic medium on vibration frequency is also examined and results are interpreted. MATLAB is used as a tool for solving the governing differential equations. The fundamental natural frequencies are validating with those available in literature and observed a good agreement between them.

Buckling analysis of double walled carbon nanotubes embedded in Kerr elastic medium under axial compression using the nonlocal Donnell shell theory

  • Timesli, Abdelaziz
    • Advances in nano research
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    • v.9 no.2
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    • pp.69-82
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    • 2020
  • In this paper, a new explicit analytical formula is derived for the critical buckling load of Double Walled Carbon Nanotubes (DWCNTs) embedded in Winkler elastic medium without taking into account the effects of the nonlocal parameter, which indicates the effects of the surrounding elastic matrix combined with the intertube Van der Waals (VdW) forces. Furthermore, we present a model which predicts that the critical axial buckling load embedded in Winkler, Pasternak or Kerr elastic medium under axial compression using the nonlocal Donnell shell theory, this model takes into account the effects of internal small length scale and the VdW interactions between the inner and outer nanotubes. The present model predicts that the critical axial buckling load of embedded DWCNTs is greater than that without medium under identical conditions and parameters. We can conclude that the embedded DWCNTs are less susceptible to axial buckling than those without medium.