• Title/Summary/Keyword: Vacuum injection

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Optimization of energy level alignment for efficient organic photovoltaics (에너지 준위 접합 최적화를 통한 유기태양전지 효율 향상법)

  • Lee, Hyunbok
    • Vacuum Magazine
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    • v.2 no.2
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    • pp.12-16
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    • 2015
  • Organic photovoltaics (OPVs) have attracted significant interest in an interdisciplinary research field for the decades as a next-generation photovoltaic device due to their unique advantages. One of requirements for OPVs having high power conversion efficiency is the favorable energy level alignment between the electrode/organic and organic/organic interfaces to manage the exciton dissociation and improve the charge transport. In this review, strategies to enhance the OPV performance by controlling the energy level alignment are discussed. The insertion of an exciton blocking layer leads to the efficient dissociation of photogenerated excitons at the donor/acceptor interface enhancing the short-circuit current density. The choice of a donor having a high ionization energy and an acceptor having a low electron affinity increases the open-circuit voltage. The insertion of an appropriate work function modifier which reduces the charge injection barrier removes the S-kink in current density-voltage characteristics of OPVs and improves the fill factor. This review would give a valuable guide to design the efficient OPV structure.

STIMULATING NEURAL ELECTRODE-A STUDY ON CHARGE INJECTION PROPERTIES OF IRIDIUM OXIDE FILMS

  • Lee, In-Seop;Ray A. Buchanan;Jim M.Williams
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.156-162
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    • 1995
  • For a stimulating neural electrode, the charge density should be as large as possible to provide adequate stimulation of the nervous system while allowing for miniaturization of the electrode. Since iridium oxide is able to produce high charge densities while preventing undesirable reactions due to charge storage, it has become a promising material for neural prostheses. Successful production of stable Ir and Ir oxide films on various substrates now limits the use of this material. Ir was deposited on two differently prepared surface of (mirror finish, passivation) surgical Ti-6AI-4V with several methods. Ion beam mixing of sputter deposited Ir films on passivated Ti-6AI-4V produced stable and good adherent Ir films. It was found that the increase in charge density of pure Ir on continuous cyclingis due to the accumulation of the oxide phase ( associated with a large surface area) in which the valence state of iridium changes and the double-layer capacitance increases. This study also showed that the double layer capacitance is equally or even more responsible for the high charge density of anodically formed Ir oxide.

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Mechanism of workfunction modification on HAT-CN/Cu(111) interface: ab initio study

  • Kim, Ji-Hoon;Park, Yong-Sup;Kwon, Young-Kyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.357-357
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    • 2010
  • Using ab initio density functional theory, we study the structural and electronic properties of interface between Cu surface and highly electron withdrawing hexaazatriphenylene-hexanitrile (HAT-CN) known as an efficient hole injection layer for organic light emitting diodes (OLEDs). We calculate the equilibrium geometries of the interface with different HAT-CN coverages. Usually, some of C-N bonds located at the edge of the HAT-CN molecule are deformed toward Cu atoms resulting in the reconstruction of Cu surface. By analyzing the electron charge and the potential distributions over the interface, we observe the formation of surface dipoles, which modify the work function at the interface. Such dipole formation is attributed to two origins, one of which is a geometrical nature and the other is a bond dipole. The former is related to structural deformation mentioned above, whereas the latter is due to charge transfer between organic and metal surface.

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Early Stage of Pentacene Growth on the CYTOP Doped Graphene Surface

  • Yang, Mi-Hyun;Lee, Kyoung-Jae;Kumar, Yogesh;Ihm, Kyuwook;Kang, Tai-Hee;Ahn, Joung-Real
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.142.1-142.1
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    • 2013
  • The patterning and doping technique enables graphene to replace the metal electrode as a charge injection layer in the pentacene based thin film transistor. However, it is known that pentacene molecules form lying-down coordination on the graphene surface. Pentacene thin film showed that the highly occupied molecular orbital is 0.2~0.4 eV lower in the standing up coordination than in the lying down coordination. Here, we report the formation of standing-up coordination and lowered HOMO level of the pentacene layer grown on the graphene layer doped with CYTOP.

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Noble Metal Nanowire Based SERS Sensor

  • Gang, Tae-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.87-87
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    • 2013
  • The interface between nanomaterials and biosystems is emerging as one of the broadest and most dynamic areas of science and technology, bringing together biology, chemistry, physics and many areas of engineering, biomedicine. The combination of these diverse areas of research promised to yield revolutionary advances in healthcare, medicine, and life science. For example, the creation of new and powerful nanosensors that enable direct, sensitive, and rapid analysis of biological and chemical species can advance the diagnosis and treatment of disease, discovery and screening of new drug molecules. Nanowire based sensors are emerging as a powerful and general platform for ultrasensitive and multiplex detection of biological and chemical species. Here, we present the studies about noble metal nanowire sensors that can be used for sensitive detection of a wide-range of biological and chemical species including nucleic acids, proteins, and toxic metal ions. Moreover, the optical and electrochemical applications of noble metal nanowires are introduced. Noble metal nanowires are successfully used as plasmonic antennas and nanoelectrodes, thereby provide a pathway for a single molecule sensor, in vivo neural recording, and molecular injection and detection in a single living cell.

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Die Making and Product Prototype Fabrication in Investment Casting by SLA Rapid Prototyping Technique (급속조형기술을 이용한 쾌속정밀주조 금형 및 시제품 제작)

  • Park, Moon-Sun;Kim, Dae-Hwan;Kwak, Jeong-Gi;Hwang, Sang-Moon;Kang, Beom-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.11
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    • pp.74-80
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    • 1999
  • In this study, a stereolithography apparatus (SLA) prototype is used as a master model to be transformed into the silicone pattern by vacuum tool forming. The tool for the first prototype is fabricated by using this silicone pattern. Following this procedure, a temporary tool with metal powder and epoxy for wax injection is prepared for the die set of quick change type which consists of upper and lower base die나 and an insert die. The die set of quick change type appears to be very effective in casting operation by changing tools rapidly. The original wax pattern is formed through the die set, and is made of lost-was. Finally the lost-wax pattern is applied to investment casting. The final casting product is checked regarding its dimensional accuracy.

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Development of 1064 nm squeezer for quantum non-demolition measurement in gravitational wave detector

  • Park, June Gyu;Kim, Chang-Hee;Lee, Sungho;Kim, Yunjong;Seong, Hyeon Cheol;Jeong, Ueejeong;Je, Soonkyu
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.60.3-60.3
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    • 2021
  • Squeezed vacuum injection을 이용한 중력파 검출기의 관측감도 향상 기술은 중력파 검출기 광신호의 양자 잡음을 제어하여 관측감도를 높이는 기술로 이론적으로는 10dB에 가까운 신호 대 잡음비 향상을 달성할 수 있다. 실험실 환경에서는 이미 10dB 이상의 신호 대 잡음비 향상을 달성했으며 실제 중력파 검출기에서는 GEO600의 6dB의 신호 대 잡음비 향상이 현재까지 가장 높은 수준이다. 한국천문연구원에서는 2019년부터 차세대 중력파 검출기 기술개발로 1064 nm 파장의 squeezer 개발을 추진했으며 현재 parametric down conversion을 이용해 squeezed vacuum을 생성하는 공진기를 제작하여 시험하는 단계에 있다. 이 발표에서는 한국천문연구원의 1064 nm squeezer 개발 연구와 개발 현황에 대해 소개하고자 한다.

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Review on the Process Safety of $SiH_{4}$ Gas used in Semiconductor and FPD Field (반도체 및 FPD 분야에 사용되는 $SiH_{4}$ 가스의 공정 안전 고찰)

  • Kim, Joung-Cho;Kim, Hong
    • Journal of the Korean Society of Safety
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    • v.22 no.4
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    • pp.32-36
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    • 2007
  • When the vacuum system for the process of $SiH_{4}$ gas used in the semiconductor and FPD field is partially vented from vacuum to atmospheric state, a fire often occurs due to auto-ignition of $SiH_{4}$ gas. In order to prevent the fire, the concentration of $SiH_{4}$ should be kept under LFL. This means that the higher capacity pump is needed to meet the process conditions as well as the condition that the concentration of $SiH_{4}$ should be kept under LFL. In this article, we conducted the injection of the dilution gas at the manifold between booster pump and dry pump compared with the typical method that the dilution gas was injected into inlet port of booster pump using computer simulation. According to the result, we can flow further more purge gas for safety without any change of the condition in the process chamber, which means that the higher capacity pump is not required for safety in some cases.

Formability Evaluation of the Vacuum Resin Transfer Molding of a CFRP Composite Automobile Seat Cross Part (탄소섬유복합재료의 시트크로스 부품에서 진공수지주입성형에 의한 성형성 평가)

  • Kim, Kun-Young;Kwak, Sung-Hun;Han, Gyu-Dong;Park, Jin-Seok;Cho, Jun-Haeng;Lee, Chang-Hoon;Kang, Myung-Chang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.3
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    • pp.24-29
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    • 2017
  • In this study, a seat cross member was fabricated by optimizing the resin transfer molding processing of CFRP (Carbon Fiber Reinforced Plastics) materials. This seat cross member is used in automotive underbody parts and provides side impact support. The seat cross was manufactured via vacuum resin transfer molding. The process included 1min of resin injection, 8 mins of heating, and 1 min of cooling, for a total molding time of 10mins. Tensile test results showed an average breaking load of 21.50kN, a tensile strength of 404 MPa, and an elastic modulus of 46.2 GPa. As a result, the CFRP seat cross provides the same strength as a similar steel part, but weighs 42% less.

Study on the Silicon Pump and Control System for TFT-LCD Manufacturing Process (TFT-LCD 생산공정을 위한 실리콘 펌프 및 제어시스템에 관한 연구)

  • Park, Hyoung-Keun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.8
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    • pp.3618-3622
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    • 2012
  • In this study, the yield of the modules in LCD production lines, improving current TFT-LCD production process is essential for high-pressure silicone injection equipment, and precision control system was developed. This full-scale production of the future through the development of next-generation display production line is being prepared, being transferred to China in LCD production facilities can make the most of efficient equipment. Therefore, minimize the cost of new investment and help create the maximum effect to control the detailed behavior of the sequence H/W and S/W system was installed on the production line. In addition, Fast-evacuating the structure proposed for the Vacuum pump, Pump control circuit design and experimental results has been completed.