• Title/Summary/Keyword: VS Reduction

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Rectal Temperature of Lactating Sows in a Tropical Humid Climate according to Breed, Parity and Season

  • Gourdine, J.L.;Bidanel, J.P.;Noblet, J.;Renaudeau, D.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.6
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    • pp.832-841
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    • 2007
  • Rectal Temperature;Thermoregulation;Sows;Breed;The effects of season (hot vs. warm) in a tropical humid climate, parity (primiparous vs. multiparous) and breed (Creole: CR, Large White: LW) on rectal temperature (RT) were studied for a total of 222 lactations obtained in 85 sows (43 CR and 42 LW; 56 primiparous and 166 multiparous) over a 28-d lactation, between June 2002 and April 2005. Mean daily ambient temperature was higher during the hot season than during the warm season (26.0 vs. $24.1^{\circ}C$) and relative humidity was high and similar in both seasons (89% on average). At farrowing, BW was lower (172 vs. 233 kg) and backfat thickness was higher (37 vs. 21 mm) in CR than in LW sows (p<0.01). During the hot season, the reduction of average daily feed intake (ADFI) was more pronounced in LW than in CR sows (-920 vs. -480 g/d, p<0.05). Rectal temperature was higher at 1200 than at 0700hr, which coincides with the maximum and the minimum values of daily ambient temperature. The daily RT increased ($+0.9^{\circ}C$; p<0.01) between d -3 and d 7 (d 0: farrowing day), remained constant between d 7 and d 25 and decreased (p<0.01) thereafter (i.e. $-0.6^{\circ}C$ between d 25 and d 32). The average daily RT was significantly higher during the hot than during the warm season (38.9 vs. $38.6^{\circ}C$; p<0.01). It was not affected by breed, but the difference in RT between the hot and warm seasons was more pronounced in LW than in CR sows (+0.4 vs. $+0.2^{\circ}C$; p<0.05). Parity influenced the RT response; it was greater in primiparous than in multiparous sows (38.9 vs. $38.7^{\circ}C$; p<0.01). This study suggests that thermoregulatory responses to heat stress can differ between breeds and between parities.

Effects of Microwave Irradiation for Elutriated Acid Fermentation of Sewage Primary Sludge (하수 일차슬러지의 세정산발효 특성에 대한 Microwave 전처리의 영향)

  • Kwon, Koo-Ho;Lee, Won-Sic;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.23 no.4
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    • pp.498-503
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    • 2007
  • The performance of elutriated acid fermentation to evaluate the effects of microwave irradiation and pH control as pretreatment was investigated. The MW pH 7 reactor which was used the pretreated primary sludge as microwave irradiation was operated at pH 7 and $35^{\circ}C$. The EAF pH 9 reactor was operated at pH 9 and $35^{\circ}C$ without pretreatment. The SCOD and VFAs production rate were 0.17 gSeOD/gVSrem. and 0.27 gVFAs as COD/gVSrem. in MW pH 7 reactor, 0.16 gSCOD/gVSrem. and 0.24 gVFAs as COD/gVSrem. in EAF pH 9 reactor, respectively. VS and Volume reduction were 54% and 48% in MW pH 7 reactor, 54.6% and 36% in EAF pH 9 reactor, respectively. A comparison of the microwave irradiation and controlled pH in elutriated acid fermentation showed that the former is more efficient in SCOD and VFAs production and it rises to slightly higher reduction in the volume of the sludge. In addition, E. coli. was not detected in the wasting sludge of MW pH 7 reactor. Based on the results, microwave irradiation appeared to be one of the viable options for generating class A sludge. According to the batch tests, sequencing batch test which was used the pretreated primary sludge as microwave was performed at pH 7 and $35^{\circ}C$, SCOD production was 0.16 gSCOD/gVSrem., VS reduction and volume reduction were 64% and 63%, respectively.

Electrochemical Reduction of 0,0-Dimethyl-0-(3-Methyl-4-Nitrophenyl)-phosphorothioate(Sumithion®) in Acetonitrile Solution (Acetonitrile 용액중(溶液中)에서 0,0-Dimethyl-0-(3-Methyl-4-Nitrophenyl)-phosphorothioate(Sumithion®)의 전기화학적(電氣化學的) 환원반응(還元反應))

  • Park, Seung Heui;Sung, Nack Do
    • Korean Journal of Agricultural Science
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    • v.11 no.2
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    • pp.315-321
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    • 1984
  • The electrochemical reduction of 0,0-dimethyl-0-(3-methyl-4 -nitrophenyl)-phosphorothioate ($Sumithion^{(R)}$) in acetonitrile solution has been studied by direct current (DC), differential pulse (DP) polarography and cyclic voltammetry methods. The irreversible electron-transfer chemical reaction (EC) mechanism of Sumithion proceeds by six electron-transfer to form radical and reduction of three-step which undergoes single bond of the phosphorus atom & phenoxy group by electron-transfer and protonation cleaved to give p-hydroxyamino-m-cresol and dimethylthiophosphonate as major product.

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Substituent Effects and Correlations of Electrochemical Behaviors with Molecular Orbital Calculation of Thioxantone DerivativesⅠ

  • 곽경도;서무룡;하광수;백우현
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.527-530
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    • 1998
  • This paper presents the electrochemistry and molecular orbital (MO) picture of a series of conformationally-restricted thioxantone derivatives. A series of $C_2-substituted$ thioxanthones were examined to probe the electronic influence of the substituent on the electrooxidation and electroreduction sites (i.e., on the electron densities at the 10-and 9-positions), respectively. In the presence of "electrophoric" groups such as C=O and S, characteristic electrochemical reduction and oxidation responses are observed. The electrochemical reaction was diffusion-controlled, because the $I_p/{\upsilon}^{1/2}$ ratio was constant for the anodic and cathodic wave of thioxantone derivatives. These substituent effects are presented in terms of correlations of oxidation (or reduction) potentials with the highest occupied molecular orbital (HOMO), or lowest unoccupied molecular orbital (LUMO) energies, respectively. There is good correlation between energies of the HOMO vs. $E_{pa}^{(+)}$ and energies of the LUMO vs. $E_{pc}^{(-)}$. Frontier Molecular Orbital (FMO) is changed by the functional group of thioxanthones. FMO energy level was offered us the information about the electron transfer direction, and the coefficient of FMO was offered the information about the electron transfer position. Sulfur atom has an important effect on oxidation potential, $E_{pa}^{(+)}$ and the carbonyl carbon has an important effect on reduction potential, $E_{pc}^{(-)}$. Therefore we were appreciated that the contribution of sulfur atom for the $E_{pa}^{(+)}$ and HOMO energies is larger than the contribution of carbonyl group for the $E_{pc}^{(-)}$ and LUMO energies.

Impact of the COVID-19 Outbreak on Anesthesiologist Assistance for Endoscopic Procedures

  • Calcedonio Calcara;Camilla Ciscato;Arnaldo Amato;Emanuele Sinagra;Costanza Alvisi;Sandro Ardizzone;Andrea Anderloni;Pietro Gambitta
    • Clinical Endoscopy
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    • v.55 no.1
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    • pp.49-57
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    • 2022
  • Background/Aims: The coronavirus disease 2019 (COVID-19) outbreak has modified the activities of endoscopy units worldwide. Herein, we investigated the impact of the COVID-19 outbreak on anesthesiologist assistance for endoscopic procedures in Lombardy, Italy. Methods: A questionnaire concerning anesthesiologist assistance provided from October 26 to December 6, 2020, in comparison with the same period in 2019, was sent to endoscopic units in Lombardy. Results: Approximately 54% (34/63) of the units responded. A reduction in the number of all endoscopies (-33.5%; 18792 in 2020 vs. 28264 in 2019) and anesthesiologist-assisted endoscopies (-15.3%; 2652 in 2020 vs. 3132 in 2019) was reported. A greater reduction in anesthesiologist assistance was observed in government community units (-29.5%) than in academic (-14%) and private community units (-4.6%). Among all units, 85% reported a reduction in anesthesiologist assistance; 65% observed a delay/cancellation of procedures; 59%, a restricted patient selection; 17%, the need to transfer some patients to other hospitals; and 32%, a related worsening of procedure quality. Conclusion: The COVID-19 pandemic compromised the anesthesiologist assistance for endoscopic procedures in Lombardy, which worsened the procedure quality mainly in government community units. The COVID-19 "stress test" suggests a more balanced allocation of anesthesiologic resources in the future.

Field Validation of a Sampling and Analytical Method Developed for Preventing Airborne Hexavalent Chromium Collected on PVC Filter from Reduction (PVC 여과지에서의 환원 방지를 위해 개발된 공기중 6가 크롬 측정방법의 현장 평가)

  • 신용철;백남원
    • Journal of Environmental Health Sciences
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    • v.28 no.2
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    • pp.109-116
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    • 2002
  • The purpose of this study was to evaluate a new sampling and analytical method for the determination of airborne hexavalent chromium, Cr(Ⅵ), in a field plating operation. The procedures of this new method (Shin & Paik's Method) are as the following: Airborne hexavalent chromium is collected on polyvinyl chloride (PVC) filter according to the National Institute iota Occupational Safety and Health (NIOSH) Method 7600, and the filler sample is placed in a screw-capped vial and soaked with 2% NaOH/3% Na₂CO₃ solution immediately after sampling. The Cr(Ⅵ) sample is analyzed by ion chromatography/visible spectrophotometry (IC/VS) according to the U.S. Environmental Protection Agency (EPA) Method 218.6. The airborne Cr(Ⅵ) concentrations measured by this method were compared with those determined by three reference methods: One (NIOSH/EPA Method) consisted of sampling airborne Cr(Ⅵ) on PVC filters and storing the sample filters in strew-capped vials according to the NIOSH method, and analyzing Cr(Ⅵ) in samples using IC/VS according to the EPA method. The second method (Impinger Method/NaHCO₃) consisted of absorbing airborne Cr(Ⅵ) into 0.02 M NaHCO₃ solution in midget impinger, and analyzing the Cr(Ⅵ) in samples using IC/VS. The third method was the OSHA Method ID-215. Using these four different methods, lour replicates of air samples were collected at an electroplating process and analyzed simultaneously. Two-way ANOVA and paired t-test were used to test difference among values determined by the methods. There was no significant difference and a strong correlation (r²:0.99) between Cr(Ⅵ) concentrations measured by the Shin & Paik's Method and an impinger method (p>0.05). However, Cr(Ⅵ) concentrations determined by Shin & Paik's Method were significant1y different from those by the NIOSH/EPA Method (p<0.05) or the OSHA method (p<0.05). The Cr(Ⅵ) concentrations of Shin & Paik's Method were significantly higher than those of the NIOSH/EPA Method or the OSHA method. This result indicated that the Shin & Paik's Method may prevent Cr(Ⅵ) losses caused by reduction and give more reliable results of airborne Cr(Ⅵ) concentrations in work environments.

Fundamental Aspects of Energy Recovery Systems based on Municipal Solid Waste Characteristics and Its Biodegradability (도시폐기물의 성상과 생분해정도에 따른 에너지회수공정의 비교)

  • Choi, Eui So;Park, Hoo Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.11 no.2
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    • pp.99-105
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    • 1991
  • This study was carried out to provide basic data to be necessary for the selection of an energy recovery process based on the characteristics of municipal solid wastes(MSW). The samples were collected at Kangdong-Ku in Seoul and conducted ultimate and proximate analyses. Laboratory scale anaerobic digesters were operated to determine the non biodegradable fractions of the wastes. The results indicated that carbon and hydrogen contents, and lower heating values could be calculated from the volatile contents of MSW by the following equations : C = 0.57 VS, H =0.084 VS, and HL=49.5 VS-(6-0.045VS) W. Nonbiodegradable fractions were respectively 58.9% of volatile matters and 77.7% of MSW. Incineration and refuse derived fuel(RDF) processes appeared to be the most efficient processes in terms of weight reduction and energy recovery, But determining the energy recovery processes, the fluctuations of heating values of MSW throughout a year and available landfill site and secondary pollution should be considered.

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Synthesis of 1-Benzyl-4-Iodomethyl-2-Azetidinone and Electrochemical Reduction on the Iodo Group (1-Benzyl-4-Iodomethyl-2-Azetidinone의 합성과 Iodo기에 대한 전기화학적 환원반응)

  • Kim Il Kwang;Lee Young Haeng;Lee Chai Ho;Chai Kyu Yun;Kim Yoon Geun
    • Journal of the Korean Chemical Society
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    • v.35 no.1
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    • pp.70-77
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    • 1991
  • 1-Benzyl-4-iodomethyl-2-azetidinone(BIMA) was synthesized and its electrochemical reduction was investigated by direct current, differential pulse polarography, cyclic voltammetry and controlled potential coulometry. The irreversible two electron transfer on reductive dehalogenation of iodo group proceeded to form 1-benzyl-4-methyl-2-azetidinone by EEC electrode reaction mechanism at the first reduction step(-1.35 volts vs. Ag-AgCl). The polarographic reduction waves separated into two reduction steps due to anionic surfactant (sodium lauryl sulfate) effects, while the waves were shifted to the positive potential as the concentration of cationic surfactant (cetyltrimethylammonium bromide) increased. Upon the basis of results on the product analysis and interpretation of polarogram with pH variable, EEC electrochemical reaction mechanism was suggested.

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Comparison of the Therapeutic Efficacy and Technical Outcomes between Conventional Fixed Electrodes and Adjustable Electrodes in the Radiofrequency Ablation of Benign Thyroid Nodules

  • Jae Ho Shin;Minkook Seo;Min Kyoung Lee;So Lyung Jung
    • Korean Journal of Radiology
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    • v.25 no.2
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    • pp.199-209
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    • 2024
  • Objective: This study aimed to compare therapeutic efficacy and technical outcomes between adjustable electrode (AE) and conventional fixed electrode (FE) for radiofrequency ablation (RFA) of benign thyroid nodules. Materials and Methods: Between 2013 and 2021, RFA was performed on histologically proven benign thyroid nodules. For the AE method, AE length ≥ 1 cm with higher power and < 1 cm with lower power were utilized for ablating feeding vessels and nodules, especially those near anatomical structures, respectively. The therapeutic efficacy (volume reduction rate [VRR], complication rate, and regrowth rate) and technical outcomes (total energy delivery, ablated volume/energy, RFA time, and ablated volume/time) of FE and AE were compared. Continuous parameters were compared using a two-sample t-test or Mann-Whitney U test, and categorical parameters were compared using a chi-squared test or Fisher's exact test. Results: A total of 182 nodules (FE: 92 vs. AE: 90) in 173 patients (mean age ± standard deviation, 47.0 ± 14.7 years; female, 90.8% [157/173]; median follow-up, 726 days [interquartile range, 441-1075 days]) were analyzed. The therapeutic efficacy was comparable, whereas technical outcomes were more favorable for AE. Both electrodes demonstrated comparable overall median VRR (FE: 92.4% vs. AE: 84.9%, P = 0.240) without immediate major complications. Overall regrowth rates were comparable between the two groups (FE: 2.2% [2/90] vs. AE: 1.1% [1/90], P > 0.99). AE demonstrated a shorter median RFA time (FE: 811 vs. AE: 627 seconds, P = 0.009). Both delivered comparable median energy (FE: 42.8 vs. AE: 29.2 kJ, P = 0.069), but AE demonstrated higher median ablated volume/energy and median ablated volume/time (FE: 0.2 vs. AE: 0.3 cc/kJ, P < 0.001; and FE: 0.7 vs. AE: 1.0 cc/min, P < 0.001, respectively). Conclusion: Therapeutic efficacy between FE and AE was comparable. AE demonstrated better technical outcomes than FE in terms of RFA time, ablated volume/energy, and ablated volume/time.