• Title/Summary/Keyword: VOX

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Characteristics of Vanadium Oxide Grown by Atomic Layer Deposition for Hole Carrier Selective Contacts Si Solar Cells (실리콘 전하선택접합 태양전지 적용을 위한 원자층 증착법으로 증착된 VOx 박막의 특성)

  • Park, Jihye;Chang, Hyo Sik
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.660-665
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    • 2020
  • Silicon heterojunction solar cells can achieve high conversion efficiency with a simple structure. In this study, we investigate the passivation characteristics of VOx thin films as a hole-selective contact layer using ALD (atomic layer deposition). Passivation characteristics improve with iVoc (implied open-circuit voltage) of 662 mV and minority carrier lifetime of 73.9 µs after post-deposition annealing (PDA) at 100 ℃. The improved values are mainly attributed to a decrease in carbon during the VOx thin film process after PDA. However, once it is annealed at temperatures above 250 ℃ the properties are rapidly degraded. X-ray photoelectron spectroscopy is used to analyze the chemical states of the VOx thin film. As the annealing temperature increases, it shows more formation of SiOx at the interface increases. The ratio of V5+ to V4+, which is the oxidation states of vanadium oxide thin films, are 6:4 for both as-deposition and annealing at 100 ℃, and 5:5 for annealing at 300 ℃. The lower the carbon content of the ALD VOx film and the higher the V5+ ratio, the better the passivation characteristics.

Effect of Vanadium Surface Density of SCR Catalyst on Reaction Activity and SO2 Durability (상용 SCR 촉매의 바나듐 표면밀도가 반응활성 및 SO2 내구성에 미치는 영향연구)

  • Won, Jong Min;Park, Kwang Hee;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.158-164
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    • 2017
  • In this study, the reaction activity and XRD, BET, and Raman analysis were performed to verify $NH_3$-SCR reaction characteristics of various commercial SCR catalysts. It can be seen that the reaction rate of each commercial SCR catalyst increased linearly with increasing the vanadium content (1.3-5.4 wt%). In addition, through the above analysis, it was possible to confirm that the addition of WOx in the catalyst increased the Turn over frequency (TOF) within the range where the VOx surface density was more than 8.1 and the crystalloid VOx was not formed through the surface structure analysis. $SO_2$ durability tended to decrease with increasing the vanadium content, and the durability increased the most when W and Si were added.

V-Zn계 산화물을 이용한 마이크로볼로미터적외선 센서의 구현

  • Han, Myeong-Su;Kim, Dae-Hyeon;Choe, In-Gyu;Go, Hang-Ju;Eom, Ju-Beom;Park, Jae-Seok;Sin, In-Hui;Lee, Byeong-Il;Kim, Du-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.376.2-376.2
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    • 2014
  • 마이크로볼로미터 적외선 센서는 인체감지, 전자부품의 품질검사, 에너지 절감, 산업시설감시 및 군사용으로 다양하게 적용되고 있다. 기존에 이러한 적외선 센서의 감지재료로 VOx 또는 비정질 Si이 가장 많이 사용되고 있으며, VOx는 감도가 높고, 세계적으로 가장 많이 사용되고 있는 물질이다. 본 연구에서는 기존의 VOx 박막 증착법을 개선하여 Zn 산화물 박막을 혼용한 적외선 감지재료를 이용한 마이크로볼로미터 제작 및 특성에 대해 보고한다. RF sputtering 방법으로 약 140 nm의 VOx/ZnO/VOx 샌드위치 박막을 증착하고, 산소분위기에서 열처리함으로써 온도저항계수(TCR)가 약 -3.0 %/K의 값을 갖는 특성을 구현하였다. 갓 증착된 V-Zn 박막에서는 XRD 스펙트럼에서는 V2O5 관련 피크가 주로 관측되었으며, 산소열처리에 의해 VO2 피크가 새롭게 관측되었다. 볼로미터 감지소자는 유효면적 $50{\times}50{\mu}m^2$ 으로 bulk micromaching 공정을 통해 제작하였다. Si 기판위에 SiNx 박막을 PECVD 장치를 이용하여 증착하였으며, 적외선 감지층으로 V-Zn 산화물을 RF sputtering 방법으로 증착하여 열처리 후 SiNx passivation 박막으로 보호하였다. 열적고립을 위해 패터닝 후 Si 기판을 KOH 용액을 이용하여 약 $20{\mu}m$ 식각하여 소자를 구현하였다. 제작된 소자의 특성을 평가한 결과 반응도는 1.57e+4 V/W, 탐지도는 $8.79e+7cmHz^{1/2}/W$를 얻을 수 있었다. 소자의 동작 특성을 평가하기 위해 진공 압력을 1e-3 torr 이하에서 thermoelectric cooler를 장착한 metal package를 제작하여 동작온도에 따른 특성을 평가하였다. 동작온도를 $10^{\circ}C{\sim}40^{\circ}C$로 하여 측정한 결과 동작온도가 증가할수록 신호전압은 감소함을 알 수 있었다.

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The Activity of Standard and Fast SCR over V-based Catalysts Supported on Various TiO2 (다양한 TiO2에 담지된 바나디아 촉매의 표준 및 빠른 SCR 활성)

  • Ji Eun Jeong;Yeon Jeong Jo;Inyoung Lee;Jeongkeun Lee;Chang-Yong Lee
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.584-589
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    • 2023
  • The physicochemical properties of VOx/TiO2 catalysts with different TiO2 supports were analyzed, and SCR reactions were performed. VOx/TiO2 catalysts were prepared by impregnation using anatase TiO2, which was manufactured by Sigma Aldrich and prepared from TiOCl2 and titanium isopropoxide (TTIP) as a precursor. They are denoted as VS, VC, and VP. The specific surface area of the VS was 1/10 or less of that of the VC and VP, and the dispersibility of vanadium oxide was relatively low. As a result of XPS analysis, the ratio of adsorbed oxygen was higher in VS and VP with Ti3+ than in VC. In VC and VP, vanadium mainly existed in V4+ and V3+ states in relation to the dispersibility of vanadium oxide. The amount of adsorbed oxygen contributed more to NH3-SCR activity than vanadium oxide dispersibility below 250 ℃, while vanadium oxide dispersibility contributed more to activity beyond 300 ℃. The fast SCR activity in all three samples was the highest at NO2/NOx = 0.5, followed by VS < VC < VP samples. It was determined that the dispersibility of vanadium oxide had a significant effect on fast NH3-SCR activity.

Development of Denture Type Electrolarynx (I) (의치형 인공 후두의 개발 (I))

  • 최홍식;박용재;정문규;김한수;신승호;박인환;박노철;이희경;손창기
    • Journal of the Korean Society of Laryngology, Phoniatrics and Logopedics
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    • v.12 no.1
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    • pp.28-33
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    • 2001
  • Denture-type Electrolarynx is being watched recently because it is easy to control the pitch and volume and it is not exposed on the outside. This system consists of three pars. The first is the Oral-Unit part, which contains a receiver, a loud speaker, and a rechargeable battery. The others are the Transmitter St Control-Unit Part, and the Charging-Unit part. We have newly developed the Korean Denture-type Electrolarynx : NeoVox. That system is designed considering low-power consumption, wireless charging system, small size and the speaker emphasizing low-frequency. So that the laryngectomees feel comfortable to use it and speak naturally.

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THE USE OF THE TECHNIQUE IN BOTH CLASSICAL AND FOLK SONG IN OCCIDENTAL SINGING

  • Naidich, Susana
    • Journal of the Korean Society of Laryngology, Phoniatrics and Logopedics
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    • v.2 no.1
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    • pp.15-19
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    • 1986
  • Our report refers to occidental vocal techniques from Greece until today. It is remarkable that even with poor anatomy knowledge, there were advices on styles given from very early periods, for both church and secular singing. During the 18th century, the names of "vox pectoris", "vox guturris" and "vox capitis" appear, nominations that somehow remain nowadays with great confusion about source of sound production and results of resonance. Vocal occidental styles developed different kinds of requirements from the singers, that had to adapt their vocal Possibilities to them. The same happened with "pop" song. Nowadays, all kinds of singers must have a conscious knowledge of its voice management to prevent vocal disturbances. We consider that the technique is the same, even when the singer has to sing Wagner, Debussy, Sconberg, Piazzola or Gershwin. The big changes occured at resonance levels, and because these different use of the vocal resonators the effects are quite different. In summary, the big differences on classical the effects are quite different. In summary, the big differences on classical and pop song are done on the different use of the resonators and its effects on the vocal tract. "Pop" singers, men and women, should be taught to use both registers, "modal" and "falsetto" to be able to reach the complete range of their songs without any harm to their larynxes. In our opinion, a good singing technique means that it could be adapted to every stylistic need. The same technique is adapted to the popular singer as well. The main difference lays on the use of resonators, pretty strong in the classic singer, weaken in the popular singer, on the volume and on the total extension of the voice. Breathing control, effortless emission and the use of "passage" at the right point should be taught to all singers, regardless of their style. (omitted)

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Integrated receptive field diversification method for improving speaker verification performance for variable-length utterances (가변 길이 입력 발성에서의 화자 인증 성능 향상을 위한 통합된 수용 영역 다양화 기법)

  • Shin, Hyun-seo;Kim, Ju-ho;Heo, Jungwoo;Shim, Hye-jin;Yu, Ha-Jin
    • The Journal of the Acoustical Society of Korea
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    • v.41 no.3
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    • pp.319-325
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    • 2022
  • The variation of utterance lengths is a representative factor that can degrade the performance of speaker verification systems. To handle this issue, previous studies had attempted to extract speaker features from various branches or to use convolution layers with different receptive fields. Combining the advantages of the previous two approaches for variable-length input, this paper proposes integrated receptive field diversification that extracts speaker features through more diverse receptive field. The proposed method processes the input features by convolutional layers with different receptive fields at multiple time-axis branches, and extracts speaker embedding by dynamically aggregating the processed features according to the lengths of input utterances. The deep neural networks in this study were trained on the VoxCeleb2 dataset and tested on the VoxCeleb1 evaluation dataset that divided into 1 s, 2 s, 5 s, and full-length. Experimental results demonstrated that the proposed method reduces the equal error rate by 19.7 % compared to the baseline.