• Title/Summary/Keyword: VOSc

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Measurement of Volatile Organic Sulfur Compounds in Ambient Air by Canister and Tedlar-bag Sampling Method (캐니스터와 Tedlar-bag 시료채집법을 이용한 대기 중의 휘발성유기황화합물의 측정)

  • 전선주;허귀석
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.4
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    • pp.417-428
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    • 1999
  • The measurement of VOSCs(volatile organic sulfur compounds) in the air is nowadays a very important environmental research field. It is, however, very difficult because the concentration of the VOSC in ambient air is usually very low and the high reactivity makes it difficult to keep in container without loss of recovery. In this study, sampling method with cryogenic preconcentration is evaluated for analysis of atmospheric VOSC such as $CH_3SH,\;CH_3CH_2SH,\;CH_3SCH_3,\;CS_2,\;CH_3SSCH_3,\;CH_3SCH_2SCHA_3,\;and\;C_2H_5SSC_2H_5$ analyzed by GC-MS or GC-FID. Repeatabilities of measurement accompanied with preconcentration for 3-successive runs were in the range of 0.2~1.0% as a relative standard deviation. Stabilities up to 13 days were measured in 6 L canister and 10 L tedlar bag filled with VOSCs in ppb level. Higher stability was observed in tedlar bag as compared to canister with glass coated inner walls, and thiol compounds show dramatic losses in canister within 2~3 days. It is found that recovery over 70% was obtained in a week for all tested VOSCs when the compounds from ambient air matrix were stored in tedlar bag. It is also found that the stabilities of VOSCs are depending on humidity and coexisting compounds in matrix gas due to sample adsorption onto inner surface and reactivity. The results indicate the possibility and limitations of VOSC analysis in ambient air using container sampling method with cryogenic preconcentration.

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Implementation of Simplified Electronic Measuring Devices Using Java Applets (자바 애플릿을 이용한 단순화된 전자계측장비의 구현)

  • Kim, Dongsik;Moon, Ilhyun;Woo, Sangyeon
    • The Journal of Korean Association of Computer Education
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    • v.10 no.6
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    • pp.69-77
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    • 2007
  • In this paper we implement main functions of electronic measuring devices, which are essential to design electric/electronic virtual laboratories on the Web. The implemented virtual electronic measuring devices such as virtual analog multimeter(VAM), virtual function generator(VFG), virtual oscilloscope(VOSC) enable the learners to perform the virtual experiments on the Web by simple mouse clicks. In order to show their validity virtual experiments for understanding how to use them are designed. The virtual experiments for measuring resistance(OHM), AC/DC Voltage(ACV/DCV) and DC Current(DCA) by the VAM are illustrated. In addition, the learners can change the frequency of the signal generated from the VFG and measure by the VOSC several types of the signals generated from the VFG such as triangular, pulse, sinusoidal waveforms. The VOSC can measure voltage and current through two channels of it and provide the learners with additional functions such as zooming, trigger, cursor, summing of waveforms. Since the virtual electronic measuring devices have been implemented as forms of Java classes, various types of applications are available according to the structures of virtual laboratories.

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Effect of Sunlight Polarization on the Absorption Efficiency of V-shaped Organic Solar Cells

  • Kang, Kyungnam;Kim, Jungho
    • Journal of the Optical Society of Korea
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    • v.18 no.1
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    • pp.9-14
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    • 2014
  • We numerically investigate the effect of sunlight polarization on the absorption efficiency of V-shaped organic solar cells (VOSCs) using the finite element method (FEM). The spectral distribution of absorbance and the spatial distribution of power dissipation are calculated as a function of the folding angle for s-and p-polarized light. The absorption enhancement caused by the light-trapping effect was more pronounced for s-polarized light at folding angles smaller than $20^{\circ}$, where s-polarized light has a relatively larger reflectance than p-polarized light. On the other hand, the absorption efficiency for p-polarized light is relatively larger for folding angles larger than $20^{\circ}$, where the smaller reflectance at the interface of the VOSC is more important in obtaining high absorption efficiency.

Power Enhance Effect on the Hybrid Cell Based on Direct Current Nanogenerator and an Organic Photovoltaic Device

  • Yun, Gyu-Cheol;Sin, Gyeong-Sik;Lee, Geun-Yeong;Lee, Ju-Hyeok;Kim, Sang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.298-298
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    • 2013
  • Finding renewable and clean energy resources is essential research to solve global warming and depletion of fossil fuels in modern society. Recently, complex harvesting of energy from multiple sources is available in our living environments using a single device has become highly desirable, representing a new trend in energy technologies. We report that when simultaneously driving the fusion and composite cells of two or more types, it is possible to make an affect the other cells to obtain a greater synergistic effect. To understand the coupling effect of photovoltaic and piezoelectric device, we fabricate the serially integrated hybrid cell (s-HC) based on organic solar cell (OSC) and piezoelectric nanogenerator (PNG). The size of increased voltage peaks when OSC and PNG are working on is larger than the case when only PNG is working. This voltage difference is the Voc change of OSC, not the voltage change of PNG and current density difference between these two cases is manifested more clearly. When the OSC and PNG are working in s-HC at the same time, piezoelectric potential (VPNG) is generated in ZnO and theoretical total voltage is sum of voltage of an OSC (VOSC) and VPNG. However, electrons from OSC are influenced by piezoelectric potential in ZnO and current loss of OSC in whole circuit decreases. As a result, VOSC increases temporarily. Current shows the similar behavior. PNG acts a resistance in the whole circuit and current loss occurs when the electrons from OSC pass through the PNG. But piezoelectric potential recover current loss and decrease the resistance of PNG. Our PNG can maintain piezoelectric potential when the strain is held owing to the LDH layer while general PNG cannot maintain piezoelectric potential. During the section that strain is held, voltage enhancement effect is maintained and same effect appeared even turn off the light. Actually at this time, electrons in ZnO nanosheets move to LDH and trapped by the positive charges in this layer. After this strain is held, piezoelectric potential of ZnO nanosheets is disappeared but potential difference which is developed by negative charge dominant LDH layer is remained. This potential acts similar role like piezoelectric potential in ZnO. Electrons from the OSC also are influenced by this potential and the more current flows.

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The adsorption efficiency of ceramic filter media prepared with the steel-making slag for the removal of VOCs (휘발성 유기화합물 제거를 위한 제강슬래그로 제조된 세라믹 여재의 흡착효율)

  • Sin, Jun-Ho;Kim, Tae-Heui;Park, Kyung-Bong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.3
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    • pp.153-157
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    • 2010
  • We studied the adsorption efficiency of steelmaking slag in removing volatile organic compounds (VOCs) for increasing the recycling rate of steel-making slag. Ceramic filter was prepared by mixing the steel-making slag and the diatomite which is used as adsorbents due to the advantage of the high specific surface area and regular mesopores. The adsorption efficiency for VOCs removal was about 80%, 96% and 85% in acetaldehyde, formaldehyde and ammonia, respectively. The adsorption efficiency over 80% for all The gases showed the practical possibility as the adsorption filter.