• Title/Summary/Keyword: VOC reduction

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A Study on Reduction Effects of Air Pollutant Emissions by Automotive Fuel Standard Reinforcement (자동차연료 기준강화에 따른 대기오염물질 배출량 저감효과)

  • Lim, Cheol-Soo;Hong, Ji-Hyung;Kim, Jeong-Soo;Lee, Jong-Tae;Lim, Yun-Sung;Kim, Sang-Kyu;Jeon, Sang-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.2
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    • pp.181-190
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    • 2011
  • The air pollutants from vehicle exhaust gas are affected by many factors including fuel qualities, engine and vehicle technologies, driving patterns. In particular, fuel qualities and after-treatment devices could directly affect the emission level of pollutants. The pollutant reduction characteristics that caused by enforced fuel quality standard were analyzed. Three types of test fuel were selected in accordance with Korean automotive fuel standard in 2006, 2009, 2012 and used for vehicle emission test in chassis dynamometer. European COPERT correction equation of fuel impact was considered as reference information to quantify the vehicle emission test results. The contribution rates of exhaust emission by COPERT correction equation showed that aromatic compounds and oxygen contents in gasoline fuel was most important. In case of diesel fuel, cetane index and polycyclic aromatic compounds accounted for the greater part. The exhaust emission effects by COPERT correction equation revealed that CO and VOC was increased 0.86%, 1.57% respectively in after 2009 gasoline when compared to before 2009 gasoline fuel. In case of light-duty diesel vehicle CO, VOC and PM were decreased in range of 3~7%. The result from this study could be provided for developing future fuel standards and be used to fundamental information for Korean clean air act.

A Study on Catalysts for Simultaneous Removal of 1,2-Dichlorobenzene and NOx (1,2-Dichlorobenzene 및 질소산화물 동시제거를 위한 촉매연구)

  • Park, Kwang Hee;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.522-526
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    • 2009
  • The catalytic oxidation of 1,2-dichloribenzene (1,2-DCB) and simultaneous catalytic reduction of nitrogen oxides over the single catalyst has been investigated over various metals (Ru, Mn, Co and Fe) supported on $Al_2O_3$ and $CeO_{2}$. The activity of the different catalysts for catalytic oxidation of 1,2-dichloribenzene depended on the used metal, Ru/Co/$Al_2O_3$, Mn-Fe/CeO2 and Cr/$Al_2O_3$ (commercial catalysts) being the most actives ones. In the catalytic oxidation of chlorobenzene (CB), Ru/Co/$Al_2O_3$ is better than Pt-Pd/$Al_2O_3$, which is the well-known catalyst good for VOC oxidation. Furthermore, it has a good durability on the deactivation by $Cl_2$ and sulfur. For nitrogen oxides (NOx) removal, NOx conversion was 70% at $260^{\circ}C$.

Current Status of Ship Emissions and Reduction of Emissions According to RSZ in the Busan North Port (부산 북항에서의 선박 배출물질 현황과 선속제한에 의한 배출량 감소 연구)

  • Lee, Bo-Kyeong;Lee, Sang-Min
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.5
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    • pp.572-580
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    • 2019
  • In view of the numerous discussions on global environmental issues, policies have been implemented to limit emissions in the field of marine transport, which accounts for a major part of international trade. In this study, a ship's emissions were calculated by applying the engine load factor to determine the total quantity of emissions based on the ship's speed reduction. For ships entering and leaving the Busan North Port from 1 January to 31 December 2017, emissions were calculated and analyzed based on the ship's type and its speed in the reduced speed zone (RSZ), which was set to 20 nautical miles. The comparison of the total amount of emissions under all situations, such as cruising, maneuvering, and hotelling modes revealed that the vessels that generated the most emissions were container ships at 76.1 %, general cargo ships at 7.2 %, and passenger ships at 6.8 %. In the cruising and maneuvering modes, general cargo ships discharged a lesser amount of emission in comparison with passenger ships; however, in the hotelling mode, the general cargo ships discharged a larger amount of emission than passenger ships. The total emissions of nitrogen oxides (NOx), sulphur oxides (SOx), particulate matter (PM), and volatile organic compounds (VOC), were 49.4 %, 45 %, 4 %, and 1.6 %, respectively. Furthermore, the amounts of emission were compared when ships navigated at their average service speed, 12, 10, and 8 knots in the RSZ, respectively. At 12 knots, the reduction in emissions was more than that of the ships navigating at their average service speed by 39 % in NOx, 40 % in VOC, 42 % in PM, and 38 % in Sox. At 10 knots, the emission reductions were 52 %, 54 %, 56 %, and 50 % in NOx, VOC, PM, and Sox, respectively. At 8 knots, the emission reductions were 62 %, 64 %, 67 %, and 59 % in NOx, VOC, PM, and Sox, respectively. As a result, the emissions were ef ectively reduced when there was a reduction in the ship's speed. Therefore, it is necessary to consider limiting the speed of ships entering and leaving the port to decrease the total quantity of emissions.

Evaluation and Improvement of Diesel Retrofit Program in Gyeonggi-do (경기도 운행차 저공해화 사업의 성과분석 및 발전방안)

  • Kim, Dong-Young;Choi, Min-Ae
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.2
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    • pp.203-210
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    • 2012
  • The purpose of this study is to evaluate the diesel retrofit program which have been proceeded for the last 7 years in Gyeonggi-do. Diesel retrofit programs in Gyeonggi-do consist of the attachment of DPF (Diesel Particulate Filter), p-DPF (partial-DPF) and DOC (Diesel Oxidation Catalyst), switching to LPG engine, scraping an old cars. Emission reduction by diesel retrofit program was estimated $N_2O$ 8,313.4 ton/year, PM10 3,626.4 ton/year, VOC 8,078.5 ton/year in 2010. The benefit-cost analysis shows that the 964 billion wons of benefits are greater than the 853 billion wons of total costs. Diesel retrofit programs could be one of the most effective measures to improve PM10 concentration in metropolitan area. But retrofit programs also need to be properly maintained by each vehicle.

Health Risk Assessment with Source Apportionment of Ambient Volatile Organic Compounds in Seoul by Positive Matrix Factorization (수용체 모델(PMF)를 이용한 서울시 대기 중 VOCs의 배출원에 따른 위해성평가)

  • Kwon, Seung-Mi;Choi, Yu-Ri;Park, Myoung-Kyu;Lee, Ho-Joon;Kim, Gwang-Rae;Yoo, Seung-Sung;Cho, Seog-Ju;Shin, Jin-Ho;Shin, Yong-Seung;Lee, Cheolmin
    • Journal of Environmental Health Sciences
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    • v.47 no.5
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    • pp.384-397
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    • 2021
  • Background: With volatile organic compounds (VOCs) containing aromatic and halogenated hydrocarbons such as benzene, toluene, and xylene that can adversely affect the respiratory and cardiovascular systems when a certain concentration is reached, it is important to accurately evaluate the source and the corresponding health risk effects. Objectives: The purpose of this study is to provide scientific evidence for the city of Seoul's VOC reduction measures by confirming the risk of each VOC emission source. Methods: In 2020, 56 VOCs were measured and analyzed at one-hour intervals using an online flame ionization detector system (GC-FID) at two measuring stations in Seoul (Gangseo: GS, Bukhansan: BHS). The dominant emission source was identified using the Positive Matrix Factorization (PMF) model, and health risk assessment was performed on the main components of VOCs related to the emission source. Results: Gasoline vapor and vehicle combustion gas are the main sources of emissions in GS, a residential area in the city center, and the main sources are solvent usage and aged VOCs in BHS, a greenbelt area. The risk index ranged from 0.01 to 0.02, which is lower than the standard of 1 for both GS and BHS, and was an acceptable level of 5.71×10-7 to 2.58×10-6 for carcinogenic risk. Conclusions: In order to reduce the level of carcinogenic risk to an acceptable safe level, it is necessary to improve and reduce the emission sources of vehicle combustion and solvent usage, and eco-car policies are judged to contribute to the reduction of combustion gas as well as providing a response to climate change.

VOCs Reduction of Visible-light Responsive Photocatalyst coated nylon/polyester composite fiber for Vehicle Interior Parts and Materials (가시광 감응형 광촉매가 코팅처리된 자동차내장재용 Nylon/Polyester 복합섬유의 VOCs 저감)

  • Choi, Sei-Young
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.53-58
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    • 2014
  • In this study, characteristics of visible-light responsive photocatalyst Weltouch, especially VOCs reduction of visible-light responsive photocatalyst coated nylon/polyester composite fiber for vehicle interior parts and materials were evaluated. Visible-light responsive photocatalyst Weltouch was observed for both anatase phase and rutile phase. It is activated by light longer than 420nm. VOCs and formaldehyde generated from visible-light responsive photocatalyst treated nylon/polyester composite fiber were reduced confirmly. Visible-light responsive photocatalyst was firmly attached to the surface of nylon/polyester composite fiber without elimination even after 25 times repeated washing. And washing durability of nylon/polyester composite fiber confirmed the excellence that reduction effects of VOCs after repeated washing has appeared as much as before washing.

Analysis of Output Characteristics of High-Power Shingled Photovoltaic Module due to Temperature Reduction (고출력 슁글드 태양광 모듈의 온도 저감에 따른 출력 특성 분석)

  • Bae, Jae Sung;Yoo, Jang Won;Jee, Hong Sub;Lee, Jae Hyeong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.6
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    • pp.439-444
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    • 2020
  • An increase in the temperature of photovoltaic (PV) modules causes reduced power output and shorter lifetime. Because of these characteristics, demands for the heat dissipation of PV modules are increasing. In this study, we attached a heat dissipation sheet to the back sheet of a shingled PV module and observed the temperature changes. The PV shingled module was tested under Standard Test Conditions (STCs; irradiance: 1,000 W/㎡, temperature: 25℃, air mass: 1.5) using a solar radiation tester, wherein the temperature of the PV module was measured by irradiating light for a certain duration. As a result, the temperature of the PV module with the heat dissipation sheet decreased by 3℃ compared to that without a heat dissipation sheet. This indicated that the power loss was caused by a temperature increase of the PV module. In addition, it was confirmed that the primary parameter contributing to the reduced PV module output power was the open circuit voltage (Voc).

Study on the Characteristics of Formaldehyde Emission from Wood-Based Panels Treated with Several Surface Finishing Materials (표면마감처리에 따른 목질보드의 포름알데히드 방산특성에 관한 연구)

  • So, Won-Tek;Lim, Jin-Ah
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.3
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    • pp.30-37
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    • 2006
  • The present study examined the formaldehyde (HCOH) emission characteristic of various wood-based panel used in interior design, and measured changes in formaldehyde emission when a number of VOC reduction methods were applied. Formaldehyde emission showed a clear tendency of increase with the rise of temperature, and the concentration of formaldehyde emitted changed according to the preprocessing condition before measuring. Formaldehyde emission from wood board after bake out treatment was lower than that of the control group. When specimens were coated with urethane, cashew, water, oil stain, they generally showed the decrease of formaldehyde emission, although varying according to finishing material, and when edge sealing was applied the decrease became significant. $TiO_2$ coating was more effective in decreasing formaldehyde under ultraviolet lamps than under ordinary lamps. When the irradiation of ultraviolet lamps gets longer, formaldehyde emission decreased.

Quantitative Assessment on Contributions of Foreign NOx and VOC Emission to Ozone Concentrations over Gwangyang Bay with CMAQ-HDDM Simulations (CMAQ-HDDM을 이용한 광양만 오존 농도의 국외 기여도 분석)

  • Bae, Changhan;Kim, Byeong-Uk;Kim, Hyun Cheol;Kim, Soontae
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.5
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    • pp.708-726
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    • 2018
  • In this study, we examined the contribution of nitrogen oxides and volatile organic compounds emitted from China and Japan to ozone concentrations over Gwangyang-bay, South Korea. We used a chemical transport model, Community Multi-scale Air Quality model, and its instrumented sensitivity tool, High-order Decoupled Direct Method. Intercontinental Chemical Transport Experiment-Phase B 2006 for East Asia and Clean Air Policy Support System 2007 emissions inventories for South Korea were used for the ozone simulation. During the study period, May 2007, the modeled maximum daily 8-hr average ozone concentration among seven air quality monitors in Gwangyang-bay was 68.8 ppb. The contribution of $NO_x$ emissions from China was 19.5 ppb (28%). The highest modeled ozone concentrations and Chinese contributions appeared when air parcels were originated from Shanghai area. The observed 8-hr average ozone concentrations in Gwangyang Bay exceeded the national ambient air quality standard (60 ppb) 203 times by daytime and 56 times by nighttime during the period. It was noticed that many exeedances happened when contribution of Chinese emissions to ozone concentrations over the area increased. Sensitivity analysis shows that a reduction in Chinese $NO_x$ and VOC emissions by 15% could lessen the total exceedance hours by 24%. This result indicates that high ozone concentrations over Gwangyang-bay are strongly enhanced by Chinese emissions.

Causes of Air pollution and Effects of Mitigation Policy in Korea (우리나라 대기오염배출 원인과 저감 정책 효과 분석)

  • Bae, Jeonghwan;Kim, Yusun
    • Environmental and Resource Economics Review
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    • v.25 no.4
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    • pp.545-564
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    • 2016
  • Recently as fine and ultra fine particles become major environmental issues in Korea, it is very important to develop effective solutions to air pollution. Accordingly this study aims at detecting causes of air pollution by using models and examining if diesel price increases contribute to reduction of diesel consumption and air pollution. TSP, PM10, $NO_X$, $SO_X$, CO, and VOC are included as major air pollutants. As a result, we found invert U shape curve between pollution and income for all air pollutants except CO. Consumer price index, coal power capacity, diesel consumption, frequency of yellow dust, number of natural gas buses, number of transport business, annual average temperature, number of manufacturing businesses are also influential in explaining causes of air pollution. As diesel price increases by 1%, air pollutants decline between 0.07~0.12% in the short run. Simultaneously, the additional revenue from increases in diesel prices might be transferred to support expansion of biofuel market. Also, stronger policy should be developed to mitigate the current air pollution problem.