• Title/Summary/Keyword: VOC emissions

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Characterization of Atmospheric Concentrations of Volatile Organic Compounds in Industrial Areas of Pohang and Gumi Cities (포항과 구미의 대규모 산단지역 대기 중 휘발성 유기화합물 농도 분포 특성에 관한 연구)

  • Baek Sung-Ok;Kim Soo-Hyun;Kim Mi-Hyun
    • Environmental Analysis Health and Toxicology
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    • v.20 no.2 s.49
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    • pp.167-178
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    • 2005
  • This study was carried out to evaluate the temporal, spatial, and seasonal variations of VOC, and to characterize the VOC concentrations in two large industrial complexes located in Pohang and Gumi cities. Twenty -four hours continuous sampling of selected VOC was made with STS 25 sequential tube samplers and double-bed adsorbent tubes. Air samples were collected every three hour interval for 7 consecutive days in each site during summer and winter. VOC were determined by thermal desorption coupled with GC/MS. A total of 27 VOCs of environmental concern were determined, including aliphatic, aromatic and halides. Generally. concentrations of toxic VOC were higher in Gumi than Pohang, and VOC levels in industrial areas were typically several-fold higher than those in residential areas. The most abundant VOC appeared to be toluene for both cities. However, chlorinated VOC were higher in Gumi than Pohang, while aromatic VOC were more abundant in Pohang than in Gumi. Two cities showed relatively different variations of VOC concentrations within a day. It is likely that traffic related sources are major factors affecting the VOC in Pohang, and industrial solvents usages are important sources in Gumi. These results imply that the occurrence and levels of atmospheric VOC are strongly dependent on the type of industries in each city. Therefore, in order to develop any control strategies or to establish the priority rankings for VOC in large industrial complexes, the type of industries and the occurrence of VOC in the atmosphere should be taken into consideration.

A Study on the Estimation of Landfill Gas Emission by LAEEM in KOREA (LAEEM에 의한 전국 매립가스 발생량 추정에 대한 연구)

  • 장영기;서정배
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.5
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    • pp.499-506
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    • 1998
  • Recently almost wastes except recycled garbage are dumped into landfill site in Korea. Landfills are significant compounds (NMOCS) are produced. NMOCS include reactive volative organic compound (VOC) and hazardous air pollutants. LAEEM (Landfill Air Emissions Estimation Model) developed by Control Technology Center, V.S. EPA is used to estimate a mount of landfill gas from all landfills. As the result, landfill gas 4,121,000 ton, carbon dioxide 2,951,000 ton, methane 1,1120,000 ton are estimated as emissions from all landfills in Korea.

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Effect of Removal of Power Plant Emissions on the characteristics of Ozone Concentration Changes in Summer (화력발전소 배출량 제거에 따른 여름철 O3 농도의 변화 특성)

  • Kim, Dongjin;Jeon, Wonbae;Park, Jaehyeong;Mun, Jeonghyeok
    • Journal of the Korean earth science society
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    • v.42 no.2
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    • pp.149-163
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    • 2021
  • In this study, the changes in ozone (O3) concentrations due to the removal of power plant emissions were analyzed using a community multi-scale air quality (CMAQ) model. Two different CMAQ model simulations, one considering the emissions from the Hadong power plant and one without considering the emissions, were conducted to investigate the effect of the emissions on the changes in the O3 concentrations in the surrounding areas. Subsequently, the CMAQ simulations exhibited an increase in the O3 concentration (25.24%) despite a decrease in the NOx (-18.87%) and volatile organic carbon (VOC, -11.27%) concentrations, which are major O3 precursors. The changes in the NO and O3 concentrations due to the removal of power plant emissions presented a strong negative correlation (r= -0.72). This indicated that the increase in the O3 concentration was mainly attributed to the significantly decreased NO concentration, thus, mitigating the O3 titration reaction (NO+O3→NO2+O2). Additionally, due to the VOC-limited (i.e., NOx-saturated) conditions in the study region, NO affected the O3 concentration, indicating that the O3 concentrations in a particular region are not only proportional to the increase or decrease in emissions. Therefore, an in-depth understanding of the chemical O3 production and loss in a particular region is necessary to accurately evaluate the effect of emission control on the changes in the O3 concentration.

The Temporal and Spatial Distribution of Volatile Organic Compounds(VOCs) in the Urban Residential Atmosphere of Seoul, Korea

  • Anthwal, Ashish;Park, Chan-Goo;Jung, Kweon;Kim, Min-Young;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.42-54
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    • 2010
  • Automobile emissions have caused a major hydrocarbon pollution problem in the ambient air of many cities around the world. This study was conducted to measure the pollution status of volatile organic compounds (VOCs) in some urban residential areas in Seoul, Korea. A total of 20 VOCs (11 aromatic and 9 chlorinated species) were identified at 4 urban residential sites in Seoul, Korea from February 2009 to July 2009. Comparison of total VOC (TVOC) concentration data indicated the dominance of the aromatic species with the maximum (72.2 ppbC) at Jong Ro (JR) and the minimum at Yang Jae (33.4 ppbC). The peak concentration of TVOC occurred during spring at all sites with an exception at Gang Seo (GS), where it was recorded during winter. The distribution of individual VOCs at the study sites was characterized by high toluene concentration. A strong correlation of benzene was also observed with other VOCs and criteria pollutants at all sites (except YJ). The overall results of this study suggest that vehicular emissions have greatly contributed to the increase in VOC pollution at all the study sites.

A Study on the Characteristics of Natural VOC Emissions from Pine Trees in Season (계절별 소나무로부터 배출되는 자연 VOC(NVOC) 배출특성에 관한 연구)

  • 김조천;임준호;홍지형;전의찬;주명칠;조규탁
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.93-94
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    • 2003
  • 대기 중 휘발성유기화합물(Volatile Organic Compounds)은 인간에게 직접적으로 위해한 영향을 준다는 보건학적인 측면과 광화학스모그 생성에 관여한다는 이유 등으로 많은 주목을 받고있다. 식생은 자연 VOC(NVOC)의 가장 주요한 배출원이며, 대기중으로 유입되는 반응성이 강한 탄소의 주요한 배출원이며, 전 세계적으로는 NVOC의 배출량이 인위적인 것의 약 7배정도에 이를 것으로 추정되고 있다. 우리나라의 경우 전 국토의 2/3이상이 산림으로 이루어져 있어 NVOC가 인위적인 VOC의 양을 훨씬 초과할 것이라고 사료된다. (중략)

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A study on the characteristics of Natural VOC emissions from Oak trees in species (참나무 수종별 자연 VOC 배출특성에 관한 연구)

  • 김조천;김기준;임수길;임용재;홍지형;강창희
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.287-288
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    • 2003
  • 식물은 자연 VOC(NVOC)의 가장 주요한 배출원이며, 대기중으로 유입되는 반응성이 강한 탄화수소의 배출원이다. 이러한 NVOC는 다소 늦게 알려진바 1970년대부터 그 중요성이 인식되기 시작했다(Dimitriades, 1981). 전 세계적으로는 NVOC의 배출량이 인위적인 것의 약 7배 정도에 이를 것으로 추정되고 있다. 특히, 우리나라의 경우는 전 국토의 65%가 산림으로 이루어져 있어 전국적인 규모로 볼때 NVOC의 양이 인위적인 VOC의 양을 휠씬 초과할 것이라고 판단된다. 그럼에도 불구하고 국내에서는 NVOC에 대한 정량적인 배출량 산출이 거의 없어 배출량 산정에 어려움이 많고, 외국 자료를 인용한 배출량 산출로 인해 자료의 신뢰성에도 논란의 여지가 많았다. (중략)

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Current Status of Ship Emissions and Reduction of Emissions According to RSZ in the Busan North Port (부산 북항에서의 선박 배출물질 현황과 선속제한에 의한 배출량 감소 연구)

  • Lee, Bo-Kyeong;Lee, Sang-Min
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.5
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    • pp.572-580
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    • 2019
  • In view of the numerous discussions on global environmental issues, policies have been implemented to limit emissions in the field of marine transport, which accounts for a major part of international trade. In this study, a ship's emissions were calculated by applying the engine load factor to determine the total quantity of emissions based on the ship's speed reduction. For ships entering and leaving the Busan North Port from 1 January to 31 December 2017, emissions were calculated and analyzed based on the ship's type and its speed in the reduced speed zone (RSZ), which was set to 20 nautical miles. The comparison of the total amount of emissions under all situations, such as cruising, maneuvering, and hotelling modes revealed that the vessels that generated the most emissions were container ships at 76.1 %, general cargo ships at 7.2 %, and passenger ships at 6.8 %. In the cruising and maneuvering modes, general cargo ships discharged a lesser amount of emission in comparison with passenger ships; however, in the hotelling mode, the general cargo ships discharged a larger amount of emission than passenger ships. The total emissions of nitrogen oxides (NOx), sulphur oxides (SOx), particulate matter (PM), and volatile organic compounds (VOC), were 49.4 %, 45 %, 4 %, and 1.6 %, respectively. Furthermore, the amounts of emission were compared when ships navigated at their average service speed, 12, 10, and 8 knots in the RSZ, respectively. At 12 knots, the reduction in emissions was more than that of the ships navigating at their average service speed by 39 % in NOx, 40 % in VOC, 42 % in PM, and 38 % in Sox. At 10 knots, the emission reductions were 52 %, 54 %, 56 %, and 50 % in NOx, VOC, PM, and Sox, respectively. At 8 knots, the emission reductions were 62 %, 64 %, 67 %, and 59 % in NOx, VOC, PM, and Sox, respectively. As a result, the emissions were ef ectively reduced when there was a reduction in the ship's speed. Therefore, it is necessary to consider limiting the speed of ships entering and leaving the port to decrease the total quantity of emissions.

A study on the characteristics of Monoterprene emissions from Coniferous trees (침엽수로부터 배출되는 Monoterprene 배출특성에 관한 연구)

  • 김조천;임준호;홍지형;선우영;강창희;신원섭
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.53-54
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    • 2003
  • 식생은 자연 VOC(NVOC)의 가장 주요한 배출원이며, 대기중으로 유입되는 반응성이 강한 탄화수소의 주요한 배출원이다. 이러한 NVOC의 연구가 외국의 경우 상당 부분 이루어져 있으며, 전 세계적으로는 NVOC의 배출량이 인위적인 VOC의 약 7배정도에 이를 것이라고 추정되고 있다. 우리나라는 국토의 2/3이상이 삼림으로 이루어져 있지만 NVOC에 대한 직접적인 배출량 산정은 거의 이루어진 바가 없다. 우리나라의 배출량 산정에 사용된 NVOC 배출계수는 주로 외국의 자료에만 의존하여 사용되었다. (중략)

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Estimation of VOCs Emissions from Laundries (세탁시설에서 방출되는 VOCs의 배출량 산정)

  • 김만구;박정진;정영림
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.231-232
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    • 2002
  • 대기 중 휘발성유기화합은 오존생성의 전구물질 및 유해화학물질 그리고 일부는 악취물질로 작용하는 주요 대기오염물질로 주목받고 있으며, 여러 가지 VOCs의 배출원 중에서 세탁소도 주요 발생원중 하나로 주목받고 있다. 세탁에 사용되는 유기용제에는 퍼클로로에틸렌(PCE)과 불소계용제, 석유계 용제가 있는데 일본을 제외한 외국에서는 밀폐형기계인 PCE를 사용하고 있는데 반해, 우리나라에서는 약 95% 정도의 세탁소가 석유계 용제를 사용하고 있다. (중략)

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The Composition and Emission Characteristics of VOCs from Major Waste Landfill Sites in Korea (전국 주요 쓰레기매립장 지역에 대한 VOC 성분의 조성과 배출특성에 대한 연구)

  • Kim, Ki-Hyun;Choi, Ye-Jin;SunWoo, Young
    • Journal of Environmental Policy
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    • v.4 no.1
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    • pp.69-91
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    • 2005
  • In order to accurately evaluate the distribution and emission characteristics of volatile organic compounds(VOCs) produced in the landfill environment, we conducted a series of field campaign to measure VOC emissions from a total of eight landfill sites located all across the Korean Peninsula. During the field measurements made from Sept. 2000 to Dec. 2004, we investigated VOC emission characteristics from 1 large scale, 5 mid scale, and 2 small scale landfill sites. The results from our 4-years study is used to provide valuable information for the management of landfill facilities in Korea. If annual emission rates of VOC are compared in terms of toluene, the magnitude of its emission differed between the closed and active landfills. Whereas closed landfills show emission rates from a few tens to 500g/yr, those of active ones were recorded as 1,000 to 40,000g/yr.

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