• 제목/요약/키워드: VOC emissions

검색결과 117건 처리시간 0.024초

A Stochastic Analysis of VOC Emissions from the Distribution Process of the Gasoline

  • Han, Wha-Jin;Song, Yanghoon;Cho, Yongsung
    • Journal of Korean Society for Atmospheric Environment
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    • 제17권E4호
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    • pp.163-168
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    • 2001
  • Estimating the emission rate of VOCs from a gasoline industry at national level can be a challenging take even though the estimation is mean-based. However, using the procedures in the US EPA AP-42 guidelines, it is possible to approximate the mean industry emission rate once enough data are available. However, this estimate can be misled in the sense that there exist many stochastic factors in the EPA\\`s estimation procedures and also throughout the marketing channels of gasoline industry. Addressing the stochasticity problem in EPA\\`s procedure is hard to tackle because the detailed data needed to execute the estimation are not usually available even from refiners. Instead, this research tries to stay focused on the second type of stochasticity issue, raised from the mean0based metrological and marketing practice data collected from the 4 major refiners. To do so emission raters from each marketing channels (8 marketing points by 3 transportation types and by storage facilities of 4 refiners) are estimated monthly, following AP-42 procedures and using Tank 4.0. Once these estimates are acquired, the distribution of VOC emission rate for each marketing channel of all 4 refiners is estimated through simulation method using @Risk. The mean-based emission rates are weighted by company quantities to estimate the emission rate from the whole gasoline industry. Simple economic implication is provided, based on the result. This study found that, on the mean-bases, about 0.66% of gasoline marketed are evaporated into air. Considering the stochasticity in the estimation, about 90% of simulation results fell into the range of 0.65 to 0.68%. For 90% chance, the estimated economic loss is $54.65 million to $57.17 million, not counting the cost caused by air quality degradation and associated health impact.

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권역별 대기오염물질의 연도별 배출 특성 분석 (Analysis of Annual Emission Trends of Air Pollutants by Region)

  • 임준현;곽경규;김정;장영기
    • 한국대기환경학회지
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    • 제34권1호
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    • pp.76-86
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    • 2018
  • Using the CAPSS emissions data, we analysed changes and reasons in the annual air pollutant emission trends from 1999 to 2014. The CO emissions in the metropolitan area decreased steadily since 2001, when the latest model year of automobiles and high efficiency fuel were applied. However, other regions have not changed significantly in annual emissions. $NO_x$ emissions continued to increase since 2003, and unchanged after the decline in 2007. $SO_x$ emissions are steadily declining due to the supply of low sulfur oil. The $PM_{10}$ and $PM_{2.5}$ emissions were repeatedly affected by the influence of motor vehicles activities in the metropolitan area. In Gangwon and Chungcheong Provinces, emissions are increasing according to the use of coal in the manufacturing sector. And VOC and $NH_3$ emissions are increasing steadily every year. The major CO emission sources was automobiles in the metropolitan area. However, agricultural residue burning was the biggest CO sources in the Chungchong, Honam and Yeongnam Provinces. The major sources of $NO_x$ emissions differ from region to region. In the Metropolitan area, Honam and Yeongnam region, the truck was the largest emitter of $NO_x$. However, the cement kiln was the largest producer of $NO_x$ in Gangwon region, and the power plant is the largest emitter in Chungcheong Provinces.

The impact of corrosion on marine vapour recovery systems by VOC generated from ships

  • Choi, Yoo Youl;Lee, Seok Hee;Park, Jae-Cheul;Choi, Doo Jin;Yoon, Young Soo
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제11권1호
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    • pp.52-58
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    • 2019
  • Marine emissions of Volatile Organic Compounds (VOCs) have received much attention because the International Maritime Organization (IMO) requires the installation of vapour emission control systems for the loading of crude oils or petroleum products onto ships. It was recently recognised that significant corrosion occurs inside these vapour emission control systems, which can cause severe clogging issues. In this study, we analysed the chemical composition of drain water sampled from currently operating systems to investigate the primary causes of corrosion in vapour recovery systems. Immersion and electrochemical tests were conducted under simulated conditions with various real drain water samples, and the impact of corrosion on the marine vapour recovery system was carefully investigated. Moreover, corrosion tests on alternative materials were conducted to begin identifying appropriate substitutes. Thermodynamic calculations showed the effects of environmental factors on the production of condensed sulphuric acid from VOC gas. A model of sulphuric acid formation and accumulation by the characteristics of VOC from crude oil and flue gas is suggested.

유류오염토양으로부터 발생하는 VOC가스처리를 위한 바이오스크러버 개발 (Development of a Bioscrubber for Treatment of VOC Emissions from Contaminated Soil with Hydrocarbons)

  • 장윤영;황경엽;곽재호;최대기
    • 한국토양환경학회지
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    • 제2권1호
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    • pp.83-90
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    • 1997
  • 저농도의 난 수용성 VOC가스가 포함되어 있는 다량의 오염가스를 처리하기 위하여 흡수탑과 생물반응기의 결합체인 새로운 처리시스템을 제시하였다. 바이오스크러버의 스크러버에서는 세정액으로 기상중의 처리대상오염물질의 흡수가 일어나며 세정액은 생물반응기로 이송되어 호기성 미생물이 오염물을 분해시킨다. 본 연구에서는 폐가스중의 VOC분리를 위하여 재순환가능한 고비점용매를 사용하였다. 고비점용매를 포함한 세정액은 기/액 향류접촉이 이루어지는 흡수탑의 충전층에서 폐가스중의 오염물을 분리한다. 흡수탑은 Pall ring충전제로 채워 실제공정을 모사 하고자 하였다. 흡수처리후 생물반응기로 이송된 흡수액은 재생 후 다시 흡수탑으로 재 순환하였다. 실험에 사용된 대상가스는 농도가 400 mg/$\textrm{m}^3$ 인 톨루엔으로, 세정액이 가스흐름과 향류로 약 10~15L/min의 유량으로 충전층을 적시며 내려오는 충전탑내부로 약 100 L/min의 유량으로 도입하였다. VOC처리를 위해 제작된 본 바이오스크러버에서 고비점용매를 이용한 연속실험결과 최적운전 조건에서 약 80%의 처리율을 얻을 수 있었다.

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산업체 VOC/악취 저감기술 (Removal Technologies of Odor and Volatile Organic Compounds from Industrial Processes)

  • 추수태;남창모
    • 한국산업융합학회 논문집
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    • 제7권3호
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    • pp.289-297
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    • 2004
  • Emissions of volatile organic compounds and odors from various industrial processes not only pollute surrounding life environments, but also lead to the deterioration of the working environments, causing various industrial health and business problems. These pollutants are usually stimulating, irritating, malodorous and sometimes carcinogenic, Which should be reduced in the pollutants formation, stage, but the practical processes do not allow This paper describes the major sources of VOC and odors, and their sampling/analysis methods. Furthermore, various removal technologies for these pollutants are suggested, which particularly include the characteristics of the catalytic and scrubber/carbon filter combined process, and even process design technologies.

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CB4를 이용하여 부산 지역의 오존 전구 물질의 배출량에 대한 오존 농도의 민감도 (Sensitivity of Ozone Concentrations to Ozone Precursor Emissions In Busan Metropolitan Area Using the Carbon Bond Mechanism IV)

  • Lee, Hwa-Woon;Roh, Soon-A;Kim, Heon-Sook
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.362-363
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    • 2003
  • Photochemical ozone is formed from nitrogen oxides (NOx) and volatile organic compounds(VOCs) through non-linear interactions between chemical reactions and meteorology, and the relationship between precursors and photochemical ozone will be changed to match the emission distribution and meteorological fields. It is generally known that for some conditions the process of ozone formation is controlled almost entirely by NOx and is largely independent of VOC, while for other conditions ozone production increases with increasing VOC and does not increase(or sometimes even decreases) with increasing NOx (omitted)

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Emission Reduction of Air Pollutants Produced from Chemical Plants

  • Lee, Byeong-Kyu;Cho, Sung-Woong
    • Journal of Korean Society for Atmospheric Environment
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    • 제15권E호
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    • pp.29-38
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    • 1999
  • This study identified emission sources and emissions of air pollutants such as volatile organic compounds (VOCs), solvents, and acid gases produced from chemical plants. We collected air samples from various processes, reactors and facilities using VOC detectors and workers' experience. We identified chemical structures and emission concentrations of air pollutants. We analyzed total emissions of air pollutants emitted from the chemical plants. Also, we developed some emission reduction technologies based on chemical types and emission situations of the identified air pollutants. For reduction of air emissions of acid gases, we employed a method improving solubility of pollutants by reducing scrubber operation temperature, increasing surface area for effective contact of gas and liquid, and modifying or changing chemicals used in the acid scrubbers. In order to reduce air emissions of both amines and acid gases, which have had different emission sources each other but treated by one scrubber, we first could separate gas components. And then different control techniques based on components of pollutants were applied to the emission sources. That is, we first applied condensation and then acid scrubbing method using H2SO4 solution for amine treatment. However, we only used an acid scrubbing method using H2O and NaOH solution for acid gas treatment. In order to reduce air emissions of solvents such as dimethylformamide and toluene, we applied condensation and activated carbon adsorption. In order to reduce air emissions of mixture gases containing acid gases and slovents, which could not be separated in the processes, we employed a combination of various air pollution control devices. That is, the mixture gases were passed into the first condenser, the acid scrubber, the second condenser, and the activated carbon adsorption tower in sequence. In addition, for improvement of condensation efficiency of VOCs, we changed the type of the condensers attached in the reactors as a control device modification. Finally, we could successfully reduce air emissions of pollutants produced from various chenmical processes or facilities by use of proper control methods according to the types and specific emission situations of pollutants.

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수도권 초미세먼지 농도모사 : (II) 오염원별, 배출물질별 자체 기여도 및 전환율 산정 (PM2.5 Simulations for the Seoul Metropolitan Area: (II) Estimation of Self-Contributions and Emission-to-PM2.5 Conversion Rates for Each Source Category)

  • 김순태;배창한;유철;김병욱;김현철;문난경
    • 한국대기환경학회지
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    • 제33권4호
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    • pp.377-392
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    • 2017
  • A set of BFM (Brute Force Method) simulations with the CMAQ (Community Multiscale Air Quality) model were conducted in order to estimate self-contributions and conversion rates of PPM (Primary $PM_{2.5}$), $NO_x$, $SO_2$, $NH_3$, and VOC emissions to $PM_{2.5}$ concentrations over the SMA (Seoul Metropolitan Area). CAPSS (Clean Air Policy Support System) 2013 EI (emissions inventory) from the NIER (National Institute of Environmental Research) was used for the base and sensitivity simulations. SCCs (Source Classification Codes) in the EI were utilized to group the emissions into area, mobile, and point source categories. PPM and $PM_{2.5}$ precursor emissions from each source category were reduced by 50%. In turn, air quality was simulated with CMAQ during January, April, July, and October in 2014 for the BFM runs. In this study, seasonal variations of SMA $PM_{2.5}$ self-sensitivities to PPM, $SO_2$, and $NH_3$ emissions can be observed even when the seasonal emission rates are almost identical. For example, when the mobile PPM emissions from the SMA were 634 TPM (Tons Per Month) and 603 TPM in January and July, self-contributions of the emissions to monthly mean $PM_{2.5}$ were $2.7{\mu}g/m^3$ and $1.3{\mu}g/m^3$ for the months, respectively. Similarly, while $NH_3$ emissions from area sources were 4,169 TPM and 3,951 TPM in January and July, the self-contributions to monthly mean $PM_{2.5}$ for the months were $2.0{\mu}g/m^3$ and $4.4{\mu}g/m^3$, respectively. Meanwhile, emission-to-$PM_{2.5}$ conversion rates of precursors vary among source categories. For instance, the annual mean conversion rates of the SMA mobile, area, and point sources were 19.3, 10.8, and $6.6{\mu}g/m^3/10^6TPY$ for $SO_2$ emissions while those rates for PPM emissions were 268.6, 207.7, and 181.5 (${\mu}g/m^3/10^6TPY$), respectively, over the region. The results demonstrate that SMA $PM_{2.5}$ responses to the same amount of reduction in precursor emissions differ for source categories and in time (e.g. seasons), which is important when the cost-benefit analysis is conducted during air quality improvement planning. On the other hand, annual mean $PM_{2.5}$ sensitivities to the SMA $NO_x$ emissions remains still negative even after a 50% reduction in emission category which implies that more aggressive $NO_x$ reductions are required for the SMA to overcome '$NO_x$ disbenefit' under the base condition.

Half-spherical Floating Chamber를 이용한 하$\cdot$폐수처리 시설에서의 온실기체 발생량 산정 (Estimating Greenhouse Gas Emissions from Municipal Wastewater using Half-spherical Floating chamber)

  • 전의찬;장영기;김득수;송민종;김전희
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 1999년도 추계학술대회 논문집
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    • pp.280-284
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    • 1999
  • 대기 중에는 $CO_2$, CH$_4$$H_2O$$_2$ 등 온실효과를 일으키는 가스가 포함되어 있고, 이들은 지구의 기온을 일정 수준으로 유지시켜 줌으로써 인간가 동식물에게 살기 좋은 환경을 제공한다. 그러나 산업 혁명 이후 화석 연료 및 화학 물질 사용 증가에 따라 $CO_2$, NOx 및 CFC, VOC 등의 온실가스는 다양한 경로를 통하여 대기 중으로 배출되고 이것은 지구 온난화의 원인이 되고 있다.(중략)

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건축자재에서 발생되는 VOCs와 HCHO의 방출특성에 관한 연구 (The Study on Characteristics of VOCs and Formaldehyde Emissions Rate from Building Materials)

  • 장미;김신도;윤중섭
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 추계학술대회 논문집
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    • pp.261-262
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    • 2003
  • 현대인들은 하루 중 80∼90% 이상의 많은 시간을 실내에서 생활하고 있어 실내에서의 발생되는 오염물질에 대한 특성파악은 무엇보다도 중요하다. 실내오염물질의 종류와 발생원은 매우 다양하며, 최근에는 산업발달과 더불어 수 많은 종류의 새로운 복합화합물질들이 발생되고 있다. 신축건물에 사용되는 건축자재는 휘발성유기화합물(VOCs)과 포름알데히드(HCHO)등의 다양한 유해화학물질들을 방출하고 실내공기질을 악화시키는 것으로 조사되고 있다. (중략)

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