• KIEAE Journal
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• v.1 no.1
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• pp.35-43
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• 2001

The VOC, which were detected from the newly built house, exist as a certain number of types according to the characteristics of the change of VOC concentration indoors. In this paper, we aim to divide the VOC into types so that those with similar characteristics of the transition of their concentration are in the same group and select the representative compound according to each classified type, and to verify these processes statistically in order to verify and propose new method creating the representing index of the VOC concentration in indoor which is used in evaluation of the degree of air pollution. As a result, the characteristic of the change of VOC concentration in the indoor can be divided into three types. Type1; the group in which the concentration is relatively high right after the completion of the house, and then decreases rapidly. Type2; the group in which the concentration is relatively low right after the completion of the house, and then although it shows the tendency of increasing and decreasing repeatedly, it decreases overall. Type3 is the group, which show only one peak at a certain time during the measuring period. As the method like this was verified to have the statistical significance, the Ethylbenzene was selected as the representative compound of type1, and Styrene was selected as that of type2. Moreover, if considering transition of the VOC from the point of similarity, the research method of making the classification and the selection of the representative compound in this study are said to be significant method.

• Journal of Environmental Policy
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• v.4 no.1
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• pp.69-91
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• 2005

In order to accurately evaluate the distribution and emission characteristics of volatile organic compounds(VOCs) produced in the landfill environment, we conducted a series of field campaign to measure VOC emissions from a total of eight landfill sites located all across the Korean Peninsula. During the field measurements made from Sept. 2000 to Dec. 2004, we investigated VOC emission characteristics from 1 large scale, 5 mid scale, and 2 small scale landfill sites. The results from our 4-years study is used to provide valuable information for the management of landfill facilities in Korea. If annual emission rates of VOC are compared in terms of toluene, the magnitude of its emission differed between the closed and active landfills. Whereas closed landfills show emission rates from a few tens to 500g/yr, those of active ones were recorded as 1,000 to 40,000g/yr.

• Journal of the Korean Society of Visualization
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• v.9 no.2
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• pp.54-60
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• 2011

This paper is a basic study on volatile organic compounds(VOC) recovery system in a crude oil carrier. VOC is easily evaporated in cargo tankers during loading and transportation of crude oil, causes serious environmental contamination and a huge economic loss. An ejector system is designed to mix VOC gas into crude oil flow to reduce VOC concentration. Detail two-phase flow inside the ejector is simulated using a commercial CFD code. To verify the numerical prediction, a scale-down experiment is conducted. Instead of crude oil and VOC, water and air are used as the working fluids. Flow characteristics and main parameters are obtained by two-phase flow visualization and PIV measurements. Air volume flow rate induced by the ejector is compared with respect to the volume flow rate of water using experimental and numerical results. Overall performance of the two-phase ejector predicted by the CFD simulation agrees well with that of the experiment.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.5
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• pp.580-602
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• 2011

Volatile organic compound (VOC) emissions in the 2007 CAPSS (Clean Air Protection Supporting System) emissions inventory are chemically speciated for the SAPRC99 (Statewide Air Pollution Research Center 99) mechanism, following the Source Classification Code (SCC) matching method to borrow the U.S.EPA's chemical speciation profiles. CMAQ simulations with High-order Direct Decoupled Method (HDDM) are in turn applied to evaluate uncertainty in the method by comparing the simulated model VOC species to the observations in the Seoul Metropolitan Area (SMA) for a 2007 June episode. Simulations under-predicted ALK1 to ALK4 in SAPRC99 by a factor of 2 to 5 and over-predicted ALK5 by a factor of 7.5 while ARO1, ARO2, OLE1, and ethylene (ETH) are comparable to the observations, showing relative difference by 10 to 30%. OLE2 emissions are roughly 4 times overestimated. Emission rates for individual VOC model species are revised referring to the ratio of simulated to observed concentrations. Impact of the VOC emission changes on the overall ozone prediction was insignificant for the days of which 1-hr maximum ozone are lower than 100 ppb. However, simulations showed ozone difference by 5 to 10 ppb when high ozone above 120 ppb was observed in the vicinity of Seoul. This result suggests that evaluations on individual model VOC emissions be necessary to lead ozone control plans to the right direction. Moreover, the simulated ratios of ARO1 and ARO2 to $NO_x$ are roughly 50% lower than the observed ones, which imply that adjustment in $NO_x$ and VOC emission rates may be required to mimic the real VOC/$NO_x$ condition over the area.

• Journal of Environmental Science International
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• v.20 no.11
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• pp.1465-1481
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• 2011

The accuracy of ozone sensitivity coefficients estimated with HDDM (High-order Decoupled Direct Method) can vary depending on the $NO_x$ (Nitrogen Oxides) and VOC (Volatile Organic Compound) conditions. In order to evaluate the applicability of HDDM over the Seoul Metropolitan Area (SMA) during a high ozone episode in 2007 June, we compare BFM (Brute Force Method) and HDDM in terms of the $1^{st}$-order ozone sensitivity coefficient to explain ozone change in response to changes in NOx and VOC emissions, and the $2^{nd}$-order ozone sensitivity coefficient to represent nonlinear response of ozone to the emission changes. BFM and HDDM estimate comparable ozone sensitivity coefficients, exhibiting similar spatial and temporal variations over the SMAduring the episode. NME (Normalized Mean Error) between BFM and HDDM for the episode average $1^{st}$- and $2^{nd}$-order ozone sensitivity coefficients to NOx and VOC emissions are less than 3% and 9%, respectively. For the daily comparison, NME for the $1^{st}$- and $2^{nd}$-order ozone sensitivity coefficients are less than 4% ($R^2$ > 0.96) and 15% ($R^2$ > 0.90), respectively. Under the emission conditions used in this study, two methods show negative episode average $1^{st}$-order ozone sensitivity coefficient to $NO_x$ emissions over the core SMA. The $2^{nd}$-order ozone sensitivity coefficient to $NO_x$ emissions leads ozone to respond muchnonlinear to the reduction in $NO_x$ emissions over Seoul. Nonlinear ozone response to reduction in VOC emissions is mitigated due to the $2^{nd}$-order ozone sensitivity coefficient which is much smaller than the $1^{st}$-order ozone sensitivity coefficient to the emissions in the magnitude.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.136-143
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• 2013

In this study, both transient behaviors of a biofilter system with improved design and a conventional biofilter were observed to perform the treatment of waste air containing malodor and volatile organic compound (VOC). Their behaviors of removal efficiency and treated concentration of malodor and VOC were compared each other. During 1st~7th stages of improved biofilter system operation it was observed that the order of treated ethanol concentration at each sampling port was switched due to the difference of microbe-population-distribution in spite of the difference of biofilter effective height. However, at 8th stage of its operation, the order of treated ethanol concentration at each sampling port was consistent to the order of biofilter effective height at each sampling port. The same was applied to the case of hydrogen sulfide, even though the difference of switched treated-hydrogen sulfide-concentrations was less than that of switched treated-ethanol-concentrations. The ethanol-removal efficiency of the biofilter system with improved design was ca. 96%, which was greater by 2% than that of the conventional biofilter. The transient behavior of treated hydrogen sulfide concentration of both biofilters were similar to each other. However, the concentration of hydrogen sulfide treated by the biofilter system with improved design was observed lower than that by the conventional biofilter. The hydrogen sulfide-removal efficiency of the biofilter system with improved design was higher by ca. 2% than that of the conventional biofilter. Therefore, the hydrogen sulfide-removal efficiency of the biofilter system with improved design was observed to be enhanced by the same as its ethanol-removal efficiency.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.229-230
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• 2002

식생은 자연 VOC(NVOC)의 가장 주요한 배출원이며, 대기중으로 유입되는 반응성이 강한 탄소의 주요한 배출원이다. 전 세계적으로는 NVOC의 배출량이 인위적인 것의 약 7배정도에 이를 것으로 추정되고 있다. 우리나라의 경우 전 국토의 2/3이상이 산림으로 이루어져 있어 NVOC가 인위적인 VOC의 양을 훨씬 초과할 것이라고 사료된다. (중략)

• Journal of Distribution Science
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• v.7 no.2
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• pp.89-119
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• 2009

The purpose of this research is showing an appropriate way of maximizing customer service and establishing VOC system by analyzing different voices from complaining customers as well as loyal customers. This research is also aimed at figuring out how companies can implement effective service marketing methods in the field complying with customers' needs and how they can survive in the competition. The range of research is confined to 5 marketing companies and their web-sites on which customers can get logged and directly post their claims. These web-sites showed how those 5 companies cope with customer claims. A questionnaire research was made in A's store to evaluate customer satisfaction. These are conclusions drawn by this research. First, prompt reactions of sincerity to customers' claims contribute to building favorable corporate images. Second, the preference to VOC channels varies with age and sex. Marketers should implement respectively different channels for customers under age 30 and those over age 40. Women have a tendency to prefer instant phone conversations and want to have their claims well listened to. Third, a series of shift in customer trend drives companies into establishing their own interactive VOC systems based on customers' preferences. Customer-oriented management has become a key factor for survival in recent intensely competitive market situation, as the web-based e-commerce market has been rapidly growing accompanied with a dramatic advance of network marketing methods. This research suggests some practical methods to establish a customer-oriented VOC system that can be easily adopted in the field.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.308-309
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• 2016

Reducing surface recombination is a critical factor for high efficiency silicon solar cells. The passivation process is for reducing dangling bonds which are carrier. Tunnel oxide layer is one of main issues to achieve a good passivation between silicon wafer and emitter layer. Many research use wet-chemical oxidation or thermally grown which the highest conversion efficiencies have been reported so far. In this study, we deposit ultra-thin tunnel oxide layer by PECVD (Plasma Enhanced Chemical Vapor Deposition) using $N_2O$ plasma. Both side deposit tunnel oxide layer in different RF-power and phosphorus doped a-Si:H layer. After deposit, samples are annealed at $850^{\circ}C$ for 1 hour in $N_2$ gas atmosphere. After annealing, samples are measured lifetime and implied Voc (iVoc) by QSSPC (Quasi-Steady-State Photo Conductance). After measure, samples are annealed at $400^{\circ}C$ for 30 minute in $Ar/H_2$ gas atmosphere and then measure again lifetime and implied VOC. The lifetime is increase after all process also implied VOC. The highest results are lifetime $762{\mu}s$, implied Voc 733 mV at RF-power 200 W. The results of C-V measurement shows that Dit is increase when RF-power increase. Using this optimized tunnel oxide layer is attributed to increase iVoc. As a consequence, the cell efficiency is increased such as tunnel mechanism based solar cell application.

• Journal of Soil and Groundwater Environment
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• v.12 no.6
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• pp.60-69
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• 2007

Understanding the behavior of gas phase VOCs (volatile organic compounds) in unsaturated soils is of a great environmental importance for public health concerns. Moment analysis for the breakthrough curves (BTCs) during transport of chemicals in porous media was known to be a useful tool to evaluate the velocity, spreadness, and the skewness of the plume of the chemicals. In this study, the temporal moments of the BTCs of a group of VOCs were analyzed for the gaseous transport in an unsaturated soil. BTCs were measured using lab-scale column experiments for four different VOCs at the water saturation range of 0.04-0.46, and for eleven VOCs at a water saturation of 0.21. The central second and third moments of the VOCs were compared with the water saturation and the first moment. It was found that both central second and third moments increased with the first moment. The central third moment was, however, found to be more sensitive to the first moment.