• Polymer(Korea)
• /
• v.35 no.6
• /
• pp.610-614
• /
• 2011

In this study, the effect of solvent on the pre-irradiation grafting of VBC(vinylbenzyl chloride) onto a ETFE(polyethylene-co-tetrafluoroethylene) was evaluated. ETFE film was irradiated to generate radical species onto its backbone chain. Each irradiated film was immersed into VBC monomer mixtures diluted with various solvents such as toluene, heptane, and isopropanol etc. for grafting process and then the degree of grafting of each film was measured. FTIR analysis confirmed that the VBC-g-ETFE film was successful prepared. For the films prepared in the various solvents, the mechanical strength and the distribution pattern of the graft polymer over the cross-section of the films were measured and the effect of solvent was evaluated.

• Journal of Korean Society of Environmental Engineers
• /
• v.38 no.10
• /
• pp.543-550
• /
• 2016

Amine-type PP-g-VBC-EDA adsorbent, which possesses anionic exchangeable function, was prepared through photoinduced graft polymerization of vinylbenzyl chloride (VBC) onto polypropylene non-woven fabric and subsequent amination reaction using ethylenediamine (EDA). Adsorption characteristics of anionic nutrients on the PP-g-VBC-EDA adsorbent have been studied by batch adsorption experiments. The equilibrium data well fitted the Langmuir isotherm model, and the maximum monolayer sorption capacity was found to be 59.9 mg/g for $NO_3-N$ and 111.4 mg/g for $PO_4-P$. The adsorption energies were higher than 8 kJ/mol indicating anion-exchange process as the primary adsorption mechanism. The pseudo-second order kinetic model described well the kinetic data and resulted in the activation energy of 9.8-36.7 kJ/mol suggesting that the overall rates of $NO_3-N$ and $PO_4-P$ adsorption are controlled by the chemical process. Thermodynamic parameters such as ${\Delta}G^o$, ${\Delta}H^o$ and ${\Delta}S^o$ indicated that the adsorption nature of PP-g-VBC-EDA for anionic nutrients is spontaneous and exothermic. The PP-g-VBC-EDA could be regenerated by washing with 0.1 N HCl.

• Polymer(Korea)
• /
• v.35 no.6
• /
• pp.586-592
• /
• 2011

In this study, we synthesized vinylbenzyl chloride-co-styrene-co hydroxyethyl acrylate (VBC-co-St-co-HEA) copolymer that can be applied to redox the flow battery process. The anion exchange membrane was prepared by the amination and crosslinking of VBC-co-St-co-HEA copolymer. The chemical structure and thermal properties of VBC-co-St-co-HEA copolymer and aminated VBC-co-St-co-HEA(AVSH) membrane were characterized by FTIR, $^1H$ NMR, TGA, and GPC analysis. The membrane properties such as ion exchange capacity(IEC), electrical resistance, ion conductivity and efficiency of all-vanadium redox flow battery were measured. The IEC value, electrical resistance, and ion conductivity were 1.17 meq/g, $1.9{\Omega}{\cdot}cm^2$, 0.009 S/cm, respectively. The charge-discharge efficiency, voltage efficiency and energy efficiency from all-vanadium redox flow battery test were 99.5, 72.6 and 72.1%, respectively.

• Proceedings of the KIEE Conference
• /
• 2009.04b
• /
• pp.165-167
• /
• 2009

The purpose of this paper is to develop a VBC (Voltage Bus Conditioner) system for a DC DPS (Distributed Power System). The advantages of the proposed VBC system are as follows: 1) the storage capacitor use smaller value than the conventional capacitive storage 2) the controller requires only one sensor to both damp the voltage transients and maintain the storage voltage. The performance of the proposed VBC system has been simulated and evaluated by Saber package.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.62 no.7
• /
• pp.943-949
• /
• 2013

Recently, an electric vehicle (EV) has been become a huge issue in the automotive industry. The EV has many electrical units: electric motors, batteries, converters, etc. The DC distribution power system (DPS) is essential for the EV. The DC DPS offers many advantages. However, multiple loads in the DC DPS may affect the severe instability on the DC bus voltage. Therefore, a voltage bus conditioner (VBC) may use the DC DPS. The VBC is used to mitigate the voltage transient on the bus. Thus, a suitable control technique should be selected for the VBC. In this research, Current controller with fixed switching frequency is designed and applied for the VBC. The DC DPS consist of both a resistor load and a boost converter load. The load variations cause the instability of the DC DPS. This instability is mitigated by the VBC. The simulation results by Matlab simulink and experimental results are presented for validating the proposed VBC and designed control technique.

• Membrane Journal
• /
• v.18 no.2
• /
• pp.138-145
• /
• 2008

A series of anion exchange composite membranes were prepared and characterized for electro-dialysis process used in the removal of toxic anion and cation polutants in groundwater or wastewater. The membranes were prepared as follows; first, porous poly(ethylene) (PE) substrates were fully impregnated with monomer mixtures with various ratio of vinylbenzylchloride (VBC), divinylbenzene (DVB) and ${\alpha},\;{\alpha}$-azobis(isobutyronitrile) (AIBN). Second, they were thermally polymerized to yield crosslinked poly(VBC-DVB)/PE composite membranes. Finally, the membranes were treated in trimethylamine (TMA)/acetone to give $-N^+(CH_3)_3$-containing poly(VBC-DVB)/PE membranes. The basic membrane properties such as ion exchange capacity (IEC), electric resistance and water content of the resulting membranes were measured as a function of VBC/DVB and TMA/Acetone content. As a result, the composite membranes showed lower electric resistance, lower water content and higher IEC than commercial anion exchange membranes (AMX, Astom) due to thin PE substrates, indicating that the composite membranes could be successfully applied to the electrodialysis for water treatment.

• Proceedings of the KSR Conference
• /
• 2011.10a
• /
• pp.2348-2356
• /
• 2011

In recent years, many researches for DC power distributed system (PDS) are being preformed and the importance of the DC PDS is more and more emphasized. Furthermore, in the railway system, the DC PDS is used in subway station lighting, facilities, etc. In the DC PDS, DC bus voltage instability may be occurred by the operation of multiple parallel loads such as pulsed power load, motor drive system, and constant power loads. Thus, good quality and high reliability for electric power are required and voltage bus conditioner (VBC) may be used the DC PDS. The VBC is a DC/DC converter for mitigation of the bus transients. In this paper, adaptive controller is designed. The simulation results by PSIM are presented for validating the proposed control algorithm.

• Proceedings of the KIEE Conference
• /
• 2011.07a
• /
• pp.1141-1142
• /
• 2011

An electrical vehicle (EV) is a huge issue in the automotive industry. The EV have many electrical units: electric motors, batteries, converters, ets. The DC power distribution system (PDS) is essential for the EV. The DC PDS offers many advantages. However, multiple loads in the DC PDS may affect the severe instability on the DC bus voltage. Therefore, a voltage bus conditioner (VBC) may use the DC PDS. The VBC is used to mitigate the voltage transient on the bus. In this paper, sliding mode controller (SMC) is designed for the VBC of DC PDS in the EV. The simulation results by PISM simulation package are presented for validating the proposed control technique.

• Journal of international Conference on Electrical Machines and Systems
• /
• v.1 no.3
• /
• pp.391-396
• /
• 2012

The Voltage Bus Conditioner(VBC) is a bidirectional DC-DC converter for damping the instability and any transients of the bus voltage in a DC Distributed Power System(DPS). In this paper, a PI controller for the VBC has been designed for the frequency domain. The proposed PI controller not only dampens the bus transients, but also keeps the storage voltage level. Simulation by Matlab/Simulink and experimental results are presented for the validity of the proposed control technique.

• Polymer(Korea)
• /
• v.36 no.5
• /
• pp.564-572
• /
• 2012

A terpolymer of vinylbenzyl chloride-co-ethyl methacrylate-co-styrene (VBC-EMA-St) was prepared for membrane capacitive deionization (MCDI) by radical polymerization and amination reaction of various amination times. Nonfluoro aminated VBC-EMA-St anion-exchange membranes were characterized by Fourier transform infrared (FTIR) spectrometry. Molecular weight, polydispersity and thermal stability were obtained by gel permeation chromatography (GPC) and thermogravimetric analysis (TGA). The basic properties such as water uptake, ion exchange capacity, electrical resistance and CDI charge-discharge current were measured. The optimal values of ion exchange capacity, water uptake, electrical resistance and molecular weight of synthesized anion-exchange membrane were 1.69 meq/g, 23.7%, 1.61 ${\Omega}{\cdot}cm$ and $3.4{\times}10^4$ g/mol, respectively. As compared with conventional membrane, the pattern of cyclic charge-discharge current of synthesized anion-exchange membrane indicated efficient electrosorption and desorption.