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Study on The lonzation Potential, Electron Affinity and Electrochemical Property of PBO and PVK using Cyclic Voltammetry and Constant Current Potentiometry (순환전압전류법과 일정전류전위차법을 이용한 PBD와 PVK의 이온화에너지, 전자친화도 및 전기화학적 특성에 관한 연구)

  • 형경우;최돈수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1273-1277
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    • 2003
  • The effects of molecular structure on the redox properties are explored by the cyclic voltammetry, constant current potentiometry and spectroscopy using the thin films of organic electroluminescence materials of Poly(N-vinylcarbazole); PVK and 2- (4'-tert-butylphenyl) -5-(4"-bisphenyl) -1,3,4-oxadiazole; PBD. The UV/visible absorption maxima and band gap (E$\_$g/) show at 310nm (4.00eV) and 368nm (3.37eV) for FBD, 344nm (3.60eV) and 356nm (3.48eV) for PVK, respectively. The measured electrochemical ionization potential (IP) and electron affinity (EA) of these materials we 5.87 and 2.82eV for PBD, 5.80 and 3.17eV for PVK, respectively. The electrical band gaps are 3.05eV for PBD and 2.78eV for PVK, respectively. The electrical hole gap and electron gap with respect to the first rising potentials and the inflection potentials are obtained to be 0.39V and 0.41V for PBD, 0.25V and 0.28V for FVK, respectively.

Improved Rate Capability of Li/Li3V2(PO4)3 Cell for Advanced Lithium Secondary Battery

  • Lim, Hyun-He;Cho, A-Ra;Sivakumar, Nagarajan;Kim, Woo-Seong;Yoon, Won-Sub;Lee, Yun-Sung
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1491-1494
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    • 2011
  • Lithium vanadium phosphate, $Li_3V_2(PO_4)_3$ was prepared by a simple solid state route. It was found that making a fine powder of $Li_3V_2(PO_4)_3$ by the mechanical milling is very effective for increasing the insertion/extraction of lithium from $Li_3V_2(PO_4)_3$ structure. In charge/discharge test, the ball-milled $Li_3V_2(PO_4)_3$ sample exhibited a higher initial discharge capacity of 174 mAh/g in the voltage range of 3.0-4.8 V, compared with pure $Li_3V_2(PO_4)_3$ sample (152 mAh/g). Furthermore, the ball-milled $Li_3V_2(PO_4)_3$ presented not only higher cycle retention rate after 50 cycles, but also better rate capability compared with pure sample in the whole region (0.1-7 C).

Manufacturing Process of the Ti-6Al-4V Billet by the Open-die Forging (자유형 단조 공정에 의한 Ti-6Al-4V 빌렛 제조기술)

  • Kim, K.J.;Choi, S.S.;Hwang, C.Y.;Kim, J.S.;Yeom, J.T.;Lee, J.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.377-380
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    • 2006
  • Manufacturing process of Ti-6Al-4V alloy billet was investigated with FEM simulation and experimental analysis. Before the breakdown process of Ti-6Al-4V alloy ingot, FEM simulation for the breakdown processes of Ti-6Al-4V alloy ingot was used to calculate the forging load and state variables such as strain, strain rate and temperature. In order to breakdown the ingot structure and make an equiaxed structure billet, two different processes were employed for a VAR/VAR processed Ti-6Al-4V alloy ingot. Firstly, the ingot was cogged in single-phase $\beta$ field at the temperature of $1,100^{\circ}C$. In the process, the coarse and inhomogeneous structure developed by the double melting process was broken down. The second breakdown was performed by upsetting and cogging processes in $\alpha+\beta$ phase field to obtain the microstructure of fine equixed $\alpha$ structure in the matrix of transformed $\beta$. Finally, the mechanical properties of Ti-6Al-4V alloy billet made in this work were compared with those of other billet and ring product.

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A study on the Spinel phase cathode materials with high capacity for lithium secondary batteries (리튬 2차 전지용 고용량 스피넬계 양극물질 연구)

  • Hong, Ki-Joo;Sun, Yang-Kook
    • Proceedings of the KIEE Conference
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    • 2001.11b
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    • pp.106-108
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    • 2001
  • As 3V cathode material, a new doping spinel material, LiMn1.6Se0.4O4 powder with a phase-pure polycrystalline was synthesized by a sol-gel method. In spite of Jahn-teller distortion in 3V region($2.4{\sim}3.5V$), the LiMn1.6Se0.4O4 electrode shows no capacity loss. The material in the 3V region initially delivers a discharge capacity of 100mAh/g which increase with cycling to reach 105mAh/g after 90cycles. And 5V cathode material LiNi0.5-xMxMn1.5O4(M=Cr, V, Fe) compounds have been synthesized by sol-gel method. a series of electroactive spinel compounds, LiNi0.5-xMxMn1.5O4(M=Cr, V, Fe) has been studied by crystallographic and electrochemical methods. The material presents only one plateau at around 4.5 V vs. Li/Li+ with a large discharge capacity of 152mAh/g and fairly good cyclability.

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Optimal Culture Conditions for Doxorubicin Production by a Mutant of Streptomyces peucetius subsp. caesius (Streptomyces peucetius subsp. caesius 돌연변이주에 의한 doxorubicin생산의 최적배양조건)

  • Kim, Seung-Wook;Song, Soo-Moon;Moon, Soon-Ok
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.660-666
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    • 1997
  • The production of doxorubicin by a mutant of Streptomyces peucetius subsp. caesius was studied. The optimal culture conditions, such as inoculum size and medium composition were established to improve the productivity of doxorubicin. The optimal medium composition was found to be 4% maltose, 0.5% HEPES, 0.02% $K_2HPO_4$, 0.01% $MgSO_4$. As an antiform agent, 0.001% KG(10% Adekanol+10% Silicone) was suitable one among various agents. Culture was carried out in 2.5 L jar-fermenter with different aeration rates of 1.5, 1.0, and 1.5 v/v min. The maximum production of doxorubicin(29 mg/l) was obtained at 1.5 v/v min of aeration rate, and even at 1.0 v/v min, the production of doxorubicin was increased up to 15% compared with that of shake-flask culture.

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The effects of electroacupuncture on blood concentration of gastrointestinal motility-related endocrine substances in horses (전침자극(電針刺戟)이 말의 위장관운동관련 내분비물질(內分泌物質)의 혈중농도(血中濃度)에 미치는 영향)

  • Kim, Byung-sun;Choi, Hee-in
    • Korean Journal of Veterinary Research
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    • v.38 no.3
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    • pp.614-628
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    • 1998
  • The effects of electroacupuncture(EA) on blood concentration of endocrine substances were investigated in 6 horses. Three acupuncture points ; Guan Yuan Shu(BL-26), Wei Shu(BL-21) and Da Chang Shu(BL-25) were stimulated for 20 minutes by EA at separate occasions under varying condition ; 2V-1Hz, 2V-5Hz, 2V-30Hz, 4V-1Hz, 4V-5Hz and 4V-30Hz. Plasma levels of adrenocorticotropic hormone(ACTH), ${\beta}$-endorphin, epinephrine, norepinephrine and serum levels of gastrin were analysed. Blood samplings were carried out before, 0, 20 and 40 minutes after the EA stimulation. The serum gastrin levels were increased by 2V-5Hz stimulation on the Wei Shu. Plasma ACTH levels were decreased by 2V-1Hz stimulation on the Wei Shu, but largely increased by 4V-30Hz stimulation on the Guan Yuan Shu. Plasma ${\beta}$-endorphin levels were slightly increased or decreased by 2V-1Hz stimulation, but largely increased by 4V-30Hz stimulation on the Guan Yuan Shu. Plasma levels of epinephrine and norepinephrine were not so much changed by 2V-1Hz or 5Hz stimulation, but tended to increase by 4V-30Hz stimulation on Guan Yuan Shu. These results suggest that the low voltage-low frequence EA stimulation increased blood concentration of gastrin, but decreased ACTH, ${\beta}$-endorphin, epinephrine and norepinephrine, whereas high voltage-high frequence EA stimulation induced opposite results. Accordingly, there appears to be a close relationship between the changes of gastrointestinal motility and the changes of blood concentration of endocrine substances by EA stimulation.

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Study on refining and melting of sponge Ti and Ti-6Al-4V alloy by electron beam melting (전자선 용해법에 의한 sponge Ti 및 Ti-6Al-4V 합금의 정련 및 용해에 관한 연구)

  • 김휘준;백홍구;윤우영;이진형;강춘식
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.2
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    • pp.224-234
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    • 1997
  • In order to make high purity materials including low contents of interstitial impurities, 70 ㎾ electron beam melter was manufactured. The sponge Ti and Ti-6Al-4V alloy were required and melted by electron beam melter. Based on the experimental results of sponge Ti refining by electron beam melting, the purity of Ti was increased for 180 seconds but thereafter did not significantly vary. In addition, it was found that with number of melting, the purity of Ti did and vary but the yield of Ti was decreased. As a results of Ti refining, high purity Ti of 3N (99.9 wt%) could be obtained including interstitial impurities with total contents of which were maximum 900 ppm. From the experimental results of Ti-6Al-4V alloy electron beam melting, the amounts of Al loss could be estimated through thermodynamic data calculated from the regular solution model and the model of solute removal kinetics and the alloy composition calculated from the models was in accord with the experimental composition of the alloy, It took 10 minutes to make Ti-29Al-4V alloy calculated from the model into Ti-6Al-4V alloy and the composition of Ti-6Al-4V alloy was very homogeneous.

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Fabrication and Measurement of 4H-SiC MESFET for High Friquency Applications (고주파용 4H-SiC MESFET 제작 및 측정)

  • Kim, Jae-Kwon;Song, Nam-Jin;Kim, Tae-Woon;Burm, Jin-Wook;An, Chul
    • Proceedings of the IEEK Conference
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    • 2002.06b
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    • pp.33-36
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    • 2002
  • MESFET was fabricated using 4H-SiC substrates and epitaxy The DC characteristics of 0.5 urn gate length, 400 urn gate width MESFET had $I_{dss}$=200 ㎃/mm, maximum transconductance of 12 ㎳/mm at Vrs=-4 V, V, Is=27 V. Thc device had an fT of 2.5 GHz and $f_{mdx}$ of 13.3 GHz at $V_{ds}$ =27 V and $V_{g}$=-4 V. The fabrication and characterization of this device are discussed.d.d.d.

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Densification Behavior of Ti-6Al-4V Powder Compacts at Room and High Temperatures (Ti-6Al-4V 분말 성형체의 상온 및 고온에서의 치밀화 거동)

  • Hong, Seung-Taek;Kim, Gi-Tae;Yang, Hun-Cheol
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.5 s.176
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    • pp.1124-1132
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    • 2000
  • Viscoplastic response and densification behaviors of Ti-6AI-4V powder compacts under uniaxial compression are studied at room and high temperatures with various initial relative densities and strain rates. The yield function and strain-hardening law proposed by Kim and co-workers were implemented into a finite element program (ABAQUS) to compare experimental data with finite element calculations for porous Ti6A14V powder compacts. Displacement-relative density, displacement-load relations and deformed geometry of Ti-A14V powder compacts were compared with finite element results. Density distributions in Ti-6AI-4V powder compacts were also measured and compared with finite element results.

Effects of Silkworm Hemolymph on Cell Viability and hCTLA4Ig Production in Transgenic Rice Cell Suspension Cultures

  • Cheon, Su-Hwan;Lee, Kyoung-Hoon;Kwon, Jun-Young;Ryu, Hyun-Nam;Yu, Da-Hyun;Choi, Yong-Soo;Kim, Dong-Il
    • Journal of Microbiology and Biotechnology
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    • v.17 no.12
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    • pp.1944-1948
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    • 2007
  • Silkworm hemolymph (SH), prepared from fifth-instar larvae of Bombyx mori and heat-treated at $60^{\circ}C$ for 30 min, was used to improve cell viability and the production of human cytotoxic T-lymphocyte antigen 4-immunoglobulin (hCTLA4Ig) in transgenic Oryza sativa L. cell suspension cultures. Even though SH could not elevate cell viability at the concentrations up to 3% (v/v), addition of 0.3% (v/v) SH to a culture medium enhanced the production of hCTLA4Ig by 36.8% over an SH-free medium. Moreover, the production period of hCTLA4Ig could be shortened in a 0.3% (v/v) SH-added medium compared with that in an SH-free culture. As a result, addition of 0.3% (v/v) SH improved the productivity of hCTLA4Ig significantly in transgenic rice cell cultures.