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Effect of Lithium Contents and Applied Pressure on Discharge Characteristics of Single Cell with Lithium Anode for Thermal Batteries (리튬 함량 및 단위 셀 압력이 열전지용 리튬 음극의 방전 성능에 미치는 영향)

  • Im, Chae-Nam;Ahn, Tae-Young;Yu, Hye-Ryeon;Ha, Sang Hyeon;Yeo, Jae Seong;Cho, Jang-Hyeon;Yoon, Hyun-Ki
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.2
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    • pp.165-173
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    • 2019
  • Lithium anodes (13, 15, 17, and 20 wt% Li) were fabricated by mixing molten lithium and iron powder, which was used as a binder to hold the molten lithium, at about $500^{\circ}C$ (discharge temp.). In this study, the effect of applied pressure and lithium content on the discharge properties of a thermal battery's single cell was investigated. A single cell using a Li anode with a lithium content of less than 15 wt% presented reliable performance without any abrupt voltage drop resulting from molten lithium leakage under an applied pressure of less than $6kgf/cm^2$. Furthermore, it was confirmed that even when the solid electrolyte is thinner, the Li anode of the single cell normally discharges well without a deterioration in performance. The Li anode of the single cell presented a significantly improved open-circuit voltage of 2.06 V, compared to that of a Li-Si anode (1.93 V). The cut-off voltage and specific capacity were 1.83 V and $1,380As\;g^{-1}$ (Li anode), and 1.72 V and $1,364As\;g^{-1}$ (Li-Si anode). Additionally, the Li anode exhibited a stable and flat discharge curve until 1.83 V because of the absence of phase change phenomena of Li metal and a subsequent rapid voltage drop below 1.83 V due to the complete depletion of Li at the end state of discharge. On the other hand, the voltage of the Li-Si anode cell decreased in steps, $1.93V{\rightarrow}1.72V(Li_{13}Si_4{\rightarrow}Li_7Si_3){\rightarrow}1.65V(Li_7Si_3{\rightarrow}Li_{12}Si_7)$, according to the Li-Si phase changes during the discharge reaction. The energy density of the Li anode cell was $807.1Wh\;l^{-1}$, which was about 50% higher than that of the Li-Si cell ($522.2Wh\;l^{-1}$).

Analysis of Insulation Breakdown Cause in 13.8 kV XLPE Cable (13.8 kV XLPE 케이블의 절연파괴 원인 분석)

  • Kim, Hee-Dong;Park, Yong-Hun;Park, Jae-Hyun;Kwon, Jae-Ho;Park, Deok-Hyun
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.1173-1174
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    • 2015
  • 내연 발전기(50 MW, 13.8 kV) 출력단자에서 차단기까지 연결된 13.8 kV XLPE(cross-linked polyethylene) 케이블에서 운전중에 절연파괴로 인해 지락이 발생하였다. XLPE 케이블의 건전성을 확인하기 위해 절연저항과 절연진단 시험을 수행하였다. 교류전압을 1~10 kV까지 증가하면서 XLPE 케이블의 유전정접 측정결과 A상과 C상은 0.1%로 일정하게 측정되었다. 반면에 B상의 유전정접은 1 kV에서 0.54%, 2 kV에서 0.68%, 3 kV에서 0.82%, 4 kV에서 1.12%로 증가하였다. 그리고 교류전압을 약 4.3 kV 인가 중에 진단장비가 차단되었다.

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배전산업의 현대화 22.9kV-y 다중접지 배전방식의 도입

  • 황원서
    • 전기의세계
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    • v.46 no.7
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    • pp.25-27
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    • 1997
  • 우리나라 배전전압은 1917년 경성전기주식회사가 표준 배전전압으로 3.3kV를 채택한 이래 1960년대 중반까지는 3.3kV, 5.7kV-y, 6.6kV이었다. 1965년 10월, 경북 칠곡군 약목변전소 관내의 당시 박정희 대통령 생가 인근을 통과하는 22kV 비접지 송전선로 9km에 다중접지된 중성선을 추가시설, 3상 4선식 배전선로화하여 4개부락 40kV의 부하를 공급함으로써 우리나라에 22.9kV-y 중성선 다중접지 배전방식 도입의 효시가 된 이래, '22.9kV-y승압'사업은 1970년부터 1986년까지 한전의 배전분야 최우선사업으로 전국 방방곡곡에 걸쳐 시행되었다. 이제는 서울 일부와 제주도에서만 시행중으로 종료단계인 오늘에 이르기까지, '22.9kV-y승압'은 한전의 본사와 전국의 사업장에서 수많은 배전분야 종사자들이 총력을 기울여 이룩한 세계 전력 산업사에 그 유례가 드문 격상에 의한 배전전압 단일화 사업으로써, 배전사업 현대화의 중심사업이었다 하지 않을 수 없다.

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THE C-M DIAGRAM OF THE GLOBULAR CLUSTER, NGC 6752

  • Lee, See-Woo;Cannon, R.D.
    • Journal of The Korean Astronomical Society
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    • v.13 no.1
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    • pp.15-26
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    • 1980
  • The BV-photographic photometry was made for 1714 stars (V<19.5) in NGC 6752. The C-M diagram of this cluster shows an unusually extended blue horizontal branch $(V=13.5{\sim}17.8)$ with a wide gap $(V=16{\sim}16.7)$ and the well defined giant branch with gaps at V=13.85 and 16.2. The turnoff point is defined at $V=17.25{\pm}0.15$ and (B-V) = $0.46{\pm}0.02$. If we take $V_{HB}=13.85$ for NGC 6752, then ${\Delta}V=2.80,\;(B-V)_{0,g}=0.76\;and\;{\Delta}V_{TO}=3.40$ and the chemical abundance is estimated to be [Fe/H]=-1.67 or $Z=4.3{\times}10^{-4}\;and\;Y=0.26$. Some other physical parameters of this cluster are derived and compared with those for the well observed clusters M 3, M 13, M 15 and M 92.

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Prototype Implementation of Control Board for Vehicle V2X Communication Performance Evaluation (자동차 V2X 통신성능 평가를 위한 제어 보드 프로토타입 구현)

  • Yoowon Kim;Byeongchan Jo;Hyuk Jung
    • Journal of Auto-vehicle Safety Association
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    • v.15 no.2
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    • pp.28-34
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    • 2023
  • The Republic of Korea aims to complete the commercialisation of Level 4+ cooperative autonomous driving in 2027. It also plans to include V2X OBU in the K-NCAP evaluation items. Therefore, communication performance safety evaluation criteria for V2X OBU need to be established, and an OBU with necessary functions is needed to develop V2X communication performance safety evaluation technology for vehicles. In this study, we implemented a V2X OBU control board prototype that can be used to develop a V2X communication performance safety evaluation technology for Level 4+ autonomous vehicles, and confirmed that the control board prototype works normally.

Surface Characteristics of Porous Ti-6Al-4V Implants Fabricated by Electro-Discharge-Sintering in a Low Vacuum Atmosphere (저진공 분위기 전기방전소결에 의해 제조된 다공성 Ti-6Al-4V 임플란트의 표면특성 연구)

  • Hyun, C.Y.;Huh, J.K.;Lee, W.H.
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.178-182
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    • 2006
  • A single electro-discharge-sintering (EDS) pulse (1.0 kJ/0.7 g), from a $300{\mu}F$ capacitor, was applied to atomized spherical Ti-6Al-4V powder in a low vacuum to produce porous-surfaced implant compacts. A solid core surrounded by a porous layer was formed by a discharge in the middle of the compact. XPS (X-ray photoelectron spectroscopy) was used to study the surface characteristics of the implant material. C, O, and Ti were the main constituents, with smaller amounts of Al, V, and N. The implant surface was lightly oxidized and was primarily in the form of $TiO_2$ with a small amount of metallic Ti. A lightly etched EDS implant sample showed the surface form of metallic Ti, indicating that EDS breaks down the oxide film of the as-received Ti-6Al-4V powder during the discharge process. The EDS Ti-6Al-4V implant surface also contained small amounts of aluminum oxide in addition to $TiO_2$. However, V detected in the EDS Ti-6Al-4V implant surface, did not contribute to the formation of the oxide film..

Influence of Applied Voltage for Bioelectrochemical Anaerobic Digestion of Sewage Sludge (하수슬러지의 생물전기화학 혐기성소화에 대한 인가전압의 영향)

  • Kim, Dong-Hyun;Song, Young-Chae;Qing, Feng
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.9
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    • pp.542-549
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    • 2015
  • The bioelectrochemical anaerobic digestion for sewage sludge was attempted at different applied voltages ranged from 0.2 V to 0.4 V. At 0.3 V of the applied voltage, pH and VFAs were at 7.32 and 760 mg COD/L, respectively, which were quite stable. The methane production rate was $1.32L\;CH_4/L.d$, and the methane content in biogas was 73.8%, indicating that the performance of the bioelectrochemical anaerobic digestion could be considerably improved by applying a low voltage. At 0.4 V of the applied voltage, however, the contents of the minor VFA components including formic acid and propionic acid were increased. The methane production rate was reduced to $1.24L\;CH_4/L.d$ and the biogas methane content was also reduced to 72.4%. At 0.2 V of the applied voltage, the pH was decreased to 6.3, and VFAs was accumulated to 5,684 mg COD/L. The contents of propionic acid and butyric acid in the VFAs were considerably increased, The performances in terms of the methane production rate and the biogas methane content were deteriorated. The poor performance of the bioelectrochemical reactor at 0.2 V of the applied voltage was ascribed to the thermodynamic potential lack for the driving of the carbon dioxide reduction into methane at cathode.

Research on the penetration depth of low-energy electron beam in the PMMA-resist film using Monte Carlo numerical analysis (Monte Carlo 수치해석법을 이용한 PMMA resist에서의 저 에너지 전자빔 투과 깊이에 관한 연구)

  • Ahn, Seung-Joon;Ahn, Seong-Joon;Kim, Ho-Seob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.4
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    • pp.743-747
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    • 2007
  • There has been steady effect for the development of the electron-beam lithography technologies for the circuit patterning of the future semiconductor devices. In this study, we have performed a Monte-Carlo simulation whore $1{\times}10^4$ electrons with various kinetic energies (100eV, 300eV, 500eV, 700eV, and 1000eV) were shot into polymethyl methacrylate(PMMA) resist of 100-nm thickness. The penetration depth of each electron beam in the resist layer were analyzed using Gaussian analysis method.

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LIGHT CURVE ANALYSIS OF CONTACT BINARY SYSTEM V523 CASSIOPEIAE (접촉쌍성 V523 CAS의 광도곡선 분석)

  • 김진희;정장해
    • Journal of Astronomy and Space Sciences
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    • v.19 no.4
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    • pp.263-272
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    • 2002
  • A total of 616 observations (308 in B, 308 in V) to. V523 Cas was made on three nights from October 19 to 21 in 1999 using the 1.8m telescope with 2K CCD camera of the Bohyunsan Optical Astronomy Observatory of KAO. With our data we constructed the BV light curves and determined 4 times of minimum light. We also obtained physical parameters of the system by combined analysis of both light and radial velocity curves using the Wilson-Devinney code.

Effect of Annealing Treatment on Microstructure and Hydrogen Embrittlement of Ti-6Al-4V Alloys Subject to Electrochemical Hydrogen Charging (전기화학적 수소 주입에 의한 Ti-6Al-4V 합금의 미세조직과 수소 취성에 미치는 어닐링 처리의 영향)

  • Ko, S.W.;Lee, J.M.;Kwon, Y.N.;Hwang, B.
    • Transactions of Materials Processing
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    • v.29 no.4
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    • pp.211-217
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    • 2020
  • This paper presents a study on the hydrogen embrittlement of Ti-6Al-4V alloys with different microstructures depending on annealing treatment. They were electrochemically charged with hydrogen and subjected to tensile tests to investigate hydrogen embrittlement behavior. Tensile test results showed that the elongation of Ti-6Al-4V alloy specimens was remarkably decreased with increasing the volume fraction of β phase after hydrogen charging. This is because the β phase with a relatively low diffusivity tends to easily form a hydride at grain boundaries during electrochemical hydrogen charging. After hydrogen charging of the Ti-6Al-4V alloy specimen, it found that silver particles were decorated mostly at the grain boundary, and coarser silver particles were usually formed in the specimen annealed at 950 ℃. Therefore, the specimen having higher β phase fraction shows a poor hydrogen embrittlement resistance because the β phase promotes the formation of coarse hydride during electrochemical hydrogen charging, which leads to a large decrease in ductility.