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A Study on the Monolayer Film Electronics (단분자막 전자소자에 대한 연구)

  • Lee, Yong-Soo;Shin, Dong-Myung;Kim, Tae-Wan;Choi, Jong-Sun;Kang, Dou-Yol;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.3
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    • pp.249-254
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    • 1999
  • The N-docosyl N'-methyl viologen-$(TCNQ)_2$, (DMVT) was synthesized. We investigated the ${\pi}-A$ isotherm of DMVT to find the optimal deposition condition. Temperature-dependent current-voltage characteristics of the DMVT LB films shows that there is an increase in conductivity at 330K or so. The in-plane electrical conductivity at room temperature is in the range of $10^{-7}{\sim}10^{-6}S/cm$. From the plot of logarithmic conductivity as a function of reciprocal temperature, two types of activation energies, 0.04eV and 0.73eV, were obtained depending on the temperature range. The Ohmic behaviour was observed below 0.6V and the Schottky effect was confirmed at $2.5{\sim}6V$, when the I-V characteristics was measured with Al/LB film/Al structure. I-V measurement for Al/LB film/ITO structure showed the asymmetrical I-V relationship, which resulted from the rectification property.

THEORETICAL STUDY ON OBSERVED COLOR-MAGNITUDE DIAGRAMS

  • Lee, See-Woo
    • Journal of The Korean Astronomical Society
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    • v.12 no.1
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    • pp.41-70
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    • 1979
  • From $B\ddot{o}hm$-Vitense's atmospheric model calculations, the relations, [$T_e$, (B-V)] and [B.C, (B-V)] with respect to heavy element abundance were obtained. Using these relations and evolutionary model calculations of Rood, and Sweigart and Gross, analytic expressions for some physical parameters relating to the C-M diagrams of globular clusters were derived, and they were applied to 21 globular clusters with observed transition periods of RR Lyrae variables. More than 20 different parameters were examined for each globular cluster. The derived ranges of some basic parameters are as follows; $Y=0.21{\sim}0.33,\;Z=1.5{\times}10^{-4}{\sim}4.5{\times}10^{-3},\;age,\;t=9.5{\sim}19{\times}10^9$ years, mass for red giants, $m_{RG}=0.74m_{\odot}{\sim}0.91m_{\odot}$, mass for RR Lyrae stars, $m_{RR}=0.59m_{\odot}{\sim}0.75m_{\odot}$, the visual magnitude difference between the turnoff point and the horizontal branch (HB), ${\Delta}V_{to}=3.1{\sim}3.4(<{\Delta}V_{to}>=3.32)$, the color of the blue edge of RR Lyrae gap, $(B-V)_{BE}=0.17{\sim}0.21=(<(B-V)_{BE}>=0.18),\;[\frac{m}{L}]_{RR}=-1.7{\sim}-1.9$, mass difference of $m_{RR}$ relative to $m_{RG},(m_{RG}-m_{RR})/m_{RG}=0.0{\sim}0.39$. It was found that the ranges of derived parameters agree reasonably well with the observed ones and those estimated by others. Some important results obtained herein can be summarized as follows; (i) There are considerable variations in the initial helium abundance and in age of globular clusters. (ii) The radial gradient of heavy element abundance does exist for globular clusters as shown by Janes for field stars and open clusters. (iii) The helium abundance seems to have been increased with age by massive star evolution after a considerable amount (Y>0.2) of helium had been attained by the Big-Bang nucleosynthesis, but there is not seen a radial gradient of helium abundance. (iv) A considerable amount of heavy elements ($Z{\sim}10{-3}$) might have been formed in the inner halo ($r_{GC}$<10 kpc) from the earliest galactic co1lapse, and then the heavy element abundance has been slowly enriched towards the galactic center and disk, establishing the radial gradient of heavy element abundance. (v) The final galactic disk formation might have taken much longer by about a half of the galactic age than the halo formation, supporting a slow, inhomogeneous co1lapse model of Larson. (vi) Of the three principal parameters controlling the morphology of C-M diagrams, it was found that the first parameter is heavy clement abundance, the second age and the third helium abundance. (vii) The globular clusters can be divided into three different groups, AI, BI and CII according to Z, Y an d age as well as Dickens' HB types. BI group clusters of HB types 4 and 5 like M 3 and NGC 7006 are the oldest and have the lowest helium abundance of the three groups. And also they appear in the inner halo. On the other hand, the youngest AI clusters have the highest Z and Y, and appear in the innermost halo region and in the disk. (viii) From the result of the clean separations of the clusters into three groups, a three dimensional classification with three parameters, Z, Y and age is prsented. (ix) The anomalous C-M diagrams can be expalined in terms of the three principal parameters. That is, the anomaly of NGC 362 and NGC 7006 is accounted for by the smaller age of the order of $1{\sim}2{\times}10^9$ years rather than by the helium abundance difference, compared with M 3. (x) The difference in two Oosterhoff types I and II can be explained in terms of the mean mass difference of RR Lyrae variables rather than in terms of the helium abundance difference as suggested by Stobie. The mean mass of the variables in Oosterhoff type I clusters is smaller by $0.074m_{\odot}$ which is exactly consistent with Rood's estimate. Since it was found that the mean mass of RR Lyrae stars increases with decreasing Z, the two Oosterhoff types can be explained substantially by the metal abundance difference; the type II has Z<$3.4{\times}10^{-4}$, and the type I has higher Z than the type II.

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A Study on the E-TDLNN Method for the Behavioral Modeling of Power Amplifiers (전력 증폭기의 Behavioral 모델링을 위한 E-TDLNN 방식에 관한 연구)

  • Cho, Suk-Hui;Lee, Jong-Rak;Cho, Kyung-Rae;Seo, Tae-Hwan;Kim, Byung-Chul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.10
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    • pp.1157-1162
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    • 2007
  • In this paper, E-TDLNN(Expanded-Tapped Delay Line Neural Network) method is suggested to make the model of power amplifier effectively. This method is the one for making the model of power amplifier through the study in neural network to the target value, the measured output spectrum of power amplifier, after adding the external value factor, gate bias, as an invariant input to the TDLNN method which suggested the memory effect of power amplifier effectively. To prove the validity of suggested method, the data at 2 points, 3.45 V and 3.50 V of gate bias range $3.4{\sim}3.6V$ with the 0.01 V step change, are studied and the predicted results at the gate bias 3.40 V, 3.48 V, 3.53 V and 3.60 V shows good coincidence with the measured values.

Oxidation of Phenol Using Ozone-containing Microbubbles Formed by Electrostatic Spray (전기장에 의해 생성된 미세기포를 이용한 페놀의 오존산화)

  • Shin, Won-Tae;Jung, Yoo-Jin;Sung, Nak-Chang
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1292-1297
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    • 2005
  • The use of ozone in water and wastewater treatment systems has been known to be a process that is limited by mass transfer. The most effective way to overcome this limitation is to increase the interfacial area available for mass transfer by decreasing the size of the ozone gas bubbles that are dispersed in solution. Electrostatic spraying(ES) of ozone into water was investigated in this work as a method of increasing the rate of mass transfer of ozone into a solution and thereby increasing the rate of phenol oxidation. Results were obtained for ES at input power levels ranging from 0 to 4 kV and compared with two different pore-size bubble diffusers($10{\sim}15{\mu}m$ and $40{\sim}60{\mu}m$). It was determined that the rate of mass transfer could be increased by as much as 40% when the applied voltage was increased from 0 to 4 kV as a result of the smaller bubbles generated by ES. In addition, ES was shown to be more effective than the medium-pore-size($10{\sim}15{\mu}m$) bubble diffuser and the best results were achieved at low gas flow rates.

A study on the Properties of $In_{l-x}Ga_{x}As$ Grown by the TGS Methods (TGS법으로 성장한 $In_{l-x}Ga_{x}As$의 특성에 관한 연구)

  • Lee, W.S.;Moon, D.C.;Kim, S.T.;Suh, Y.S.
    • Proceedings of the KIEE Conference
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    • 1988.11a
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    • pp.372-375
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    • 1988
  • The III-V ternary alloy semiconductor $In_{l-x}Ga_{x}As$ were grown by the temperature Gradient of $0.60{\leq}x{\leq}0.98$. The electrical properties were investigated by the Hall effect measurement with the Van der Pauw method in the temperature range of $90{\sim}300K$. $In_{l-x}Ga_{x}As$ were revealed n-type and the carrier concentration at 300K were in the range of $9.69{\times}10^{16}cm^{-3}{\sim}7.49{\times}10^{17}cm^{-3}$. The resistivity was increased and the carrier mobility was decreased with increasing the composition ratio. The optical energy gap determined by optical transmission were $20{\sim}30meV$ lower than theoretical valves on the basis of absorption in the conduction band tail and it was decreased with increasing the temperature by the Varshni rule. In the photoluminescence of undoped $In_{l-x}Ga_{x}As$ at 20K, the main emission was revealed by the radiative recombination of shallow donor(Si) to acceptor(Zn) and the peak energy was increased with increasing the composition, X. The diffusion depth of Zn increases proportionally with the square root of diffusion time, and the activation energy for the Zn diffusion into $In_{0.10}Ga_{0.90}As$ was 2.174eV and temperatures dependence of diffusion coefficient was D = 87.29 exp(-2.174/$K_{B}T$). The Zn diffusion p-n $In_{x}Ga_{x}As$ diode revealed the good rectfying characteristics and the diode factor $\beta{\approx}2$. The electroluminescence spectrum for the Zn-diffusion p-n $In_{0.10}Ga_{0.90}As$ diode was due to radiative recombation between the selectron trap level(${\sim}140meV$) and Zn acceptor level(${\sim}30meV$). The peak energy and FWHM of electroluminescence spectrum at 77K were 1.262eV and 81.0meV, respectively.

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Study on Electrical Characteristics of Ideal Double-Gate Bulk FinFETs (이상적인 이중-게이트 벌크 FinFET의 전기적 특성고찰)

  • Choi, Byung-Kil;Han, Kyoung-Rok;Park, Ki-Heung;Kim, Young-Min;Lee, Jong-Ho
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.43 no.11 s.353
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    • pp.1-7
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    • 2006
  • 3-dimensional(3-D) simulations of ideal double-gate bulk FinFET were performed extensively and the electrical characteristics. were analyzed. In 3-D device simulation, we changed gate length($L_g$), height($H_g$), and channel doping concentration($N_b$) to see the behaviors of the threshold voltage($V_{th}$), DIBL(drain induced barrier lowering), and SS(subthreshold swing) with source/drain junction depth($X_{jSDE}$). When the $H_g$ is changed from 30 nm to 45nm, the variation gives a little change in $V_{th}$(less than 20 mV). The DIBL and SS were degraded rapidly as the $X_{jSDE}$ is deeper than $H_g$ at low fin body doping($1{\times}10^{16}cm^{-3}{\sim}1{\times}10^{17}cm^{-3}$). By adopting local doping at ${\sim}10nm$ under the $H_g$, the degradation could be suppressed significantly. The local doping also alleviated $V_{th}$ lowering by the shallower $X_{jSDE}\;than\;H_g$ at low fin body doping.

Antimicrobial Characteristics of Chitosan and Chitosan Oligosaccharides on the Microorganism related to Kimchi (키토산 및 키토산 올리고당의 김치 관련 미생물에 대한 항균 특성)

  • Kim, Myung-Hee;Oh, Se-Wook;Hong, Sang-Pill;Yoon, Suk-Kwon
    • Korean Journal of Food Science and Technology
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    • v.30 no.6
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    • pp.1439-1447
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    • 1998
  • Antimicrobial activity of chitosan and chitosan oligosaccharides on the microorganism related to Kimchi was investigated. 5 kinds of chitosan, which have different deacetylation degrees and molecular weights were prepared and its effect on the organoleptic characteristics, pH and titrable acidity of Kimchi in the storage time were examined. C-4 and C-5 chitosan (D.A.:$92{\sim}99%$, M.W.: $16,000{\sim}32,000)$ recorded high score in the texture and showed pH 4.9 and titrable acidity 0.35%, compared with control (pH 4.1, titrarable acidity 0.50 %) evaluated to optimal ripening time. The chitosan oligosaccharides containing relatively large amount of $pentamer{\sim}heptamer$ were chosen from C-4 chitosan hydrolyzates. Antimicrobial activity of C-4 and chitosan oligosaccharides against B. subtilis, B. cereus, Pse. fluorescens, E. coli, Lac. plantarum, Leu. mesenteroides, Lac. brevis, Ent. faecalis and 3 kinds of microflora from Kimchi were examined. The clear zone against microorganism were $9{\sim}20mm$ at 3.0% C-4 chitosan and $8{\sim}24mm$ at 5.0% chitosan oligosaccharides, and MIC of chitosan and chitosan oligosaccharides was shown $0.01{\sim}0.05%$ and $0.05{\sim}0.2%$, respectively. The antimicrobial effect of chitosan and chitosan oligosaccharides was also observed in 3 kinds of total microflora from Kimchi and was most strong in the microflora from the ripening stage of Kimchi, suggesting C-4 chitosan and chitosan oligosaccharides could be applicable to extending shelf-life of Kimchi.

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Design of a CMOS DC-to-DC Converter for Portable Devices (휴대용 기기를 위한 CMOS DC-DC 변환기 설계)

  • O, N.G.;Lee, J.K.;Cho, I.H.;Jang, S.H.;Cha, C.H.;Yu, C.G.
    • Proceedings of the KIEE Conference
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    • 2008.10b
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    • pp.520-521
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    • 2008
  • This paper describes a low voltage, low-power CMOS buck DC/DC converter, which has a simple common-gate current sensing circuit. It consumes low power because it includes less transistors than other converters which use operational amplifiers for current sensing. The designed DC-DC converter is fabricated in a 0.18um CMOS technology. A maximum efficiency of 88% has been obtained with the proposed circuit. It has $2V{\sim}3.7V$ input voltage range, $1V{\sim}2.5V$ output voltage range and maximum output current of 1000mA.

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Unexpected Rate Retardation in the Formation of Phthalic Anhydride from N-Methylphthalamic Acid in Acidic H2O-CH3CN Medium

  • Ariffin, Azhar;Khan, M. Niyaz
    • Bulletin of the Korean Chemical Society
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    • v.26 no.7
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    • pp.1037-1043
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    • 2005
  • Kinetic study on the cleavage of N-methylphthalamic acid (NMPA) in mixed acidic aqueous-acetonitrile solvent reveals the formation of both phthalic anhydride (PAn) (through O-cyclization) and N-methylphthalimide (NMPT) (through N-cyclization). The formation of NMPT varies from $\sim$20% to $\sim$3% with the increase in the content of acetonitrile from 2 to 70% v/v. Pseudo first-order rate constants for the formation of PAn are more than 4-fold larger than those for the formation of NMPT at 2% v/v $CH_3CN$ in mixed aqueous solvents. Pseudo first-order rate constants for alkaline hydrolysis of NMPT reveal a nonlinear decrease with increase in the content of $CH_3CN$ in mixed aqueous solvents.