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Heterogeneously Catalyzed Oxidations of Cyclopentene and of 1-Pentene (시클로펜텐과 1-펜텐의 불균일 촉매 산화반응)

  • Yang, Hyun S.;Kim, Young H.
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.888-901
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    • 1996
  • Oxidations of cyclopentene and of 1-pentene with air have been studied on a V/Mo/P/Al/Ti-mixed oxide catalyst in a fixed bed integral reactor. At high levels of conversion maleic anhydride was in each case produced as the major organic product, along with minor amounts of phthalic anhydride and, only starting from 1-pentene, also of citraconic anhydride. At lower levels of conversion a total of 30 organic products have been identified, some of which may be intermediates on the way from the substrates to the three anhydrides mentioned above. Based on the dependence of selectivities of the organic products on conversion, reaction schemes for the formation of maleic anhydride, phthalic anhydride and citraconic anhydride have been proposed. Oxidation at $310^{\circ}C$ led to increasing conversions and selectivities for maleic anhydride with decreasing space velocities. The highest selectivities for maleic anhydride were obtained at conversion of ca. 100%. Oxidation at a constant space velocity of $2{\cdot}10^4h^{-1}$ led to increasing conversions with increasing temperatures in the range of $300^{\circ}C{\sim}420^{\circ}C$, while the selectivity for maleic anhydride passed through a maximum value of ca. 39% at $370^{\circ}C$ in the oxidation of cyclopentene and a maximum value of ca. 30% at $400^{\circ}C$ in the oxidation of 1-pentene.

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Study of Catalytic Filter on the Removal of Dust and HVOC (촉매필터를 이용한 먼지 및 HVOC 제거 특성 연구)

  • Jeong, Soon Kwan;Park, Young Ok
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.80-85
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    • 2008
  • Catalytic filter is capable of performing shallow bed dust filtration plus a catalytic reaction, promoted by a catalyst deposited in its inner structure. Such a feature may allow potential cost and space reduction in several environmental applications. Dust filtration and halogenated volatile organic compound (1,2-dichlorobenzene) destruction were carried out in a lab-scale reactor. $WO_3-V_2O_5/TiO_2$ supplied by MaGreen, which showed high catalytic acitivity at low temperature, was used as a catalyst. P-84 that can be operated under $250^{\circ}C$ was used as a felt. The catalytic activity and filtration efficiency of catalytic filters were investigated under the operating conditions, including temperature, face velocity, and dust concentration. The catalytic activity of catalytic filter increased with increasing temperature and the amount of catalyst loaded. The test results showed that the filtration efficiency was primarily affected by the face velocity. Pressure drop variations as a function of time were investigated for a variety of conditions. In case of virgin filter, a dramatic decrease in the pulse interval and a slightly increase in the base line pressure drop were observed. A relatively slow pressure drop build-up was recorded for the catalytic filter due to smooth and slippery surface characteristics of nanofiber. The catalytic filter indicated that high filtration efficiency over 99.98% and high catalytic activity over 90% at 1 m/min and $210^{\circ}C$.

Gamma Ray Detection Processing in PET/CT scanner (PET/CT 장치의 감마선 검출과정)

  • Park, Soung-Ock;Ahn, Sung-Min
    • Journal of radiological science and technology
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    • v.29 no.3
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    • pp.125-132
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    • 2006
  • The PET/CT scanner is an evolution in image technology. The two modalities are complementary with CT and PET images. The PET scan images are well known as low resolution anatomic landmak, but such problems may help with interpretation detailed anatomic framework such as that provided by CT scan. PET/CT offers some advantages-improved lesion localization and identification, more accurate tumor staging. etc. Conventional PET employs tranmission scan require around 4 min./bed position and 30 min. for whole body scan. But PET/CT scanner can reduced by 50% in whole body scan. Especially nowadays PET scanner LSO scintillator-based from BGO without septa and operate in 3-D acquisition mode with multidetectors CT. PET/CT scanner fusion problems solved through hardware rather than software. Such device provides with the capability to acquire accurately aligned anatomic and functional images from single scan. It is very important to effective detection from gamma ray source in PETdetector. And can be offer high quality diagnostic images. So we have study about detection processing of PET detector and high quality imaging process.

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Effect of Plug Cell Volume and Medium Composition on Rooting and Growth of Lateral Shoot Cuttings of Tomato Plant (플러그 셀의 크기와 배지(培地) 조성이 토마토 삽목묘(揷木苗)의 발근(發根)과 생육(生育)에 미치는 영향(影響))

  • Yang, Seung-Koo;Cho, Myeong-Su;Choe, Kyeong-Ju;Kim, Wol-Soo
    • Horticultural Science & Technology
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    • v.19 no.3
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    • pp.325-328
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    • 2001
  • This experiment was conducted to investigate the effect of plug cell volume and medium on rooting and growth of lateral shoot cuttings of a few tomato cultivars. Plug cell volume was varied from 23 to 300 mL or control (cutting bed) and media used were carbonized rice hull (CRH), CRH+perlite, CRH+peatmoss and perlite+peatmoss. Nursery plants were able to be transplanted in 15 to 20 days after lateral shoots cutting in tomato. In volume of cutting media, the pots of 23 to 300 mL were proper, although root growth was gradually limited in decreased media volume. Rooting and growth was not influenced by plug tray cell medium of 120 mL or more. Cherry tomato Pepe (c.v.) showed 100% rooting and better growth, while in Momotaro (c.v.) rooting was 90%. There were 100% rooting and no considerable changes grown in all media tested of cutting plug tray volume of 30 mL.

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Strategy Prospects of Environmental Restoration of Stream Side in Japan(V) -With a Special Reference to the Application of Korean Style- (일본(日本)에서 계류변(溪流邊)의 환경복원(環境復元) 발전전략(發展戰略)(V) -한국적(韓國的) 적용(適用)을 중심(中心)으로-)

  • Park, Jae-Hyeon;Woo, Bo-Myeong;Kwon, Tae-Ho;Lee, Heon-Ho
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.4 no.1
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    • pp.80-89
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    • 2001
  • The objective of this study was to introduce the current status and development strategy for the environmental restoration of stream side in Japan, and to consider the methodology which could be effectively applied to the environmental restoration of stream side in Korea. 1. We should establish a new paradigm of forest conservation and erosion control which can emphasize the restoration of the stream side ecosystem and reduce soil movement in the areas. Also, in the past, the objective of forest conservation and erosion control was to fix soil by constructing permanent structures. The direction of future forest conservation and erosion control needs to be new forest conservation and erosion control technology to prevent large scale soil movement but allow small scale soil movement to conserve sound ecosystem and biotic habitats. 2. In the past, the goal of forest conservation and erosion control planning was to fix the amount of soil movement by constructing permanent facilities. Forest conservation and erosion control planning in the future needs to change the techniques which could prevent soil movement from large scale of soil disasters, but allow soil movement effectively to a small and middle scale's soil movement. Also, it is considered to change erosion control dams from non passing type to passing type. 3. In the point of ecological conservation aspects, we should evaluate the effects of new forest conservation and erosion control methods which are emphasized on the restoration of the stream side ecosystem. Also, forest conservation and erosion control construction projects for restoring stream and river ecosystem should be planned for perfectly restorating their ecosystems by the way of sustainable maintenance and management. 4. The restoration direction of stream and river ecosystems needs to be restoring the diversity of small geographies such as waterway, shoal and puddles rather than flattening stream bed. And the restoration of the stream side ecosystem should provide continuity of the stream side environment which allows desirable biological habitats, and environmentally sound facilities to harmonize with the environment.

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Feasibility Study of Deep Inspiration Breath-Hold Based Volumetric Modulated Arc Therapy for Locally Advanced Left Sided Breast Cancer Patients

  • Swamy, Shanmugam Thirumalai;Radha, Chandrasekaran Anu;Kathirvel, Murugesan;Arun, Gandhi;Subramanian, Shanmuga
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.20
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    • pp.9033-9038
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    • 2014
  • Background: The purpose of this study was to assess the feasibility of deep inspiration breath-hold (DIBH) based volumetric modulated arc therapy (VMAT) for locally advanced left sided breast cancer patients undergoing radical mastectomy. DIBH immobilizes the tumor bed providing dosimetric benefits over free breathing (FB). Materials and Methods: Ten left sided post mastectomy patients were immobilized in a supine position with both the arms lifted above the head on a hemi-body vaclock. Two thermoplastic masks were prepared for each patient, one for normal free breathing and a second made with breath-hold to maintain reproducibility. DIBH CT scans were performed in the prospective mode of the Varian real time position management (RPM) system. The planning target volume (PTV) included the left chest wall and supraclavicular nodes and PTV prescription dose was 5000cGy in 25 fractions. DIBH-3DCRT planning was performed with the single iso-centre technique using a 6MV photon beam and the field-in-field technique. VMAT plans for FB and DIBH contained two partial arcs ($179^{\circ}-300^{\circ}CCW/CW$). Dose volume histograms of PTV and OAR's were analyzed for DIBH-VMAT, FB-VMAT and DIBH-3DCRT. In DIBH mode daily orthogonal ($0^{\circ}$ and $90^{\circ}$) KV images were taken to determine the setup variability and weekly twice CBCT to verify gating threshold level reproducibility. Results: DIBH-VMAT reduced the lung and heart dose compared to FB-VMAT, while maintaining similar PTV coverage. The mean heart $V_{30Gy}$ was $2.3%{\pm}2.7$, $5.1%{\pm}3.2$ and $3.3%{\pm}7.2$ and for left lung $V_{20Gy}$ was $18.57%{\pm}2.9$, $21.7%{\pm}3.9$ and $23.5%{\pm}5.1$ for DIBH-VMAT, FB-VMAT and DIBH-3DCRT respectively. Conclusions: DIBH-VMAT significantly reduced the heart and lung dose for left side chest wall patients compared to FB-VMAT. PTV conformity index, homogeneity index, ipsilateral lung dose and heart dose were better for DIBH-VMAT compared to DIBH-3DCRT. However, contralateral lung and breast volumes exposed to low doses were increased with DIBH-VMAT.

Assessing the Positioning Accuracy of High density Point Clouds produced from Rotary Wing Quadrocopter Unmanned Aerial System based Imagery (회전익 UAS 영상기반 고밀도 측점자료의 위치 정확도 평가)

  • Lee, Yong Chang
    • Journal of Korean Society for Geospatial Information Science
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    • v.23 no.2
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    • pp.39-48
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    • 2015
  • Lately, Unmanned Aerial Vehicles(UAV), Unmanned Aerial Systems(UAS) or also often known as drones, as a data acquisition platform and as a measurement instrument are becoming attractive for many photogrammetric surveying applications, especially generation of the high density point clouds(HDPC). This paper presents the performance evaluation of a low-cost rotary wing quadrocopter UAS for generation of the HDPC in a test bed environment. Its performance was assessed by comparing the coordinates of UAS based HDPC to the results of Network RTK GNSS surveying with 62 ground check points. The results indicate that the position RMSE of the check points are ${\sigma}_H={\pm}0.102m$ in Horizonatal plane, and ${\sigma}_V={\pm}0.209m$ in vertical, and the maxium deviation of Elevation was 0.570m within block area of ortho-photo mosaic. Therefore the required level of accuracy at NGII for production of ortho-images mosaic at a scale of 1:1000 was reached, UAS based imagery was found to make use of it to update scale 1:1000 map. And also, since this results are less than or equal to the required level in working rule agreement for airborne laser scanning surveying of NGII for Digital Elevation Model generation of grids $1m{\times}1m$ and 1:1000 scale, could be applied with production of topographic map and ortho-image mosaic at a scale of 1:1000~1:2500 over small-scale areas.

Odorous Gas Removal in Biofilter with Powdered Activated Carbon and Zeolite Coated Polyurethane Foam (분말활성탄 및 제올라이트 담지 폴리우레탄 담체를 이용한 바이오필터에서의 악취가스 제거)

  • Lee, Soo-Chul;Kim, Dong-Jin
    • Clean Technology
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    • v.18 no.2
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    • pp.209-215
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    • 2012
  • The performance and removal efficiencies of a pilot scale biofilter were estimated by using ammonia and hydrogen sulfide as the odorous gases. Expanded polyurethane foam coated with powdered activated carbon and zeolite was used as a biofilm supporting medium in the biofilter. Odorous gases from the sludge thickener of a municipal wastewater treatment plant were treated in the biofilter for 10 months and the inlet ammonia and hydrogen sulfide concentrations were 0.1-1.5 and 2-20 ppmv, respectively. The removal efficiencies reached about 100% at the empty bed retention time (EBRT) of 3.6-5 seconds except for the adaptation periods. The pressure drop of the biofilter caused by the gas flow was also low that the maximum attained was 31 mm $H_2O$ during the operation. Its stability was confirmed in the long term due to the fact that the biofilter and the polyurethane medium had a minimum plugging and compression. The microbial community on the medium is critical for the performance of the biofilter especially the distribution of ammonia oxidizing bacteria (AOB) and sulfur oxidizing bacteria (SOB). The distribution of Nitrosomonas sp. (AOB) and Thiobacillus ferroxidans (SOB) was confirmed by FISH (fluorescence in situ hybridization) analysis. The longer the operation time, the more microbial population observed. Also, the medium close to the gas inlet had more microbial population than the medium at the gas outlet of the biofilter.

A Study on the Risk Assessment of River Crossing Pipeline in Urban Area (도심지 하천매설배관의 위험성 평가에 관한 연구)

  • Park, Woo-Il;Yoo, Chul-Hee;Shin, Dong-Il;Kim, Tae-Ok;Lee, Hyo-Ryeol
    • Journal of the Korean Institute of Gas
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    • v.24 no.2
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    • pp.22-28
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    • 2020
  • In this study, quantitative risk assessment was carried out for city gas high-pressure pipelines crossing through urban rivers. The risk assessment was performed based on actual city gas properties, traffic volume and population and weather data in the worst case scenario conditions. The results confirmed that the social and individual risks were located in conditionally acceptable areas. This can be judged to be safer considering that the risk mitigation effect of protecting the pipes or installing them in the protective structure at the time of the construction of the river buried pipe is not reflected in the result of the risk assessment. Also, SAFETI v8.22 was used to analyze the effects of wind speed and pasquil stability on the accident damage and dispersion distances caused by radiation. As a result of the risk assessment, the safety of the pipelines has been secured to date, but suggests ways to improve safety by preventing unexpected accidents including river bed changes through periodic inspections and monitoring.

Geochemical Characteristics of Stream Sediments Based on Bed Rocks in the Naju Area, Korea (기반암에 따른 나주지역 하상퇴적물의 지구화학적 특성)

  • Park, Young-Seog;Kim, Jong-Kyun;Jung, Young-Hwa
    • Journal of the Korean earth science society
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    • v.27 no.1
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    • pp.49-60
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    • 2006
  • The purpose of this study is to investigate geochemical characteristics for stream sediments in the Naju area. We collected 139 stream sediments samples from primary channels. Samples were dried slowly in the laboratory and chemical analysis was carried out using XRF. ICP-AES and NAA. In order to investigate geochemical characteristics, the geological groups categorized into granitic gneiss area, schist area, granite area, arenaceous rock area, tuff area, andesite area, and rhyolite area. Average contents of major elements for geological groups are $SiO_2\;58.37{\sim}66.06wt.%,\;Al_2O_3\;13.98{\sim}18.41wt.%,\;Fe_2O_3\;4.09{\sim}6.10wt.%,\;CaO\;0.54{\sim}1.33wt.%,\;MgO\;0.86{\sim}1.34wt.%,\;K_2O\;2.38{\sim}4.01wt.%,\;Na_2O\;0.90{\sim}1.32wt.%,\;TiO_2\;0.82{\sim}1.03wt.%,\;MnO\;0.09{\sim}0.15wt.%,\;P_2O_5\;0.11{\sim}0.18wt.%$. According to the comparison of average contents of major elements, $Al_2O_3\;and\;K_2O$ are higher in granitic gneiss area, $Fe_2O_3,\;CaO,\;P_2O_5$ are higher in tuff area, MgO and $TiO_2$ are higher in andesite area, $Na_2O_$ is higher in rhyolite area, $SiO_2$, and MnO are higher in arenaceous rock area. Average contents of minor and rare earth elements for geological groups are $Ba\;1278{\sim}1469ppm,\;Be\;1.1{\sim}1.5ppm,\;Cu\;18{\sim}25ppm,\;Nb\;25{\sim}37ppm,\;Ni\;16{\sim}25ppm,\;Pb\;21{\sim}28ppm,\;Sr\;83{\sim}155ppm,\;V\;64{\sim}98ppm,\;Zr\;83{\sim}146ppm,\;Li\;32{\sim}45ppm,\;Co\;7.2{\sim}12.7ppm,\;Cr\;37{\sim}76ppm,\;Cs\;4.8{\sim}9.1ppm,\;Hf\;7.5{\sim}25ppm,\;Rb\;88{\sim}178ppm,\;Sc\;7.7{\sim}12.6ppm,\;Zn\;83{\sim}143ppm,\;Pa\;11.3{\sim}37ppm,\;Ce\;69{\sim}206ppm,\;Eu\;1.1{\sim}1.5ppm,\;Yb\;1.8{\sim}4.4ppm$. According to the comparison of average contents of minor and rare earth elements for geological groups, Pb, Li, Cs, Hf, Rb, Sb, Pa, Ce, Eu, and Yb are higher in granitic gneiss area; Ba, Co, and Cr in schist area; Nb, Ni, and Zr in arenaceous rock area; Sr in tuff area: and Be, Cu, V, Sc, and Zn are such in andesite area.