• 제목/요약/키워드: Urethane rubber

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수용성 고무 아스팔트계 도막방수재의 실외 적용을 위한 기본 물성 연구 (A Study on the Basic Physical Properties of Water-Soluble Rubber Asphalt-based Coating Waterproofing for Exterior Application)

  • 강효진;윤성환;오상근
    • 한국건설순환자원학회논문집
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    • 제8권4호
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    • pp.553-561
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    • 2020
  • 국내 건축 구조물 방수재료 중 하나인 수용성 고무 아스팔트계 도막 방수재는 주로 실내(화장실, 주방, 배란다 등)에 많이 사용되고 있다. 일반적으로 아스팔트계열의 재료는 검은색의 기본 채도를 벗어나지 못하여 노출용보다는 비노출용으로 많이 쓰이고 있으며, 수용성 고무 아스팔트계 도막방수재의 경우는 기본적으로 낮은 물성 때문에 실내로 한정하여 적용하고 있다. 이에 인장 및 신장성 향상을 위하여 실란커플링제와 무기필러, 프로세서 오일 넣어 물성을 향상시켰고, 이에 따라 실외 도막방 수재 품질기준과의 기초 물성을 분석하였다. 그 결과 노출용 품질기준과 비교한 수용성 고무 아스팔트 도막방수재는 시험 평가가 진행된 전 항목에서 실리콘 고무계의 기본 물성 품질기준을 상회하는 결과가 나타났으나, 우레탄 고무계 1류의 인장강도 및 인열강도 클로로프렌 고무계 인열강도 품질기준 대비 성능이 약 34.2%에서 약 40.8% 정도 부족한 것으로 나타났다.

FCEV용 고압 밸브 실링부의 고무재질에 따른 기밀해석 (Sealing analysis of sealing rings with respect to rubber material properties for high pressure valve of FCEV)

  • 박근영;양갑진;노의동;박준수;전문수;이형욱
    • 융복합기술연구소 논문집
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    • 제7권2호
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    • pp.13-16
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    • 2017
  • The design of sealing mechanisms of a manual pressure valve was analyzed with FE analysis for a hydrogen fuels charge and discharge system of FCEV. The damage prediction of the O-ring with respect to the material models of rubbers was calculated by the gap analysis of the backup ring and O-ring according to the internal pressure. Two kinds of the rubber material characteristic models were adopted to the O-ring. One was the linear elastic and the other was hyperelastic of Ogden $3^{rd}$ order model. The experimental data of urethane of Shore hardness 90 was utilized to the curve fitting of hyperelastic properties. It was found that the contact pattern of the backup ring was different in two models and the sealing mechanism was better in the case of the hyperelastic characteristic model.

원통 봉을 적용한 압전 캔틸레버의 성능 향상 (Improved Power Output by a Piezoelectric Cantilever after Addition of a Cylindrical Bar)

  • 이영진;김세기;김영득
    • 한국세라믹학회지
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    • 제51권5호
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    • pp.516-521
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    • 2014
  • This paper describes the development of a new piezoelectric unimorph cantilever structure intended to improve electrical output power, compared to a conventional cantilever. The proposed structure employs a cylindrical bar attached to one side of a steel plate, which is a significant factor in forced vibration mode. The feasibility of the proposed methodology was assessed experimentally and theoretically. The influence of three different types of bar material (i.e., stainless steel, silicon rubber, and urethane), and bar position, on the output voltage were examined and compared with those without the bar. The optimal position and material for the bar were identified through experimental and theoretical analyses. It appears that the electrical output power of the proposed cantilever is about 40% higher than that of a conventional unimorph cantilever.

완충재 종류에 따른 중량바닥충격음 저감특성 평가 (A Study on the Heavy-weight Floor Impact Sound Reduction Evaluation of Characteristics by Resilient Materials)

  • 김경우;양관섭;정진연;임정빈;정갑철
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2007년도 추계학술대회논문집
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    • pp.1145-1148
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    • 2007
  • Resilient materials are generally used for the floating floors to reduce the floor impact sound. Dynamic stiffness of resilient material, which has the most to do with the floor impact sound reduction. The resilient materials available in Korea include EPS (Styrofoam), recycled urethane types, EVA (Ethylene Vinylacetate) foam rubber, foam PE (Polyethylene), glass fiber & rock wool, recycled tire, foam polypropylene, compressed polyester, and other synthetic materials. In this study, we tested floor impact sound reduction characteristic to a lot of kinds of resilient material. The result of test showed that the amount of the heavy-weight impact sound reduction appeared by being influenced from this dynamic stiffness of resilient material. The dynamic stiffness looked like between other resilient materials, a similar to the amount of the heavy-weight impact sound reduction was shown.

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조절방출성 약제를 위한 소프트 하이드로겔 소재의 개발

  • 이승진;구영순
    • 한국응용약물학회:학술대회논문집
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    • 한국응용약물학회 1994년도 춘계학술대회 and 제3회 신약개발 연구발표회
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    • pp.196-196
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    • 1994
  • DDS에 활용될 수 있는 고분자 소재를 개발할 목적으로 물성 및 응용성이 우수한 고분자 겔에 관한 연구를 수행하였다. Ethylene oxide,propylene oxide 각각의 copolymer인 poloxamer등의 prepolymer들을 triisocyanate로 가교시키고 diisocyanate 로 chain이 연장된 "soft hydrogel"을 제조하였다. 모델 약물을 선정하여 crosslinker와 extender의 조절에 따른 hydrogel의 약물 방출 조절능을 조사하였으며 그 기전을 규명하고자 하였다. 가교부위에 urethane bond를 함유한 soft hydtogel은 건조상태에서도 고무와 같은 전연성을 보여 일반적인 hydrogel과 대비되는 특성을 보였으며 이에 따른 다양한 활용성이 기대되었다. Extender및 crosslinker의 비율에 따라서 이 rubber elasticity가 조절되었다. 가교도가 감소할수록 팽윤도가 상승하였고 이에 따른 약물방출도 증가함을 확인하였다. 또한 Prepolymer의 분자량 및 친수/소수성등의 물성에 따라 약물방출을 조절할 수 있었다. 제조된 hydrogel에 조절방출시 필요한 기능을 부가시키고자 poly(carylic acid)류와 IPN 공중합체를 합성하여 물성을 조사하였고 비이온성/양이온성/음이온성 모델약물을 선정하여 pH에 따른 가변적 팽윤도와 이온성 상호작용등에 근거한 약물 조절방출기전을 조사하였다.기전을 조사하였다.

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완충재 종류에 따른 경량바닥충격음 저감특성 평가 (Evaluation of the Light-weight Floor Impact Sound Reduction Characteristics by Types of Resilient Material)

  • 김경우;양관섭;정진연;임정빈;정갑철
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2008년도 춘계학술대회논문집
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    • pp.830-834
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    • 2008
  • Resilient materials are generally used for the floating floors to reduce the floor impact sound. Dynamic stiffness of resilient material, which has the most to do with the floor impact sound reduction. The resilient materials available in Korea include EPS (Styrofoam), recycled urethane types, EVA (Ethylene Vinylacetate) foam rubber, foam PE (Polyethylene), glass fiber & rock wool, recycled tire, foam polypropylene, compressed polyester, and other synthetic materials. In this study, we tested floor impact sound reduction characteristic to a lot of kinds of resilient material. The result of test showed that the amount of the Light-weight impact sound reduction appeared by being influenced from this dynamic stiffness of resilient material. As the decreasing dynamic stiffness of resilient material, the impact sound reduction amount is increased, especially in the low frequency domain.

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Thermal Decomposition Kinetics of Polyurethane Elastomers Prepared with Different Dianiline Chain Extenders

  • Ahn, WonSool
    • Elastomers and Composites
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    • 제51권2호
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    • pp.122-127
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    • 2016
  • Thermal decomposition kinetics for two different types of polyurethane elastomers prepared with 2,2'-dichloro-4,4'-methylenedianiline (MOCA) and 3,5-dimethyl-thiotoluenediamine (Ethacure-300), based on PTMG/TDI isocyanate prepolymer, were studied using non-isothermal thermogravimetric analysis (TGA). Thermograms were obtained and analyzed using Friedman (FR) and Kissinger-Akahira-Sunose (KAS) methods for activation energy, $E_a$. The results obtained showed that decomposition reaction of both samples was observed similarly to occur through three different stages, i.e., initial stage with vaporization of low molecular weight materials, second stage of urethane linkage decompositions, and later stage of polyol segment decompositions. However, activation energy values at each stage for the sample cured with Ethacure-300 was much lower than those for the sample with MOCA, exhibiting relatively lower thermal stability for the sample with Ethacure-300 than that with MOCA.

Effects of Amine Catalysts on Structure of Polyurethane Foams

  • Furukawa, Mutsuhisa;Takamatsu, Katsuhiro
    • Elastomers and Composites
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    • 제34권4호
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    • pp.285-291
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    • 1999
  • Effects of catalysts on network structure, hard segment length and distribution of polyurethane foams in the absence of catalysts were investigated. CFC free all MDI-based poly urethane foams were prepared from poly(ethylene adipate)glycol, 4,4'-diphenylmethane diisocyanate, and water. Amino catalysts used were 1,4-diazabicyclo[2,2,2]octane(DABCO), N, N,N',N'-tetramethyl--hexane-1,6-diamine(MR), bis(2-methylamino ethyl)ether(ET), 1,8-diazabicyclo-[5,4,0]-undecene-7(DBU). Dibutyltindilaurate(DBTL) as control was also used. Hard segment components of polyurethane foams were obtained by a selective degradation of polyester chains with 0.01N KOH-methanol solution. The PUFs with DBU catalyst contained more amount of isocyanurate components than other PUFs. On the other hand, the PUFs with ET, MR, DBTL catalysts contained more amount of allophanate and biuret component than the other PUFs.

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바닥충격음 방지재의 재료강성 효과 (Effect of the Stiffness on the Performance of Impact Noise Isolation Pads of a Floor)

  • 이동훈;황윤;강문;김민배
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2000년도 추계학술대회논문집
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    • pp.425-430
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    • 2000
  • This paper describes the effect of the pad stiffness on the noise reduction of impact noise isolation pads of a floor. And also a new semi-experimental method for measuring the impact noise isolation capability of a pad is introduced. The impact noise isolation pads made of wire-mesh, urethane-chip and foam rubber are used for measuring the stiffness, the vibrational insulation performance and the impact noise isolation capability. The correlation between the stiffness and impact noise isolation capability of pads is theoretically reviewed, and confirmed from the experimental results. For measuring the impact noise isolation capability of only an isolation pad, a semi-experimental method proposed in this study is more effective than the reverberation room method.

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Application of High Performance Coatings for Service Life Extension of Steel Bridge Coatings

  • Lee, Chan-Young
    • Corrosion Science and Technology
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    • 제20권4호
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    • pp.169-174
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    • 2021
  • In this study, performance tests, a field evaluation, and a life cycle cost (LCC) analysis for high performance coating systems were conducted to prepare a plan to reduce the cost of maintenance coating and contribute to the service life extension of steel bridges by applying high performance coatings to steel bridges that will be constructed in the future. From the deterioration models based on the field evaluation for chlorinated rubber and urethane topcoat systems, which have been applied often, the mean service lives were derived as 20.8 and 26.6 years, respectively. For the other coating systems that have not been applied in practice, the coordination factors were differentially applied with evaluation items. The most durable coating system was predicted to be thermal spray coating (TSC) primer/epoxy intermediate coat/fluoride resin topcoat, with a predicted value as long as 42.2 years. The LCC analysis indicates that partial application of high performance coating, such as TSC and fluoride resin, to specific parts vulnerable to corrosion and ultraviolet ray (UV) is more advantageous than the use of general coating systems.