• Title/Summary/Keyword: Uranium contamination

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U-phosphate biomineralization induced by Bacillus sp. dw-2 in the presence of organic acids

  • Tu, Hong;Yuan, Guoyuan;Zhao, Changsong;Liu, Jun;Li, Feize;Yang, Jijun;Liao, Jiali;Yang, Yuanyou;Liu, Ning
    • Nuclear Engineering and Technology
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    • v.51 no.5
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    • pp.1322-1332
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    • 2019
  • In this paper, we systematically investigated the influence of some selected ligands on the U-phosphate precipitation induced by soil bacteria. These organics are widely ranging from acetate, lactate, salicylate and citrate to oxalate. The results revealed that uranium could be biomineralized on bacteria as $UO_2HPO_4{\cdot}4H_2O$ or $(UO_2)_3(PO_4)_2{\cdot}4H_2O$. The influence of organic ligands on the biomineralization had clear-cut correlations with its complexation abilities to uranyl. It was clearly found that the U-phosphate biomineralization was affected noticeably by the strong ligands (oxalate and citrate). Further study discovered that when the organic ligands were uncompetitive with biotic $PO_4^{3-}$ for uranyl, the transformation of uranyl species from ${\beta}-UO_2(OH)_2$ colloidal particles to free $UO_2^{2+}$-ligands ions could facilitate the U-phosphate biomineralization. However, when the organic ligands competed with biotic $PO_4^{3-}$ for uranyl, the U-phosphate biomineralization were inhibited. Our results highlight the importance of complex interactions of strong organic ligands with uranyl during the bacterial precipitation of U-P compounds and thus for the mobilization and immobilization of radio-nuclides in the nature.

Assessment of a U Product purity from Pyroprocessing Spent EBR-II Fuel (EBR-II 사용후핵연료의 건식처리공정에 의한 우라늄의 순도 평가)

  • Lee, Jung-Won;Lee, Han-Soo;Kim, Eung-Ho;Lee, Jong-Hyeon;Vaden, D.;Westphal, B.;Simpson, M.F.
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.3
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    • pp.167-174
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    • 2009
  • A comprehensive analysis has been conducted on the purity of the uranium product generated from a pyroprocessing of EBR-II spent fuel. The analysis results were compared to the low-level waste criteria for both ROK and USA under a collaborative program between INL and KAERI. It is found that the US LLW definition does not include the activity from any U isotopes, but the Korean one does. The analysis results show that Pu-239 is the only alpha emitting isotope other than U isotopes that exceed the limit in the EBR-II U product. Pu contamination of the product seems to be drastically reduced in a preliminary test of the modified cathode process, and the further development of the proposed technology may be possible to meet the US LLW criteria.

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Study on Concentration Variation of 222Rn for Various Scintillators Using Low-Level Liquid Scintillation Counter (저 준위 액체섬광계수기를 이용한 섬광체 종류에 따른 222Rn 농도 변화 연구)

  • Jeon, JaeWan;Lee, Deuk-Hee;Kim, Jin-Seop
    • Journal of the Korean Society of Radiology
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    • v.13 no.6
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    • pp.847-856
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    • 2019
  • The various environmental issues arose with the development of today's economy. naturally, people were increased interest in environment and the importance of research on drinking water and contamination are emerging especially. A number of country areas, uranium and 222Rn in ground water have been detected to people using as drinking water. So this study evaluated the way for more accurate measurements than when measuring 222Rn concentrations in the ground water containing. the experiment was performed using the low-level liquid scintillation counter with an alpha, beta analysis easy PSA function of pulse. the scintillator as the preparation of the ground water samples are mixed, the measure value detection is lowered over prepare period and expiration date. Energy spectrum was also moved to a lower side channel. As a long time to buy the scintillator and over time after opening, it was confirmed that detection is lowered. if the purpose is to use a different scintillator can see the energy through the channel change.

A Study on Nuclear Legacy Site Management according to International Management Guidance (국제 관리 지침에 따른 레거시 부지 관리에 대한 연구)

  • Chang, Sunyoung
    • Journal of the Korean Society of Radiology
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    • v.16 no.2
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    • pp.185-194
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    • 2022
  • The decommission of nuclear legacy sites, which have been contaminated by previous activities such as uranium mining & milling as well as nuclear tests, has started to gain global attention. Within the Korean peninsula, Republic of Korea(ROK)has had experience in dismantling research reactors. For the Democratic People's Republic of Korea(DPRK), the possibility of nuclear activities being implemented and operations records being managed without consideration of the latest nuclear safety regulations are high. Hence, the chances of DPRK's sites remaining as nuclear legacy is also high. This study investigates approaches and considerations that needs to be taken in account in the event of a nuclear legacy site occurrence, reviewing its international cases for the solution of the legacy sites. The regulation, process of optimization, and stakeholder engagement for a nuclear legacy site should be considered in such an event. Developing legacy site response plans can be used to prevent future legacy site occurrences.

Biogeochemistry of Metal and Nonmetal Elements in the Surface Sediment of the Gamak Bay (가막간 표층퇴적물 중의 금속 및 비금속 원소의 생지화확적 분포특성)

  • Kim, Pyoung-Joong;Shon, Sang-Gyu;Park, Soung-Yun;Kim, Sang-Soo;Jang, Su-Jeong;Jeon, Sang-Baek;Ju, Jae-Sik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.2
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    • pp.67-83
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    • 2012
  • In order to evaluate die geochemical characteristics of sediment in a semi-enclosed bay used as shellfish and fish farming area, the concentrations of metallic(V, Cr, Mn, Fe, Co. Ni, Cu, Zn, Ag, Cd, Hg, Ph, As) and non-metallic(P, Se) elements and uranium were measured in the surface sediment samples collected from 19 stations of Gamak Bay in April 2010. Metal contamination status in the sediments were also evaluated using the sediment quality guidelines(SQGs) proposed by the National Oceanic and Atmospheric Administration(NOAA) and the enrichment factor(EF). The concentrations of elements in sediment were mainly controlled by quartz-dilution effect(V, Cr, Fe, Co and Ni), the dilution effect of organic matter(Cd and U), and metal redistribution by the decomposition of organic matter(Mn, Ag, As, and Se). The concentrations of metals, except As and Ni, in sediments from all sampling stations were lower than ERL values of NOAA. Conclusively, the surface sediment of Gamak Bay was slightly polluted with Ni, Ag, Cd, and Cd but was not polluted with other elements on the basis of EF results. Our results suggest that the surface sediment in Gamak Bay is not polluted by metallic elements.

Acute oral toxicity and bioavailability of uranium and thorium in contaminated soil

  • Nur Shahidah Abdul Rashid;Wooyong Um ;Ibrahim Ijang ;Kok Siong Khoo ;Bhupendra Kumar Singh;Nurul Syiffa Mahzan ;Syazwani Mohd Fadzil ;Nur Syamimi Diyana Rodzi ;Aina Shafinas Mohamad Nasir
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1460-1467
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    • 2023
  • A robust approach was conducted to determining the absolute oral bioavailable (fab) fractions of 238U and 232Th in rats exposed to contaminated soil along with their hematotoxicity and nephrotoxicity. The soil sample is the International Atomic Energy Agency-312 (IAEA-312) certified reference material, whereas blood, bones, and kidneys of in vivo female Sprague-Dawley (SD) rats estimate 238U- and 232Th-fab fractions post-exposure. We predict the bioavailable concentration (Cab) and fab values of 238U and 232Th after acute soil ingestion. The blood 238U (0.750%) and 232Th (0.028%) reach their maximum fab values after 48 h. The 238U (fab: 0.169-0.652%) accumulates mostly in the kidney, whereas the 232Th (fab: 0.004-0.021%) accumulates primarily in the bone. Additionally, 238U is more bioavailable than 232Th. Post 48 h acute ingestion demonstrates noticeable histopathological and hematological alterations, implying that intake of 238U in co-contaminated soil can lead to erythrocytes and proximal tubules damage, whereas, 232Th intake can harm erythrocytes. Our study provides new directions for future research into the health implications of acute oral exposures to 238U and 232Th in co-contaminated soils. The findings offer significant insight into the utilization of in vivo SD rat testing to estimate 238U and 232Th bioavailability and toxicity in exposure assessment.

Radon concentration measurement at general house in Pusan area (부산지역 일반주택에서의 라돈농도측정)

  • Im, In-Cheol
    • Journal of radiological science and technology
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    • v.27 no.2
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    • pp.29-33
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    • 2004
  • Until early 1980s we have lived without thinking that radon ruins our health. But, scientists knew truth that radon radioactive danger is bedeviling on indoor that we live for a long time. Specially, interest about effect that get in danger and injury for Radon and human body is inactive in our country. Recently, with awareness for Radon contamination, We inform about importance and danger of Radon in some station of the Seoul subway, indoor air of school facilities and We had interest with measure and manages. Usually, Radon gas emitted in base of building enters into indoor through building floor split windage back among radon or indoor air of radon daughter nucleus contamination is increased. Therefore, indoor radon concentration rises as there are a lot of windages between number pipe of top and bottom and base that enter crack from estrangement of the done building floor, underground to indoor. Thus, Radon enters into indoor through architecture resources water as well as, kitchen natural gas for choice etc., but more than about 85% from earth's crust emit. Danger and injury of health by Radon and Radon daughter nucleus that is indicated for cause of lung cancer incerases content of uranium of soil rises specially from inside pit of High area and a mine, cave, hermetical space with house. Safe sub-officer of radon concentration can not know and danger always exists large or small during. So, Important thing reduces danger of lung cancer by lowering concentration of Radon within house and building. Therefore, is thought that need general house Radon concentration measurement, measured Radon concentration monthly using Sintillator radon monitor. Study finding appeared high all underground market 1 year than the ground, and the winter appeared high than the summer. Specially, month that pass over 4pCi in house that United States Environmental Protection Agency advises appeared in underground, and appeared and know Radon exposure gravity by 4 months during 12 months. Therefore, Thinking that establishment and regulation of norm and preparation of reduction countermeasure about Radon are pressing feels, and inform result that measure Radon concentration.

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