• Journal of the Korean Geotechnical Society
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• v.17 no.6
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• pp.123-133
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• 2001

Since most of soil slopes are in an unsaturated state, it is necessary to consider the unsaturated characteristics of soil slopes, in order to obtain more reasonable results. Therefore in this study we supplemented a slope stability analysis program to consider them, based on the concept of limit equilibrium. We also applied an optimization technique to search for a failure surface. Besides, we carried out experiments to obtain the unsaturated soil properties required in the analysis with weathered granite soils. We formulated a nonlinear apparent cohesion relationship with the matrix suction to be able to apply the unsaturated shear strength characteristics to the stability analysis. In addition, we intended to obtain more accurate soil water characteristic curves(SWCC) by measuring the change in volume of the specimen in the SWCC tests. As a result, we could appropriately assess the change of the safety factor according to the rainfall intensity and duration, by considering the variation of suction, permeability, and shear strength caused by the infiltration of rainfall into slopes.

• Journal of Photoscience
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• v.10 no.1
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• pp.9-20
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• 2003

Recent studies on the photoreactivity of l,4-unsaturated systems have changed some ideas that were firmly established in this area of research for many years. Thus, we have described the first examples of 2-aza-di-$\pi$-methane (2-ADPM) rearrangements promoted by triplet-sensitization and by single electron transfer (SET) using electron-acceptor sensitizers. These reactions afford N-vinylaziridine and cyclopropylimine photoproducts in the first examples of di-$\pi$-methane processes that yield three-membered ring heterocycles. l-Aza-1,4-dienes also undergo SET-promoted l-aza-di-$\pi$-methane (l-ADPM) rearrangements via radical-cation intermediates using electron acceptor sensitizers. In some cases, alternative cyclizations yielding different carbocycles and heterocycles have been observed. The l-ADPM and di-$\pi$-methane (DPM) reactions also occur via radical-anion intermediates on irradiation using electron donor sensitizers. On the other hand, the photoreactivity reported for $\beta$,${\gamma}$-unsaturated aldehydes for many years was decarbonylation to the corresponding alkenes. However, our studies demonstrate that these compounds undergo the oxa-di-$\pi$-methane (ODPM) rearrangement with high chemical and quantum efficiency. A comparison of the photochemical reactivity of $\beta$,${\gamma}$-unsaturated aldehydes and corresponding methyl ketones has shown that the ketones do not undergo the ODPM rearrangement while the corresponding aldehydes are reactive by this pathway. Monosubstituted $\beta$,${\gamma}$-unsaturated aldehydes at C-2 undergo the ODPM rearrangement yielding the corresponding cyclopropane carbaldehydes diastereoselectively. Finally, we have described the first examples of reactions, similar to the well know Norrish Type I process, which take place in the triplet excited state of $\beta$,${\gamma}$-unsaturated carbonyl compounds by excitation of the C-C double bond instead of the carbonyl group.

• Journal of the Korean Geotechnical Society
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• v.27 no.11
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• pp.55-69
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• 2011

The importance of unsaturated state in various geo-engineering problems has led to the advance of mechanical constitutive model emulating behavior of unsaturated soils in response to thermo-hydro-mechanical loading. Elasto-plastic mechanical constitutive model for unsaturated soil is formulated based on Bishop's effective stress. Effective stress and temperature are main variables in constitutive equation, and incremental formulation of constitutive relationship is derived to compute stress update and stiffness tensor. Numerical simulations involving coupled THM processes are conducted to discuss numerical stability and applicability of developed constitutive model: one-dimensional test, tri-axial compression test, and clay-buffering at high level radioactive waste disposal. Numerical results demonstrated that developed model can predict very complex behavior of coupled THM phenomena and is applicable to geo-engineering problems under various environmental conditions, as well as interpret typical behavior of unsaturated soils.

• Journal of the Korean GEO-environmental Society
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• v.10 no.3
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• pp.13-20
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• 2009

Generally, soil is regarded as fully saturated in Geotechnical Engineering and under ground structure design. Because it is in convenience and safety. But soils treated in field are almost in unsaturated state. Design in unsaturated state is difficult comparing with saturated soil. In unsaturated soil mechanics, parameters are usually not constant unlike saturated soil mechanics. Additionally lab or field tests in unsaturated soil mechanics are required more cost, time and theoretical difficulty. One of essential requisites for examination about unsaturated soil is Soil-Water Characteristic Curve (SWCC). It show the relation between soil suction and soil water content. Through many studies in and out of country, computation and testing methods for SWCC were introduced. But in this the country, most soil is granite soil that is widely spread in Korea. And the studies for granite soil's SWCC are not enough yet. In this paper, through studying for existing proposal methods about computation SWCC and collection data for domestic granite soils, It was determined the suitable method for domestic granite soils, and computed each granite soil's SWCC. The purpose of this paper is establishing database for domestic granite soil's SWCC as each region to convenience for applying to actual affairs. For this, studying about existing proposal methods for SWCC was performed and a computer program Soil-Vision is used. Furthermore for verification theoretical and testing methods were also performed.

• Journal of the Korean Geotechnical Society
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• v.15 no.6
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• pp.45-55
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• 1999

Wave-induced response, liquefaction and stability of unsaturated seabed are studied. The unsaturated seabed is modeled as a fluid-filled polo-elastic medium. The coupled process of fluid flow and the deformation of soil skeleton is formulated in the framework of Biot's theory. The resulting governing equations are solved using a semi-analytical method to evaluate the stresses and pore water pressure of unsaturated and multi-layered seabed. The semi-analytical method can be applied to calculate a pore pressure and the stresses of in anisotropic inhomogeneous seabed. The results indicate that the degree of saturation influences mostly on the magnitudes of a pore pressure and the stresses of unsaturated and multi-layed seabed. Based on the pore pressure and stresses in seabed, the analysis on the possibilities of liquefaction and shear failure was performed. The results show that the maximum depth of shear failure occurrence is deeper than the maximum liquefaction depth.

• Journal of the Korean GEO-environmental Society
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• v.7 no.5
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• pp.31-39
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• 2006

In this study, modified triaxial compression tests were carried out to investigate the characteristics of shear strength of unsaturated dredged soils. The variation of shear strength generally depends on more matric suction than drained conditions, and then is gradually converged in matric suction 100kPa. It indicates that the effective angle of internal friction and effective cohesion in unsaturated conditions increase due to degree of saturation, namely, matric suction than those of saturated conditions. Therefore, it shows that apparent friction angle, ${\phi}^b$ due to the variation of matric suction to evaluate reasonable shear strength parameters in unsaturated soils should be considered.

• Proceedings of the Korean Geotechical Society Conference
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• 2004.03b
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• pp.146-153
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• 2004

The goals of this study are to investigate the feasibility of the reference state approach in determining the generalized soil-water characteristic curve that is essential for characterization of unsaturated soil behavior. The soil-water characteristic curves are obtained from a number of specimens of fine-grained residual soils compacted with different void ratios. Based on the experimental test results, the feasibility of using the liquid limit state as the reference state for predicting the soil-water characteristic curve are verified. Finally, through the regression analysis of experimental data using the equation of Fredlund and Xing (1994), a reliable method is proposed to predict the generalized soil-water characteristic curve of fine-grained residual soils using the liquid limit state as the reference.

• Macromolecular Research
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• v.12 no.3
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• pp.282-289
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• 2004

We have extensively characterized the fluorescence behavior of unsaturated polyester (UP) resin in the absence and presence of a 1,3-bis-(l-pyrenyl)propane (BPP) fluorescent probe at various dynamic and isothermal cure histories by means of a steady-state fluorescence technique using a front-face illumination equipment. In addition, we explored the effect of the fluorescence intensity on the relaxation of the fluorescent probe in the UP resin by resting the dynamically and isothermally cured resin at ambient temperature and pressure for 24 h. The monomer fluorescence intensity, which has two characteristic peaks at 376 and 396nm, changed noticeably depending on the cure temperature and time and provided important information with respect to the molecular and photophysical responses upon curing. The result of the fluorescence study indicates that the increased local viscosity and restricted molecular mobility of the UP resin surrounding the BPP probe after curing are both responsible for the enhancement of the monomer fluorescence intensity. Our results also demonstrate that once the BPP probe has enough time to rearrange and become isolated prior to fluorescence, a sufficient amount of fluorescence is emitted. Therefore, we note that the fluorescence behavior of this UP resin system is influenced strongly by the relaxation process of the fluorescent probe in the resin as well as process used to cure the resin.

• Journal of Microbiology and Biotechnology
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• v.13 no.3
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• pp.360-365
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• 2003

The ability of 19 lactic acid bacteria to produce hydroxy fatty acids (HFAs) from unsaturated food fatty acids (USFAs) was tested. HFAs are related to human ailments, including steatorrhea. All the cultures produced HFAs from USFAs, unless their growth was inhibited by free USFAs. Lactococcus lactis subsp. lactis KFRI 131 converted oleic, linoleic, and linolenic acid into 10-hydroxyoctadecanoic acid (10-HODA), 10-hydroxyoctadecaenoic acid (10-HODEA), and 10-hydroxyoctadecadienoic acid (10-HODDEA), respectively. Both a USFA and a surfactant were needed for the bacterium to convert the fatty acid into the corresponding HFA. It was apparent that the production of 10-HODA was growth-related, while that of 10-HODDEA was not. It was unclear whether the production of 10-HODEA was growth-related.

• Geomechanics and Engineering
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• v.8 no.5
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• pp.687-706
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• 2015

Methods commonly used to evaluate the improvement of lime-treated expansive soil include swelling characteristics and unconfined compressive strength. In the field, lime-treated expansive soils are in compacted unsaturated state. Soil water characteristic curves (SWCCs) represent a key parameter to interpret and describe the behavior of unsaturated expansive soil. This paper investigates the use of SWCC as a technique to evaluate improvements acquired by expansive soil after lime treatment. Three different lime contents were considered 2%, 4% and 6% by dry weight of clay. Series of tests were performed to determine the SWCC for the different lime content under curing periods of 7 and 28 day. Correlations between key features of the soil water characteristic curves of lime treated expansive soils and basic engineering behavior such as swelling characteristics and unconfined compression strength were established. Test results revealed that initial slope ($S_1$), saturated water content ($w_{sat}$), and air entry value (AEV) play an important role in reflecting improvement in engineering behavior achieved by lime treatment.