• Title/Summary/Keyword: Unsaturated polyester

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Flexural Rigidity of MMA-Modified Fiberglass Reinforced Plastic Composite Pipe (MMA 개질 강화 플라스틱 복합관의 휨강성)

  • 연규석;최종윤;백종만;권택정;정중호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.429-432
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    • 2003
  • MMA-modified fiberglass-reinforced plastic composite pipe was produced by using the binder of MMA-modified unsaturated polyester resin in which low viscosity MMA was added to unsaturated polyester resin. Sixteen specimens were made of polymer mortar and fiberglass-reinforced plastic by the centrifugal method. For these specimens the external strength tests were carried out by taking the core thickness consisting of polymer mortar and the fiberglass content per unit area as experimental variables to figure out the effect of variations of these variables influencing on flexural rigidity that is an important property for the composite pipe. Results of this study are believed to provide the basic data for more economical and practical design of MMA-modified fiberglass-reinforced plastic composite pipe.

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Preparation and Properties of Low-shrinkage Polymer Concretes (저수축형 폴리머 콘크리트의 제조 및 물리.역학적 특성)

  • 황진하;연구석;이윤수;이기원
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.321-326
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    • 2000
  • Many different polymer based concrete materials are known today, but the large setting or hardening shrinkage of polymer concrete is a problem to overcome in their practical applications. The setting shrinkage reaches about five to ren times he drying shrinkage ordinary cement concrete, i.e, 50 to $60\times10^{-4}$. This paper deals with a reduction in the hardening shrinkage of unsaturated polyester resin concrete which is treated with respect to shrinkage-reducing agent content, S/a ratio and catalyst content, and tested for length change during hardening, and flexural and compressive strength. It is show that the change of shrinkage-reducing agent content and S/a ratio affected the length change of the unsaturated polyester resin concrete during hardening.

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A Experimental Study on Characteristic of Polymer Concrete Using Recycled PET Waste (폐PET를 재활용한 폴리머 콘크리트 특성에 관한 실험적 연구)

  • 조병완;구자갑;박승국;나선권
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.840-845
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    • 2003
  • Polymer concrete (PC) using unsaturated polyester resins based on recycled polyethylene terephthalate (PET) plastic waste were used in our study for grasping its mechanical properties such as compressive strength, tensile strength and flexural strength, etc. by changing its quantity of resin, filler and dilution(SM) respectively. As a result of it, compressive, tensile and flexural strength of PC indicated 752kgf/$cm^2$, 80kgf/$cm^2$, and 243kgf/$cm^2$, kind of satisfaction successively. Judging from the above results, polymer concrete (PC) using unsaturated polyester resins as a coupling are suitable for construction material both in the aspect of ECO-building materials and in the aspect of superior strength of PC so that it is good possibility of success as a product.

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An Experimental Study on Performance in Elevation of Porous Polymer Concrete (투수성 폴리머 콘크리트의 성능 향상에 관한 실험적 연구)

  • Choi, Kyu-Hyung;Lho, Byeong-Cheol;Joo, Myung-Ki;Lee, Bok-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.953-956
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    • 2008
  • The purpose of this study is to ascertain the void ratio, permeability coefficient and compressive strength of porous polymer concretes with unsaturated polyester. The porous polymer concretes using unsaturated polyester with polymer binder contents of 3.5, 4.0, 4.5 and 5.5% are prepared, and tested for void ratio, permeability coefficient and compressive strength. As a result, void ratio and permeability coefficient of porous polymer concrete decrease with increasing polymer binder content. However, the compressive strength of porous polymer concrete increase with increasing polymer binder content. The compressive strength of porous polymer concrete decrease with increasing permeability coefficient.

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Synthesis and Characterization of Graphene Based Unsaturated Polyester Resin Composites

  • Swain, Sarojini
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.2
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    • pp.53-58
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    • 2013
  • Graphene-based polymer nanocomposites are very promising candidates for new high-performance materials that offer improved mechanical, barrier, thermal and electrical properties. Herein, an approach is presented to improve the mechanical, thermal and electrical properties of unsaturated polyester resin (UPR) by using graphene nano sheets (GNS). The extent of dispersion of GNS into the polymer matrix was also observed by using the scanning electron microscopy (SEM) which indicated homogeneous dispersion of GNS through the UPR matrix and strong interfacial adhesion between the GNS and UPR matrix were achieved in the UPR composite, which enhanced the mechanical properties. The tensile strength of the nanocomposites improved at a tune of 52% at a GNS concentration of 0.05%. Again the flexural strength also increased around 92% at a GNS concentration of 0.05%. Similarly the thermal properties and the electrical properties for the nanocomposites were also improved as evidenced from the differential scanning caloriemetry (DSC) and dielectric strength measurement.

Fire Characteristics of Phenolic Resin for Interial Materials of Passenger Train (철도차량 내장재료용 페놀수지의 내열특성)

  • Lee, Cheul-Kyu;Lee, Duck-Hee;Jung, Woo-Sung
    • Journal of the Korean Society of Hazard Mitigation
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    • v.4 no.2 s.13
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    • pp.29-34
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    • 2004
  • The time to ignition, heat release rate characteristics, and carbon monoxide yield of fiber reinforced and sandwich phenol resin were investigated with cone calorimeter. The fire characteristics of unsaturated polyester, mostly being applied to the existing passenger train, and phenolic resin were compared. DSC & TGA was used to monitor the degree of thermal decomposition and weight loss for the phenolic resin. According to the cone calorimeter data, the time to ignition was shorter, heat release rate, and CO yield was higher as the external heat flux increased. Under the same heat flux, the time to ignition of sandwich type phenolic resin was shorter than that of laminated. The result of comparison between unsaturated polyester and phenolic resin was that phenolic resin was shown to have better fire resistance than unsaturated polyester.

Cure Behavior, Thermal Stability and Flexural Properties of Unsaturated Polyester/Vinyl Ester Blends (불포화 폴리에스터/비닐에스터 블렌드의 경화 거동, 열안정성 및 굴곡 특성)

  • 이종문;조동환
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.120-128
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    • 2003
  • The effects of catalyst, accelerator and blend composition on the cure behavior of unsaturated polyester resin (UPE), vinyl ester resin (VE) and their blends were studied using differential scanning calorimetry(DSC). The DSC thermograms strongly depend on each variable. The result shows that the small exothermic peak at 115$^{\circ}C$ is due mainly to the UPE component in the UPE/VE blends and the large one at 134~138 $^{\circ}C$ is due mainly to the VE component. The results also indicate that the change of the DSC thermogram measured after each blend was exposed to high temperature 18$0^{\circ}C$ and the fast curing conditions of a few tens seconds provide useful information on understanding the thermal processing of a blend at high speed. The measurements of resin flow time represent that there are three distinct stages of cure in the UPE/VE blends: induction, transition and macro-gelation stages, as similarly reported for UPE by others earlier. The thermal stability and flexural properties of the cured UPE are significantly improved by blending it with the VE, depending on the composition.

Curing Behaviors and Viscoelastic of UPE Resins with Different Glycol Molar Ratios (글리콜 몰비가 다른 불포화 폴리에스테르 수지의 경화거동 및 점탄성)

  • Lee, Sang-Hyo;Park, Yung-Hoon;An, Seung-Kook;Lee, Jang-Oo
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.15-24
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    • 2001
  • In this study, the effects of different glycol molar ratios of unsaturated polyester(UPE) resins on the curing behaviors were investigated. The cross linking process was checked or monitored by differential scanning calorimetry(DSC) and by viscoelastic properties of rigid-body pendulum model. The knife-edge from which the pendulum is suspended, is immersed in a reaction mixture, and the change of the viscoelastic behavior brings on those of the period(T) and logarithmic decrement(${\Delta}$) of the damped free oscillations of the pendulum. The values of T and ${\Delta}$ obtained are related to the dynamic modulus(E') and modulus loss(E'). The information on the viscoelastic behavior of unsaturated polyester(UPE) resins during the curing process are shown to illustrate the usefulness of the techniques. As the content of NPG in a propylene glycol(PG)/NPG glycol mixture increased, both the cycle time during cure and the change of damping during cure of UPE resin decreased.

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