• Title/Summary/Keyword: Unsaturated Polyester

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Effect of Organic Modifiers and Mixing Times on the Properties of Unsaturated Polyester/Montmorillonite Nanocomposite (유기 개질제의 종류와 혼합 시간에 따른 불포화 폴리에스터/ 몬모릴로나이트 나노복합체의 제조 및 특성)

  • 김호겸;이동호;서관호;김우식;박수영;민경은
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.589-595
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    • 2003
  • Unsaturated polyester (UP) nanocomposite with montmorillonite (MMT) which contains different types of organic modifiers far nano-filler have been prepared to investigate the effect of chemical structure of organic modifiers and mixing time of all components on properties of products. It was found that the morphology and various physical properties of UP/MMT nanocomposites were influenced by properties of organic modifiers of MMTs. It was also confirmed that the content of MMT does not significantly affect properties of UP/MMT nanocomposites.

A Study on the Frictional Characteristics of Fiber Reinforced Composites under Corrosive Environment (부식 환경 하에서의 섬유강화복합재료의 마찰 및 마모 특성 연구)

  • Choong-Yong Park;Dong-Hyun Park;Soo-Jeong Park;Yun-Hae Kim
    • Composites Research
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    • v.36 no.1
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    • pp.37-41
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    • 2023
  • The treated water inside the ballast electrolytic cell creates a highly alkaline atmosphere due to hydroxide generated at the DSA(Dimension Stable Anode) electrode during electrolysis. In this study, a composite material that can replace the weakness of the PE-coated steel pipe used in the existing ballast pipe was prepared. The test samples are BRE(Basalt fiber reinforced epoxy), BRP(Basalt fiber reinforced unsaturated polyester), GRE(Glass fiber reinforced epoxy), and GRP(Glass fiber reinforced unsaturated polyester). And then it was immersed in NaOH for 720 hours. The friction test of each specimen was conducted. The Friction coefficient analysis according to material friction depth and interfacial adhesion behavior between resin and fiber were analyzed. As a result, the mechanism of interfacial separation between resin and fiber could be analyzed. In the case of the unsaturated polyester resin with low interfacial bonding strength the longer the immersion time in the alkaline solution, the faster the internal deterioration caused by the deterioration that started from the surface, resulting in a decrease in the friction coefficient. It is hoped that this study will help to understand the degradation behavior of composite materials immersed in various chemical solutions such as NaOH, acid, and sodium hypochlorite in the future.

Fabrication and Mechanical properties of Steel Fiber Reinforced Polyester Resin Composites Utilizing by-Products (Fly Ash) (산업부산물을 이용한 강섬유보강 폴리에스터 수지복합체의 제조 및 역학적 특성)

  • 박승범;윤의식
    • Proceedings of the Korea Concrete Institute Conference
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    • 1992.04a
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    • pp.35-40
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    • 1992
  • Results of an experimental study on the manufacture, the workability and mechanical properties of steel fiber reinforced polyester resin composites utilizing industrial waste products are presented in this paper. The fly ash polyester resin composites using steel fiber, fly ash and calcium carbonic acid (CaCo3), unsaturated polyester resin, styrene monomer, cobalt octate and methyl ethyl ketone peroxide, fine and coarse aggregates are prepared with various filler~binder rations, binder rates and mixing conditions. As a test results, the workability of steel fiber reinforced polyester resin composites are considerably dropped with increasing fly ash-binder ratio and steel fiber volume. And compressive, flexural strength and bending toughness of the composites are remarkably improved with augmenting fiber contents.

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A Study on the Effects of Flame Retardants in Unsaturated Isophthalic Acid Polyester Resin (불포화 이소프탈산 폴리에스터 수지의 난연제 첨가 효과 연구)

  • 최원종
    • Fire Science and Engineering
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    • v.12 no.4
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    • pp.41-49
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    • 1998
  • In this study, the thermal improvement of an isophthalic acid polyester resin by the incorporation of flame retardants has been investigated. Aluminium hydroxide, antimony oxide and alumina powder were used to formulate the flame retardant systems. The improvement of an isophthalic resin by incorporating aluminium hydroxide is dramatic(burning rate and smoke emission are reduced), although the mechanical property is decreased significantly. The addition of small amount(2.5 phr) of antimony oxide produces high char yield(31%) which acts as a protective layer on the surface of the resin.

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Development of A Recycling Process for Waste FRP from Boats (선박용 폐 FRP 수지의 재활용 공정 개발)

  • 강세란;김영우;황덕기;김시영;이민규;주창식
    • Journal of Environmental Science International
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    • v.12 no.6
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    • pp.635-641
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    • 2003
  • A recycling process for the waste FRP from boats was developed. The recycling process is composed of decomposition of waste FRP with propylene glycol and synthesis of recycled unsaturated polyester resin from the decomposed liquid material. Prior to the decomposition, waste FRP was cut into 2cm x 5cm segments and mechanical impact was applied by press roller to give gaps between cumulated laminates. Propylene glycol effectively decomposed the waste FRP segments and glass fibers were easily separated from decomposed liquid material. Recycled unsaturated polyester resin could be made from the decomposed liquid material by reaction with maleic anhydride and phthalic anhydride.

A study on the Spectra reinforcement composite of its ballistic performance (방탄용 Spectra 섬유 강화 복합재료에 관한 연구)

  • 강은영;윤영기;윤희석
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.83-86
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    • 2001
  • This paper presents an investigation of the contribution of fibers in energy absorption during impact and the effect of resin types on properties of the high strength polyethylene (Spectra-900 PE) composite. In high strength polyethylene fiber, main impact energy absorbing mechanism was tensile breakage and deformation of fiber. Two types of resin were examined : Unsaturated polyester (UP) and Epoxy. Tensile and 3-point bending test have been performed to investigate the changes of mechanical properties. In tensile and flexural testes, the Spectra Composite prepregged with UP showed higher properties than Spectra Composite prepregged with epoxy.

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Effect of Unsaturated Polyester Resin Content on Properties of PMMA Mortars (PMMA 모르타르의 성질에 미치는 불포화 폴리에스테르 수지 첨가율의 영향)

  • Choi Nak Woon;Lee Chol Woong;Kim Wan Young;So Yang Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.332-335
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    • 2004
  • Polymethyl Methacrylate(PMMA) mortars using EPS solution-based binders are prepared with various unsaturated polyester resin(UP) contents of binder, and tested for working life. heat exothorm temperature, length change. compressive strength and temperature dependence of compressive strength. As a result, the working life of PMMA mortar is lengthened with raising UP content of binder. Length change of the mortar was condensed from expansion to shrinkage with increasing UP content, and non shrinkage of the mortar is obtained at about UP content of $2.5\%$. The compressive strength of the mortar is increased with an increase in the UP content and reach maximum at UP content of $5\%$. However thermal resistance improvement of the mortar by increasing UP content was not recognized. UP resin was recommended as an effective agent for shrinkage control and strength development of PMMA mortar.

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The Tree Growth and Breakdown Characteristics of Unsaturated Polyester Dissolving the Electronegative Gases (부성기체를 용해시킨 불포화 폴리에스터의 Tree 성장과 절연파괴 특성)

  • 이보호;전춘생
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.2
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    • pp.178-184
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    • 1992
  • This study treats the improvement of the dielectric strength of polymer by eliminating the air in it and dissolving electronegative gases. As experimental material, unsaturated polyester resin was used and the specimen was made by dissolving NS12T. SFS16T abd CCIS12TFS12T gases which have strong electron affinity. And also the electrical properties (tree growth and breakdown characteristics) of them were tested and discussed. The results are as follows. When the specimen dissolved with electronegative gas compared with one with air` 1) The tree breakdown voltage of the former is higher than that of the latter. 2) The tree growth of the former is slower than that of the latter. 3) The temperature dependence of the former is smaller than that of the latter. 4) The breakdown voltage of the specimen dissolved with electronegative gas is much higher than that dissolved with air.

Conductivity stability of carbon nanofiber/unsaturated polyester nanocomposites

  • Wu, Shi-Hong;Natsuki, Toshiaki;Kurashiki, Ken;Ni, Qing-Qing;Iwamoto, Masaharu;Fujii, Yoshimichi
    • Advanced Composite Materials
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    • v.16 no.3
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    • pp.195-206
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    • 2007
  • Carbon nanofiber (CNF)/unsaturated polyester resin (UPR) was prepared by a solvent evaporation method, and the temperature dependency of electrical conductivity was investigated. The CNF/UPR composites had quite a low percolation threshold due to CNF having a larger aspect ratio and being well dispersed in the UPR matrix. The positive temperature coefficient (PTC) was found in the CNF/UPR composites and it showed stronger effect around the percolation threshold. The electrical resistance of the CNF/UPR composites decreased and had lower temperature dependency with increasing numbers of thermal cycles.

Planting Properties of Porous Polymer Block Using Recycled Coarse Aggregates (재생굵은골재를 사용한 다공성 폴리머 블록의 식생 특성)

  • Sung, Chan-Yong;Kim, Young-Ik
    • Korean Journal of Agricultural Science
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    • v.37 no.1
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    • pp.87-96
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    • 2010
  • This study was performed to evaluate the planting properties of herbaceous plant and cool-season grass in porous polymer blocks that were manufactured by using recycled coarse aggregates and unsaturated polyester resin to develop environmentally friendly planting blocks. Unsaturated polyester resin, natural and recycled coarse aggregates and $CaCO_3$ were used. The mix proportions were determined to satisfy the requirement for the workability and slump according to aggregate sizes(5-10 and 5-20mm). Tests for the void ratio and compressive strength of porous polymer concrete were performed at curing age 7 days. Also, porous polymer block using recycled coarse aggregates were applied to kinds of plants such as tall fescue, Perennial ryegrass, Lesedeza and Alfalfa. After seed, initial germination, germination ratio, cover view and growth length for planting blocks were estimated by various methods.