• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1534-1538
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• 2011

Uniform, hollow nanosilica spheres were prepared by the chemical coating of cationic polystyrene (cPS) with tetraethylorthosilicate (TEOS), followed by calcination at 600 $^{\circ}C$ under air. cPS was synthesized by surfactant-free emulsion polymerization using 2,2'-azobis (2-methyl propionamidine) dihydrochloride as the cationic initiator, and poly(vinyl pyrrolidone) as a stabilizer. The resulting cPS spheres were 280 nm in diameter, and showed monodispersion. After coating, the hollow silica product was spherically shaped, and 330 nm in diameter, with a narrow distribution of sizes. Dispersion was uniform. Wall thickness was 25 nm, and surface area was 96.4 $m^2/g$, as determined by BET. The uniformity of the wall thickness was strongly dependent upon the cPS surface charge. The effects of TEOS and ammonia concentrations on shape, size, wall thickness, and surface roughness of hollow $SiO_2$ spheres were investigated. We observed that the wall thicknesses of hollow $SiO_2$ spheres increased and that silica size was simultaneously enhanced with increases in TEOS concentrations. When ammonia concentrations were increased, the irregularity of rough surfaces and aggregation of spherical particles were more severe because higher concentrations of ammonia result in faster hydrolysis and condensation of TEOS. These changes caused the silica to grow faster, resulting in hollow $SiO_2$ spheres with irregular, rough surfaces.

• 한국전기전자재료학회논문지
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• 제15권3호
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• pp.238-243
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• 2002

The dielectric properties and synthesis of $LaAIO_3$ ceramics from mixtures of $La_2O_3$ and $AI(OH)_3$ via ground(planetary ball mill) and unground(wet ball mill) were investigated. The single phase $LaAIO_3$ of ground powder was formed at $1000^{\circ}C$, while that of unground powder was formed at $1300^{\circ}C$. Density and grains of ground sample showed 98% of theory density and a uniform size of 0.75\mu\textrm{m}$, respectively, However those of unground sample showed 93% and non-uniform sizes of 4-5 $\mu\textrm{m}$. Dielectric constant and temperature coefficient of capacitance ($\tau$c) of both ground and unground samples were 21~22 and +70~74 ppm$/^{\circ}C$, respectively. Dielectric loss of ground sample(0.0004) was 10 times as low as that of unground sample(0.003) due to a uniform and small gram size.

• 한국재료학회지
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• 제13권8호
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• pp.524-530
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• 2003

In order to prepare the uniform copper particles from copper sulfate solution by using hydrazine as a reduction agents, the reduction behavior of copper particles from copper sulfate was investigated in detail at room temperature by the observation of reaction products. The effects of $NH_4$OH and $Na_4$$P_2$$O_{7}$ on the formation of uniform copper particles were discussed. ($NHCu_3$)$_4$$SO_4$was completely formed at over pH 11 by adding $NH_4$OH in copper sulfate solution. The fine $Cu_2$O with the particle size of 50 nm was produced in the initial reduction process of (NH$Cu_3$)$_4$$SO_4$solution with $Na_4$$P_2$$O_{ 7}$ and then the Cu$_2$O was converted into copper particles by inserting additional hydrazine. When Cu(NH$_3$)$_4$SO$_4$solution with $Na_4$$P_2$$O_{ 7}$ was reduced at $80^{\circ}C$ by hydrazine, the highly dispersed copper particles with the particle size of about 0.8 $\mu\textrm{m}$ was obtained.

• 한국의류학회지
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• 제21권5호
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• pp.854-864
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• 1997

This study was initiated to develop a uniform design suitable for child inpatients. The experimental hospital inpatient uniform design was developed based on the results of the prior studies. The panel was composed of 5 experienced nurses and 5 clothing specialists. They evaluated the function of the experimental inpatient uniforms developed in this study. The experimental hospital gown design was reformed based on the panel's evaluation.1'hen the child inpatients performed the wear test for the reformed experimental hospital gown. The results of the study are as follows; 1. The child inpatient hospital gown design of the most hospitals were similar to the adult patient's uniform : the V-neckline shirts with full length set-in sleeves. The bottom was full length pull-on pants. The fabric was white cotton with blue hospital logo and stripe print in most cases. 2. The panel's specialty affected the evaluation of the uniform design. The nurses concerned about the durability after washing and ease for medical treatment. The clothing specialists cared about the features related to the clothing construction and ease for physical movement of body. 3. The most preferred hospital inpatient uniform design by the panels was the shirts or one- piece gown with three-quarter length sleeve and overarm seam opening. 4. The researchers developed one-piece dress gown for the children under two years old. Three different size pajamas were developed for children 2∼5 years old,5∼8 years and 8∼12 years old.

• 한국표면공학회지
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• 제28권2호
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• pp.67-76
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• 1995

The microstructure of 95wt.%Pb/5wt.%Sn and 63wt.%Sn/37wt.%Pb solders for flip chip bonding process has been characterized. Solders were deposited by thermal evaporation and reflowed in the conventional furnace or by rapid thermal annealing(RTA) process. As-deposited films show columnar structure. The microstructure of furnace cooled 63Sn/37Pb solder shows typical lamellar form, but that of RTA treated solder has the structure showing an uniform dispersion of Pb-rich phase in Sn matrix. The grain size of 95Pb/5Sn solder reflowed in the furnace is about $5\mu\textrm{m}$, but the grain size of RTA treated solder is too small to be observed. The microstructure in 63Sn/37Pb solder bump shows the segregation of Pb phase in the Sn rich matrix regardless of reflowing method. The 63Sn/37Pb solder bump formed by RTA process shows more uniform microstructure. These result are related to the heat dissipation in the solder bump.

• 환경위생공학
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• 제11권1호
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• pp.39-44
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• 1996

The pressure fluctuations in a gas-solid fluidized bed has been analysed using s statistical method interpreting fluidized 냥d behavior. The performing statistical a analysis of the pressure fluctuations in a fluidized bed of 6.7cm-ID. using uniform p particle size of 115 to $1015{\mu}m$ in diameter. The fluidized gas used air(velocity 0.1~1.2m/sec) at settled bed height to diameter ratios which is LlD=l.O. Then, the pressure fluctuations measured by DPT(differantial pressure transducer). The measuring characteristic values of pressure fluctuation were the mean value and standard value, and also, it has been found that the standard deviation of the pressure fluctuations can be effectively used to predict minimum fluidizing velocity and to explain the fluidized phenomena.

• 대한기계학회논문집B
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• 제26권10호
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• pp.1451-1457
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• 2002

When an aqueous liquid such as water having high electric conductivity and high surface tension is discharged from a nozzle under a strong DC electric field, fine drops ranging from 30 to 450 microns can be obtained only through the spindle mode. In the present study, effects of the electric conductivity and the surface wettability of nozzle materials on formation of drops with this mode were investigated. For that, three nozzles with the same size but with different materials were prepared and tested; a stainless steel needle, and a plain and a metal (gold)-coated (except for the tip portion) silica needles. Uniform drops were obtained with the gold-coated silica nozzle over the wider range of the DC voltage input. That is, formation of the liquid cone and detachment of the liquid spindle (ligament) can be more stabilized and frequent with the needles having high electric conductivity but with low surface wettability at their tips.

• Structural Engineering and Mechanics
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• 제60권4호
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• pp.707-727
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• 2016

In this paper, thermal vibration of a nonlocal functionally graded (FG) plates with arbitrary boundary conditions under linear and non-linear temperature fields is explored by developing a refined shear deformation plate theory with an inverse cotangential function in which shear deformation effect was involved without the need for shear correction factors. The material properties of FG nanoplate are considered to be temperature-dependent and graded in the thickness direction according to the Mori-Tanaka model. On the basis of non-classical higher order plate model and Eringen's nonlocal elasticity theory, the small size influence was captured. Numerical examples show the importance of non-uniform thermal loadings, boundary conditions, gradient index, nonlocal parameter and aspect and side-to-thickness ratio on vibrational responses of size-dependent FG nanoplates.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 추계학술대회 논문집
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• pp.96-99
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• 2007

The microstructure with fine and uniform AGS(austenite grain size) along thickness direction over no recrystallization temperature is strongly required for production of the high strength steels. The previous AGS prediction only based on the average strain improves to find the rolling conditions for accomplishment of the fine grain, but cannot find those for uniform grain. In this paper, an integrated mathematical model for prediction of the strain distribution along thickness direction is developed by carrying out finite element simulation for a series of rolling conditions. Also, the AGS distribution after rough rolling is predicted by applying the proposed model with AGS prediction model.

• 소성∙가공
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• 제3권3호
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• pp.320-334
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• 1994

A set of full size cold rolled steel sheets has been prestrained in the direction of rolling by uniform tensile elongation of 3% and 6%. Then mid-sized tensile specimens were cut from each of the full size sheets at 30, 45, 60 and 90 degrees to the rolling direction. The mid-sized tensile specimens were then prestrained again by uniform tensile elongation by 1%, 2%, 5%, 10% and 15%. finally, miniature tensile specimens were prepared from each of the mid-sized specimens at every 10 degrees to the specimen axis. From the tensile tests on miniature specimens material's hardening behavior under non-proportional loading has been investigated. There are a number of new observations which has not been known to the authors before current work. One of them is continuous reservation of orthoropic symmetry during tensile elongation of mid-sized specimens. Another is continuous rotations of orthotropy axes. Existing theories seem to fail to explain this observations. A new model is proposed in relation to the rotation of orthotropy axes.