• Title/Summary/Keyword: Ultraviolet (UV) irradiation

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Analysis of the Surface Degradation in UV-irradiated High-Temperature Vulcanized Silicone Rubber (자외선 조사된 HTV 실리콘 고무의 표면열화 분석)

  • 연복희;이태호;허창수;이종한
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.5
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    • pp.411-419
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    • 2000
  • In this paper we have investigated the surface degradation by ultraviolet-irradiation in high-temperature vulcanized silicone rubber. Through the measurement of surface potential decay by corona-charging and of contact angle it is found that the change of surface electrostatic properties and the decrease of contact angle under UV-radiation. For the changes in micro-morphological and chemical structure of the UV-treated silicone rubber we utilized several analytical techniques such as SEM, ATR-FTIR,XPS. From this study it is shown that the chemical reactions(scissoring of side chain(S-$CH_3$) cross-linking and branching) occur on the surface of silicone rubber during the UV-irradiation. Also we obtained the results of the loss of low molecular weight chain by cross-linking and oxidation reaction.

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Erythrodermic Actinic Reticuloid Is Characterized by the Overspill of Oligoclonal CD8+ Lymphocytes Responsive To Ultraviolet Irradiation

  • Iwatsuki, Keiji;Ohtsuka, Mikio;Matsui, Takashi;Yamamoto, Takenobu;Fujii, Kazuyasu;Yamasaki, Osamu;Tsuji, Kazuhide
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.491-493
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    • 2002
  • Erythrodermic actinic reticuloid (EAR) is a photosensitive disorder characterized by dense lymphocytic infiltration in the sun-exposed areas and an increased number of atypical lymphocytes in the peripheral blood. We have reported 2 patients with EAR with circulating atypical lymphocytes and photosensitivity to both ultraviolet (UV) B and A. Although no clonal proliferation of T-cells was observed in the peripheral blood, CD8+ cells were increased in number in an oligoclonal fashion. A number of proliferating CD8+ cells were small, but most cells expressed bcl-2. These findings suggest EAR is a photosensitivity dermatitis characterized by the overspill of oligoclonal CD8+ lymphocytes responsive to UV irradiation.

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The Effect of Bamboo (Phyllostachys nigra var. henenis Strapf) Leaf Extract on Epidermal Melanocytes in Ultraviolet B-irradiated Mice (자외선 B를 조사한 마우스 표피멜라닌세포 변화에 대한 분죽(Phyllosrachys nigra var. henenis Strapf)잎 추출물의 효과)

  • Lee, Hae-June;Chae, Se-Lim;Kim, Sung-Ho
    • Journal of Radiation Protection and Research
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    • v.32 no.2
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    • pp.59-64
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    • 2007
  • We induced the activation of melanocytes in the epidermis of C57BL/6 mice by ultraviolet B (UVB) irradiation and observed the effect of bamboo (Phyllostachys nigra var. henenis Strapf) leaf extract (BLE) on the formation, and decrease of UVB-induced epidermal melanocytes. C57BL/6 mice were irradiated by $UVB\;80mJ/cm^2(0.5mW/sec)$ daily for 7 days, and BLE was intraperitoneally or topically applied pre-or post-irradiation. For the estimation of change of epidermal melanocytes, light microscopic observation with dihydroxyphenylalanine (DOPA) stain was performed. Split epidermal sheets prepared from the ear of untreated mice exhibited 11-16 $melanocytes/mm^2$, and one week after UV irradiation, the applied areas show an increased number of strongly DOPA-positive melanocytes with stout dendrites. But intraperitoneal or topical treatment with BLE before each irradiation interrupted UVB-induced pigmentation and resulted in a marked reduction in the number of epidermal melanocytes as compared to radiation control skin. The number and size of DOPA-positive epidermal melanocytes were also significantly decreased in intraperitoneally injected or topically applicated group after irradiation with BLE at 3rd and 6th weeks after irradiation. The results of present study indicate that BLE is likely to be useful as inhibitor of UVB-induced pigmentation and depigmenting agent.

The Inactivation Effects of UV Light on Bacteriophage f2 (박테리오파지 f2에 대한 자외광선의 살균효과)

  • Kim, Chi-Kyung;Quae Chae
    • Microbiology and Biotechnology Letters
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    • v.11 no.3
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    • pp.155-161
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    • 1983
  • The effects of ultraviolet light on bacteriophage f2 were investigated to determine the inactivation kinetics and its mechanism. The 260nm light showed a little higher inactivation rate than the one of 300 nm. In this work, our main concern was whether structural and/or conformational changes in the protein capsid could occur by UV irradiation. The inactivation for the first 20 minutes irradiation was rapid with a loss of about 4 logs and followed by a slower rate during the next 40 minutes with no survival noted in the samples irradiated for 90 minutes or longer. The structural change of the protein capsid was examined by optical spectroscopic techniques and electron microscopy. The absorption spectra of the UV irradiated phages showed no detectable differences in terms of the spectral shape and intensity from the control phage. However, the fluorescence emission spectroscopic data, i.e. 1) fluorescence quenching of tryptophan residues upon irradiation of 300 nm light, 2) enhancement of fluorescence emission of ANS (8-aniline-1-naphthalene sulfonate) bound to the intact phages compared to the one in the UV-treated phages, and 3) decrease of energy transfer efficiency from tryptophan to ANS in the UV-treated samples, presented remarkable differences between the intact and UV-treated phages. Such a structural alteration was also observed by electron microscopy The UV-treated phages appeared to be broken and empty capsids. Therefore, the inactivation of the bacteriophage f2 by UV irradiation is thought to be attributed to the structural change in the protein capsid as well as damage in the viral RNA by UV irradiation.

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Inactivation of various bacteriophages by different ultraviolet technologies: Development of a reliable virus indicator system for water reuse

  • Bae, Kyung Seon;Shin, Gwy-Am
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.350-354
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    • 2016
  • There is an urgent need to identify more reliable indicator systems for human pathogenic viruses in water reuse practice. In this study, we determined the response of different bacteriophages representing various bacteriophage groups to different ultraviolet (UV) technologies in real wastewater in order to identify more reliable bacteriophage indicator systems for UV disinfection in wastewater. Bacteriophage ${\varphi}X174$ PRD1, and MS2 in two different real wastewaters were irradiated with several doses of both low pressure (LP) and medium pressure (MP) UV irradiation through bench-scale UV collimated apparatus. The inactivation rate of ${\varphi}X174$ by both LP and MP UV was rapid and reached ${\sim}4{\log}_{10}$ within a UV dose of $20mJ/cm^2$. However, the inactivation rates of bacteriophage PRD1 and MS2 were much slower than the one for ${\varphi}X174$ and only ${\sim}1{\log}_{10}$ inactivation was achieved by the same UV dose of $20mJ/cm^2$. Overall, the results of this study suggest that bacteriophage MS2 could be a reliable indicator for human pathogenic viruses for both LP and MP UV disinfection in wastewater treatment processes and water reuse practice.

The Change of ATPase-positive Dendritic Cell and the Effect of Green Tea in Mouse Skin by Ultraviolet B Irradiation (자외선 B 조사에 의한 마우스 피부 ATPase 양성 가지세포의 변화 및 녹차투여의 효과)

  • Kim Sung-Ho;Kim Se-Ra;Lee Hae-June;Lee Jin-Hee;Kim Yu-Jin;Kim Jong-Choon;Jang Jong-Sik;Jo Sung-Kee
    • Toxicological Research
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    • v.20 no.4
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    • pp.315-320
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    • 2004
  • In this study we assessed the influences of ultraviolet (UV) light B radiation on epidermal ATPase-positive dendritic cell (DC) and the effect of green tea treatment in ICR mouse. The extent of changes following 200 mJ/$cm^2$ (0.5 mW/sec) was studied at 0, 6, 12, 18, 24, 30 or 36 hours after exposure. SBCs were decreased by 6 hours after irradiation. There was tendency to decrease from 6 hours to 24 hours and had little further change from then to 36 hours after irradiation. The mice that received 0, 50, 100, 200, 300 or 400 mJ/$cm^2$ of UVB were examined 24 hours after irradiation. The DCs were decreased as the radiation dose increases from 100 to 400 mJ/$cm^2$. The frequency of UVB (200 mJ/$cm^2$)-induced DC decrease was reduced by treatment of green tea (i.p. and topical application, p<0.01).

The Effects of Baickbujasan Extract on the Skin Damage and Pigmendation Induced by Ultraviolet Irradiation (백부자산(白附子散)이 자외선 조사된 피부 손상과 색소침착에 미치는 영향)

  • Kim, Ji-Hoon;Hong, Seong-Ug
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.21 no.1
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    • pp.70-82
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    • 2008
  • Objective : The purpose of this study is to examine the effects of Baickbujasan(BB) on the skin damage and depigmentation. Method : The inhibition of tyrosinase activity, melanogenesis and cell viability in cultured B16 melanoma cells were measured. In order to test effects of reduction of melanogenesis, B16 F-10 mouse melanoma stem line was employed to extract melanin from cultured cell, where BB was added or not, and was dissolved in alkali for colorimetric analysis. Also, in order to test skin alteration in C57BL/6 after UV irradiation, the animals were grouped into a UV urradiation group and UV irradiation after BB application group. Dopa oxidase tissue staining was excuted to invesitage the change in the distribution of active melanin cell. The distribution of active melanin cell in inner skin of iNOS after damage from UVB irradiation and the manifestation condition of P53 which takes part in natural death of keratinocyte were examined. Result : The results indicate that BB has significant effects on tyrosinase activity, and melanogenesis in vivo test. BB seems to reduce C57BL/6, external dermatological damage, for instance, erythematous papule, eczema, loss of keratinocyte, reduction in pus, and relieves dermatological damages. Conclusion : BB can be applied externally for UV protection and depigmentation.

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The Study on Swtiching Characterics of Organic Film by Photoisomerization (광이성화 유기박막의 스위칭 특성에 관한 연구)

  • 강용철;이우선;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.306-308
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    • 1997
  • The Maxwell displacement current was investigated in the connection with stwiching characteristics by photoisomerization of monolayers. The displacement current was generated due to the trans-to-cis photoisomerization by irradiation with ultraviolet light( λ$_1$1=360nm). whereas the displacement current was generated in the opposite direction due to the sis-to-trans photoisomerization by irradiation with visible light( λ$_1$=450nm). The reversible displacement current generation was found to be sustained by alternative irradiation with UV light and visible light.

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The improvement of characteristics for hydrogenated amorphous silicon thin films by photo-induced CVD (광 CVD에 의한 비정질 실리콘 박막 특성 향상)

  • 김용상;이성규;전명철;박진석;한민구
    • Electrical & Electronic Materials
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    • v.7 no.2
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    • pp.94-99
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    • 1994
  • The purpose of this work is to investigate the interface characteristics of hydrogenated amorphous silicon thin films prepared by PECVD and photo-induced CVD and to examine the annealing effects of ultraviolet irradiation on hydrogenated amorphous silicon thin films which were degraded by visible light illumination. The interface layer thickness of films deposited by photo-induced CVD was about 600-900.angs. while that by PECVD was about 1000-1300.angs.. These results can show that the quality of interface layer in photo induced CVD film is better than that in PECVD sample. The electrical properties are improved by ultraviolet irradiation on visible light soaked a-Si:H films using photo-CVD light sources, probably due to the fact that UV generates phonons in a-Si:H films and anneal the meta stable defects.

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Photocatalytic Degradation of Organic Dyes using CdSe-Mn-C60 Nanocomposites

  • Jiulong Li;Jeong Won Ko;Weon Bae Ko
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.181-187
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    • 2022
  • CdSe-Mn nanocomposites were synthesized using a microwave method with sodium sulfite (Na2SO3), selenium (Se), cadmium sulfate octahydrate (3CdSO4·8H2O), ammonia solution (NH3·H2O), and manganese (II) sulfate monohydrate (MnSO4·H2O). We obtained CdSe-Mn-C60 nanocomposites by calcining CdSe-Mn nanocomposites and fullerene (C60) in an electric furnace at 700 ℃ for 2 h. X-ray diffraction, Raman spectroscopy, and scanning electron microscopy were used to characterize the crystal structures, lattice vibrations, and surface morphologies of the products, respectively. The photocatalytic activities of the CdSe-Mn-C60 nanocomposites were investigated based on the photocatalytic degradations of organic dyes such as BG, MB, MO, and RhB under ultraviolet (UV) irradiation at 254 nm. UV-visible spectrophotometry was used to confirm the degradation process.