• Title/Summary/Keyword: Ultrafast Laser

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Ultrafast Time-Resolved Laser Spectroscopic Studies of trans-Bis(ferrocene-carboxylato)(tetraphenyl-porphyrinato)tin(IV): Intramolecular Electron-Transfer Dynamics

  • Jang, Joon-Hee;Kim, Hee-Jung;Kim, Hee-Joon;Kim, Chul-Hoon;Joo, Tai-Ha;Cho, Dae-Won;Yoon, Min-Joong
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1967-1972
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    • 2007
  • Photophysical properties of a newly-synthesized porphyrin derivative, trans-bis(ferrocene carboxylato)- (5,10,15,20-tetraphenylporphyrinato)tin(IV) [Sn(TPP)(FcCOO)2] were investigated by means of steady-state and fs-time resolved laser spectroscopic techniques, and compared with those of a standard molecule, trans-dichloro( 5,10,15,20-tetraphenyl-porphrinato)tin(IV) [Sn(TPP)Cl2]. The fluorescence spectrum of Sn(TPP)- (FcCOO)2 was observed to exhibit dual emission bands originating from the S2-state and the S1-state, which was greatly quenched as compared to those of Sn(TPP)Cl2. The fs-time resolved fluorescence and transient absorption spectroscopic measurements revealed that the fluorescence quenching is due to formation of the long-lived charge transfer state by intramolecular electron transfer from ferrocene to the S2-excited SnTPP in addition to the enhanced non-radiative deactivation processes.

Characteristic of FS-laser ablation of metal thin film with respect to the variation of material and substrate (펨토초 레이저를 이용한 박막 재료 및 기판 변화에 따른 가공 특성에 관한 연구)

  • Kim B.H.;Shin H.G.;Lee J.G.;Jeong S.C.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.671-672
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    • 2006
  • We have investigated the behavior of the ultrafast laser ablation of chromium films (200nm) on the silicon and pyrex-glass(corning 7740) substrate with respect to the laser fluence and the number of laser pulses. In addition, several experiments about ITO thin film were carried out with femto-second Ti:Sapphire laser (150fs). Finally, we introduce the ablation characteristic in accordance with materials of thin film and substrate.

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Precessional Motion of Ferromagnetic Pt/Co/Pt Thin Film with Perpendicular Magnetic Anisotropy (수직 자기 이방성을 갖는 Pt/Co/Pt 자성 박막의 세차 운동 측정 및 분석)

  • Yun, Sang-Jun;Lee, Jae-Chul;Choe, Sug-Bong;Shin, Kyoung-Ho
    • Journal of the Korean Magnetics Society
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    • v.21 no.6
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    • pp.204-207
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    • 2011
  • We developed a time-resolved magneto-optical Kerr effect microscope system to investigate ultrafast magnetization dynamics. Based on the pump-probe method, 0.1-ps time resolution was achieved by use of a fs Ti:Sapphire laser. The magnetization dynamics was then measured on Pt/Co/Pt thin films with various Co thicknesses. All the samples exhibited ultrafast demagnetization within a few ps by direct heating of pump laser. Some thicker samples showed precessional motion of magnetization, from which the Gilbert damping constant was determined based on the Landau-Lifshitz-Gilbert equation.

Laser Drilling of High-Density Through Glass Vias (TGVs) for 2.5D and 3D Packaging

  • Delmdahl, Ralph;Paetzel, Rainer
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.2
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    • pp.53-57
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    • 2014
  • Thin glass (< 100 microns) is a promising material from which advanced interposers for high density electrical interconnects for 2.5D chip packaging can be produced. But thin glass is extremely brittle, so mechanical micromachining to create through glass vias (TGVs) is particularly challenging. In this article we show how laser processing using deep UV excimer lasers at a wavelength of 193 nm provides a viable solution capable of drilling dense patterns of TGVs with high hole counts. Based on mask illumination, this method supports parallel drilling of up over 1,000 through vias in 30 to $100{\mu}m$ thin glass sheets. (We also briefly discuss that ultrafast lasers are an excellent alternative for laser drilling of TGVs at lower pattern densities.) We present data showing that this process can deliver the requisite hole quality and can readily achieve future-proof TGV diameters as small $10{\mu}m$ together with a corresponding reduction in pitch size.

FSF laser Development for the optical communication diagnosis and medical tomography application (광통신용 및 의용 계측을 위한 FSF Laser의 개발)

  • 지명훈;이영우
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.05a
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    • pp.514-517
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    • 2002
  • We developed Frequency-shifted feedback laser using AOM inside the cavity. The feedback loop of the laser is formed with the first-order diffracted light of the AOM to output mirror. It is shown that the FSF laser output has spectral output called“chirped frequency comb”with an ultrafast frequency chirp rate of several hundreds of PHz/s. It can know the range using chirped frequency comb in the optical range measurement that is FSF laser as source.

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Coherent Diffraction Imaging at PAL-XFEL

  • Kim, Sangsoo;Nam, Kihyun;Park, Jaehyun;Kim, Kwangoo;Kim, Bongsoo;Ko, Insoo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.85.2-85.2
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    • 2016
  • With the advent of ultra-short high-intense XFEL (X-ray Free Electron Laser), time-resolved dynamics has become of great importance in exploring femtosecond real-world phenomena of nanoscience and biology. These include studying the response of materials to femtosecond laser excitation and investigating the interaction of XFEL itself with condensed matter. A variety of dynamic phenomena have been investigated such as radiation damage, ultrafast melting process, non-equilibrium phase transitions caused by orbital-lattice-spin couplings. As far as bulk materials are concerned, the sample size has no effect on the following dynamic process. As a result, imaging information is not required by and large. If the sample size is of tens of nanometers, however, sample starts to experience quantum confinement effect which, in turn, affects the following dynamic process. Therefore, to understand the fundamental dynamic phenomena in nano-science, time-resolved imaging information is essential. In this talk, we will briefly introduce scientific highlights achieved in XFEL-based dynamics. In case of bio-imaging, recent scientific topics will be mentioned as well. Finally, we will aim to present feasible topics in ultrafast time-resolved imaging and to discuss the future plan of CXI beamline at PAL-XFEL.

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Coherent Control of Autler-Townes Splitting in Photoelectron Spectroscopy: The Effect of Laser Intensity and Laser Envelope

  • Qin, Chaochao;Zhai, Hongsheng;Zhang, Xianzhou;Liu, Yufang
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3294-3298
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    • 2014
  • We theoretically investigated the coherent control of Autler-Townes splitting in photoelectron spectroscopy of K2 molecule within an ultrafast laser pulse by solving the time-dependent Schrodinger equation using a quantum wave packet method. It was theoretically shown that we can manipulate the splitting of photoelectron spectroscopy by altering the laser intensity. Furthermore, it was found that the percentages of each peak in photoelectron spectroscopy can be controlled by changing the envelope of the laser pulse.

Real-Time Determination of Relative Position Between Satellites Using Laser Ranging

  • Jung, Shinwon;Park, Sang-Young;Park, Han-Earl;Park, Chan-Deok;Kim, Seung-Woo;Jang, Yoon-Soo
    • Journal of Astronomy and Space Sciences
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    • v.29 no.4
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    • pp.351-362
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    • 2012
  • We made a study on real-time determination method for relative position using the laser-measured distance data between satellites. We numerically performed the determination of relative position in accordance with extended Kalman filter algorithm using the vectors obtained through nonlinear equation of relative motion, laser simulator for distance measurement, and attitude determination of chief satellite. Because the spherical parameters of relative distance and direction are used, there occur some changes in precision depending on changes in relative distance when determining the relative position. As a result of simulation, it was possible to determine the relative position with several millimeter-level errors at a distance of 10 km, and sub-millimeter level errors at a distance of 1 km. In addition, we performed the determination of relative position assuming the case that global positioning system data was not received for long hours to see the impact of determination of chief satellite orbit on the determination of relative position. The determination of precise relative position at a long distance carried out in this study can be used for scientific mission using the satellite formation flying.

Non-Destructive Evaluation of Material Properties of Nanoscale Thin-Films Using Ultrafast Optical Pump-Probe Methods

  • Kim, Yun-Young;Krishnaswamy, Sridhar
    • Journal of the Korean Society for Nondestructive Testing
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    • v.32 no.2
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    • pp.115-121
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    • 2012
  • Exploration in microelectromechanical systems(MEMS) and nanotechnology requires evaluation techniques suitable for sub-micron length scale so that thermal and mechanical properties of novel materials can be investigated for optimal design of miro/nanostructures. The ultrafast optical pump-probe technique provides a contact-free and non-destructive way to characterize nanoscale thin-films, and its ultrahigh temporal resolution enables the study of heat-transport phenomena down to a sub-picosecond regime. This paper reviews the principle of optical pump-probe technique and introduces its application to the area of micro/nano-NDE.

Phase Modulation Optical Delay Line for Ultrafast OCT Application (초고속 OCT응용을 위한 위상변조 광지연단)

  • Hwang Daeseo;Lee Young-Woo
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.4
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    • pp.861-864
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    • 2005
  • In this paper, we system the system design and numerical analysis of the ultrafast optical delay line using by optical phase modulator. The numerical analysis carried out with 1310nm, lops laser and electro-optic phase modulator. As the results of numerical analysis, we show a scanning rate of 0.5 GHz and a delay range of 19.0ps. Compare with mechanical delay line, the optical delay line has a high scanning speed and a high repetition rate.