• 한국응용과학기술학회지
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• 제30권3호
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• pp.431-443
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• 2013

Sulfur content of diesel fuel has been cut down to under 10 ppm ULSD (ultra low sulfur diesel) level by environmental regulation with the aim of reducing exhaust emissions. This review discusses the methods and principles of sulfur reduction in diesel and presents an overview of new approaches for ultra-deep desulfurization. The deep HDS (hydrodesulfurization) problems of diesel streams is exacerbated by the inhibiting effect of co-existing aromatics, nitrogen compounds and $H_2S$. The new approaches to deep desulfurization includes non-HDS type processing schemes such as adsorptive, extractive and oxidative desulfurization.

• Journal of Mechanical Science and Technology
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• 제19권3호
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• pp.870-876
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• 2005

It seems very difficult to comply with upcoming stringent emission standards in vehicles. To develop low emission engines, better quality of automotive fuels must be achieved. Since sulfur contents in diesel fuels are transformed to sulfate-laden particulate matters as a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied. In general, flash point, distillation $90\%$ and cetane index are improved but viscosity can be worse in the process of desulfurization of diesel fuel. Excessive reduction of sulfur may cause to degrade viscosity of fuels and engine performance in fuel injection systems. This research focused on the performance of an 11,000 cc diesel engine and emission characteristics by the introduction of ULSD, bio-diesel and a diesel oxidation catalyst, where the bio-diesel was used to improve viscosity of fuels in fuel injection systems as fuel additives or alternative fuels.

• International Journal of Automotive Technology
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• 제4권2호
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• pp.95-100
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• 2003

Automobile industry has been developed rapidly as a key manufacturing industry in Korea. Meanwhile, air pollution is getting worse noticeably than ever. In the diesel emission, PM (Particulate Matter) and NOx (Nitrogen Oxides) have been exhausted with a great amount and the corresponding emission regulations are getting stringent. In order to develop low emission engines, it is necessary to research on better qualified fuels. Sulfur contained in fuel is transformed to sulfur compound by DOC (Diesel Oxidation Catalyst) and then it causes to the increase of sulfate-laden PM on the surface of catalyst. In this research, ULSD (Ultra Low Sulfur Diesel) is used as a fuel and some experimental results are investigated. ULSD can reduce not only PM but also gas materials because cetane value, flash point, distillation 90%, pour point and viscosity are improved in the process of desulfurization. However, excessively reduced sulfur may cause to decease lubricity of fuel and engine performance in fuel injection system. Therefore, it requires only modest adjusted amount of sulfur can improve engine performance and DOC, as well as decrease of emission.

• International Journal of Automotive Technology
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• 제7권6호
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• pp.653-658
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• 2006

The enormous increase in the use of fossil energy sources throughout the world has caused severe air pollution and a depletion of energy. Besides, it seems very difficult to comply with the upcoming stringent emission standards in vehicles. In order to develop low emission engines, research on better qualified fuels as alternative fuels to secure high engine performance becomes a more important issue than ever. Since sulfur contained in diesel fuel is transformed in sulfate-laden particulate matters when a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied. But the excessive reduction of sulfur levels may cause the lubricity of fuel and engine performance to degrade. In this aspect, biodiesel fuel derived from rice bran is applied to compensate viscosity lost in the desulfurization treatment. This research is focused on the performance of an 11,000cc diesel engine and the emission characteristics by the introduction of ULSD(Ultra Low Sulfur Diesel), BD20(Diesel 80%+Biodiesel 20%) and a diesel oxidation catalyst, where BD20 is used to improve the lubricity of fuel in fuel injection systems as fuel additives or alternative fuels.

• Tribology and Lubricants
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• 제16권5호
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• pp.332-340
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• 2000

The reduction of sulfur content in the diesel fuel has caused the poor lubricity of diesel fuel in the distributor type injection pumps of diesel engines that use the diesel for lubrication of their moving parts. To investigate the reason for poor lubricity of low sulfur diesel fuels, the wear scar diameters by HFRR (High Frequency Reciprocating Rig) were measured on the diesel fuels from Korean markets and the results were compared with their physical and chemical properties. Also, the lubricity change and the improvement effects on lubricity additives for the ultra low sulfur diesel fuel, were made experimentally, that will be regulated to a maximum of 0.005 wt% from about 2005 were evaluated. As a result, a good correlation was found between the wear scar diameter and the polyaromatic compound which includes heterocyclic compound in the diesel fuel. It was also found that the content of polyaromatic compound including heterocyclic compound was affected by the amount of desulfurization treatment fraction. And the lubricity additives with ester base were more effective than that with acid base on the ultra low sulfur diesel fuel. Therefore, it is suggested that the factors affecting the lubricity stated above should be taken into account to improve the lubricity property of the diesel fuel in the refining process.

• 한국대기환경학회지
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• 제22권1호
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• pp.53-61
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• 2006

Recently, lots of researchers have been attracted to develop various alternative fuels and to use renewable fuels in order to solve the exhaust emission problems. DME (Dimethylether) is synthetic fuel, and can be produced from natural gas, coal and biomass. The emission is clean because it contains little sulfur and aromatic components In this study, the fuel was tested to investigate the applicability as an alternative fuel for diesel. This study was carried out by comparing the exhaust emissions and performance of diesel engine with DME, ULSD (ultra low sulfur diesel), LSD (low sulfur diesel) respectively. In order to measure regulated emissions, CO, $NO_{3}$, HC from vehicle different fuel types were used on chassis dynamometer CVS (constant volume sampler)-75 mode and EPA TO-I1A method was chosen for aldehydes analysis.

• 한국산학기술학회논문지
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• 제7권5호
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• pp.788-792
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• 2006

본 논문은 터보가 장착된 8000cc 대형디젤엔진에 연속재생장식 매연저감장치를 장착함으로써 기관성능과 배기가스에 대한 영향을 알아보기 위하여 수행되었으며, 실험 조건은 황 함량이 430ppm 인 표준 디젤 연료와 황 함량이 50ppm인 저유황 연료의 조건 하에서 이루어졌다. CO, HC, NOx 및 PM은 D-13 모드에서 수행되었고 매연은 D-3 모드를 기준으로 배기가스 실험이 진행되었다.

• 대한기계학회논문집B
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• 제28권1호
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• pp.52-58
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• 2004

To develop a low emission engine, it is necessary to obtain some better quality of automotive fuels. Sulfur in fuel is transformed to sulfate-laden PM as DOC is applied. Therefore, it necessary to provide low sulfur fuels before DOC is applied. According to the specification of test fuels, flash point, distillation 90％, cetane index are improved but viscosity is decreased in the process of desulfurization. Excessively reduced sulfur may cause to decrease lubricity of fuel and engine performance in fuel injection system. Therefore, this research was emphasized how the application of Bio-diesel affects on the emission characteristics and engine performance under the circumstance of ULSD and DOC.

• 한국자동차공학회논문집
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• 제19권6호
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• pp.17-22
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• 2011

This study is to investigate the effect of the cetane number in ultra low sulfur diesel fuel on combustion characteristics and exhaust emissions at 1500 rpm and 2.6bar BMEP in low-temperature diesel combustion with 1.9L common rail direct injection diesel engine. Low-temperature diesel combustion was achieved by adopting external high EGR rate with the strategic injection control without modification of engine components. Test fuels are ultra low sulfur diesel fuel (sulfur less than 12 ppm) with two cetane numbers (CN), i.e., CN30 and CN55. For the CN30 fuel, as a start of injection (SOI) timing is retarded, the duration of an ignition delay was decreased while still longer than $20^{\circ}CA$ for all the SOI timings. In the meanwhile, the CN55 fuel showed that an ignition delay was monotonically extended as an SOI timing is retarded but much shorter than that of the CN30 fuel. The duration of combustion for both fuels was increased as an SOI timing is retarded. For the SOI timing for the minimum BSFC, the CN30 produced nearly zero PM much less than the CN55, while keeping the level of NOx and the fuel consumption similar to the CN55 fuel. However, the CN30 produced more THC and CO than the CN55 fuel, which may come from the longer ignition delay of CN30 to make fuel and air over-mixed.

• 대한기계학회논문집B
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• 제34권10호
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• pp.941-946
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• 2010

1.7L 커먼레일 직접분사 디젤엔진에 대하여 바이오 디젤 연료가 conventional 연소(PM-NOx 트레이드오프 존재)와 저온 연소(low temperature combustion, LTC)에서 배기가스 배출에 미치는 영향을 분석하였다. LTC 연소는 conventional 연소 대비 다량의 EGR 과 연료분사 조건 최적화를 통하여 이루어졌다. 실험에 사용한 두 가지 연료는 초저유황 디젤연료(ultra low sulfur diesel fuel, ULSD), ULSD 에 대두유를 20%(vol. base)혼합한 바이오 디젤 연료(B20)이다. 사용된 연료에 관계없이 LTC 연소를 통하여 conventional 연소 대비 PM 및 NOx 의 동시 저감이 가능하였다. 동일한 엔진작동 조건에 대하여 conventional 연소의 경우 B20 는 ULSD 보다 PM은 적게 배출되나, NOx 는 많이 배출되었다. LTC 연소의 경우 B20 는 ULSD 보다 PM 및 NOx 생성이 많았다.