• Journal of the Korean Applied Science and Technology
• /
• v.30 no.3
• /
• pp.431-443
• /
• 2013

Sulfur content of diesel fuel has been cut down to under 10 ppm ULSD (ultra low sulfur diesel) level by environmental regulation with the aim of reducing exhaust emissions. This review discusses the methods and principles of sulfur reduction in diesel and presents an overview of new approaches for ultra-deep desulfurization. The deep HDS (hydrodesulfurization) problems of diesel streams is exacerbated by the inhibiting effect of co-existing aromatics, nitrogen compounds and $H_2S$. The new approaches to deep desulfurization includes non-HDS type processing schemes such as adsorptive, extractive and oxidative desulfurization.

• Journal of Mechanical Science and Technology
• /
• v.19 no.3
• /
• pp.870-876
• /
• 2005

It seems very difficult to comply with upcoming stringent emission standards in vehicles. To develop low emission engines, better quality of automotive fuels must be achieved. Since sulfur contents in diesel fuels are transformed to sulfate-laden particulate matters as a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied. In general, flash point, distillation $90\%$ and cetane index are improved but viscosity can be worse in the process of desulfurization of diesel fuel. Excessive reduction of sulfur may cause to degrade viscosity of fuels and engine performance in fuel injection systems. This research focused on the performance of an 11,000 cc diesel engine and emission characteristics by the introduction of ULSD, bio-diesel and a diesel oxidation catalyst, where the bio-diesel was used to improve viscosity of fuels in fuel injection systems as fuel additives or alternative fuels.

• International Journal of Automotive Technology
• /
• v.4 no.2
• /
• pp.95-100
• /
• 2003

Automobile industry has been developed rapidly as a key manufacturing industry in Korea. Meanwhile, air pollution is getting worse noticeably than ever. In the diesel emission, PM (Particulate Matter) and NOx (Nitrogen Oxides) have been exhausted with a great amount and the corresponding emission regulations are getting stringent. In order to develop low emission engines, it is necessary to research on better qualified fuels. Sulfur contained in fuel is transformed to sulfur compound by DOC (Diesel Oxidation Catalyst) and then it causes to the increase of sulfate-laden PM on the surface of catalyst. In this research, ULSD (Ultra Low Sulfur Diesel) is used as a fuel and some experimental results are investigated. ULSD can reduce not only PM but also gas materials because cetane value, flash point, distillation 90%, pour point and viscosity are improved in the process of desulfurization. However, excessively reduced sulfur may cause to decease lubricity of fuel and engine performance in fuel injection system. Therefore, it requires only modest adjusted amount of sulfur can improve engine performance and DOC, as well as decrease of emission.

• International Journal of Automotive Technology
• /
• v.7 no.6
• /
• pp.653-658
• /
• 2006

The enormous increase in the use of fossil energy sources throughout the world has caused severe air pollution and a depletion of energy. Besides, it seems very difficult to comply with the upcoming stringent emission standards in vehicles. In order to develop low emission engines, research on better qualified fuels as alternative fuels to secure high engine performance becomes a more important issue than ever. Since sulfur contained in diesel fuel is transformed in sulfate-laden particulate matters when a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied. But the excessive reduction of sulfur levels may cause the lubricity of fuel and engine performance to degrade. In this aspect, biodiesel fuel derived from rice bran is applied to compensate viscosity lost in the desulfurization treatment. This research is focused on the performance of an 11,000cc diesel engine and the emission characteristics by the introduction of ULSD(Ultra Low Sulfur Diesel), BD20(Diesel 80%+Biodiesel 20%) and a diesel oxidation catalyst, where BD20 is used to improve the lubricity of fuel in fuel injection systems as fuel additives or alternative fuels.

• Tribology and Lubricants
• /
• v.16 no.5
• /
• pp.332-340
• /
• 2000

The reduction of sulfur content in the diesel fuel has caused the poor lubricity of diesel fuel in the distributor type injection pumps of diesel engines that use the diesel for lubrication of their moving parts. To investigate the reason for poor lubricity of low sulfur diesel fuels, the wear scar diameters by HFRR (High Frequency Reciprocating Rig) were measured on the diesel fuels from Korean markets and the results were compared with their physical and chemical properties. Also, the lubricity change and the improvement effects on lubricity additives for the ultra low sulfur diesel fuel, were made experimentally, that will be regulated to a maximum of 0.005 wt% from about 2005 were evaluated. As a result, a good correlation was found between the wear scar diameter and the polyaromatic compound which includes heterocyclic compound in the diesel fuel. It was also found that the content of polyaromatic compound including heterocyclic compound was affected by the amount of desulfurization treatment fraction. And the lubricity additives with ester base were more effective than that with acid base on the ultra low sulfur diesel fuel. Therefore, it is suggested that the factors affecting the lubricity stated above should be taken into account to improve the lubricity property of the diesel fuel in the refining process.

• Journal of Korean Society for Atmospheric Environment
• /
• v.22 no.1
• /
• pp.53-61
• /
• 2006

Recently, lots of researchers have been attracted to develop various alternative fuels and to use renewable fuels in order to solve the exhaust emission problems. DME (Dimethylether) is synthetic fuel, and can be produced from natural gas, coal and biomass. The emission is clean because it contains little sulfur and aromatic components In this study, the fuel was tested to investigate the applicability as an alternative fuel for diesel. This study was carried out by comparing the exhaust emissions and performance of diesel engine with DME, ULSD (ultra low sulfur diesel), LSD (low sulfur diesel) respectively. In order to measure regulated emissions, CO, $NO_{3}$, HC from vehicle different fuel types were used on chassis dynamometer CVS (constant volume sampler)-75 mode and EPA TO-I1A method was chosen for aldehydes analysis.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.7 no.5
• /
• pp.788-792
• /
• 2006

The test was conducted on an 8000cc heavy-duty turbo-charged heavy-duty diesel engine on which continuous regeneration DPF was installed in order to investigate regeneration characteristics fur DPF and engine performance under conditions of standard (430ppm) or ultra low sulfur diesel (50ppm) and the results were compared with each other. Exhaust emissions, CO, HC, NOx, PM and soot were investigated carefully and tested under D-13 and D-3 modes.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.28 no.1
• /
• pp.52-58
• /
• 2004

To develop a low emission engine, it is necessary to obtain some better quality of automotive fuels. Sulfur in fuel is transformed to sulfate-laden PM as DOC is applied. Therefore, it necessary to provide low sulfur fuels before DOC is applied. According to the specification of test fuels, flash point, distillation 90％, cetane index are improved but viscosity is decreased in the process of desulfurization. Excessively reduced sulfur may cause to decrease lubricity of fuel and engine performance in fuel injection system. Therefore, this research was emphasized how the application of Bio-diesel affects on the emission characteristics and engine performance under the circumstance of ULSD and DOC.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.19 no.6
• /
• pp.17-22
• /
• 2011

This study is to investigate the effect of the cetane number in ultra low sulfur diesel fuel on combustion characteristics and exhaust emissions at 1500 rpm and 2.6bar BMEP in low-temperature diesel combustion with 1.9L common rail direct injection diesel engine. Low-temperature diesel combustion was achieved by adopting external high EGR rate with the strategic injection control without modification of engine components. Test fuels are ultra low sulfur diesel fuel (sulfur less than 12 ppm) with two cetane numbers (CN), i.e., CN30 and CN55. For the CN30 fuel, as a start of injection (SOI) timing is retarded, the duration of an ignition delay was decreased while still longer than $20^{\circ}CA$ for all the SOI timings. In the meanwhile, the CN55 fuel showed that an ignition delay was monotonically extended as an SOI timing is retarded but much shorter than that of the CN30 fuel. The duration of combustion for both fuels was increased as an SOI timing is retarded. For the SOI timing for the minimum BSFC, the CN30 produced nearly zero PM much less than the CN55, while keeping the level of NOx and the fuel consumption similar to the CN55 fuel. However, the CN30 produced more THC and CO than the CN55 fuel, which may come from the longer ignition delay of CN30 to make fuel and air over-mixed.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.34 no.10
• /
• pp.941-946
• /
• 2010

This study aims to investigate the effects of soybean biodiesel fuel on exhaust emissions with regards to two combustion modes: conventional combustion(existence of PM-NOx trade-off behavior) and low temperature combustion(LTC) in a 1.7 L common rail direct injection diesel engine. As compared to conventional combustion, LTC was achieved by adopting a heavier exhaust gas recirculation and strategic injection parameter optimization. Two sets of fuels, i.e. ultra low sulfur diesel(ULSD) and 20% volumetric blends of soybean biodiesel with ULSD(B20) were used. Regardless of the fuel type, in LTC the simultaneous reduction of PM and NOx was observed and both levels were significantly lower than in case of conventional combustion. Under the given engine operating condition in the case of conventional combustion, B20 produced less PM and more NOx than ULSD. In the case of LTC combustion, B20 produced more PM and NOx than ULSD.