• Title/Summary/Keyword: UV-visible spectroscopy

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Analysis of Germanium in the Ore Samples by UV-Visible Spectroscopy

  • Reddy, K. Raghava;Lee, Kwang-Pill;Gopalan, Anantha Iyengar;Showkat, Ali Md;Kim, Sang-Ho;Paek, U-Hyon
    • Analytical Science and Technology
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    • v.17 no.6
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    • pp.476-480
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    • 2004
  • A simple, rapid, reproducible and selective UV-Visible spectrophotometric method has been developed for determination of germanium in a week acid medium (pH = 3.0) in the presence of mandelic acid (MA) and malachite green (MG). A single extraction in chlorobenzene was used for the analysis. The germanium-MA ion association complex exhibits an absorption maximum at ${\lambda}_{max}=618nm$ with MG as counter ion and has an apparent molar absorptivtity of $1.313{\times}10^5L\;mol^{-1}\;cm^{-1}$. The values obtained by this UV-Visible spectrophotometric method are in good agreement with the values from inductively coupled plasma-mass spectrometer analysis.

Facile Hydrothermal Synthesis and Characterization of the $CeO_2$ Nanorings

  • Arul, N. Sabari;Kim, Tae Whan;Mangalaraj, Devanesan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.455-455
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    • 2013
  • $CeO_2$ nanorings were synthesized by using a surfactant free hydrothermal method. The surface morphology, structural and optical properties of the synthesized $CeO_2$ was investigated by using scanning electron microscopy (SEM), X-ray diffraction (XRD), and ultraviolet-visible (UV) spectroscopy measurements. SEM images showed that the surface morphology of the formed $CeO_2$ appeared as nanorings. The XRD pattern of $CeO_2$ nanorings showed the presence of the polycrystalline $CeO_2$ phase readily indexed to the cubic fluorite structure of the $CeO_2$. The mean crystallite size of the $CeO_2$ was calculated using the Scherrer equation from the XRD line broadening of the (111) planes of the cubic $CeO_2$. The UV-Visible spectroscopy spectrum of the $CeO_2$ nanorings exhibited a strong UV absorption band around 350 nm.

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Determination of the Dissociation Constant of Thymol Blue with Diode-Laser/Fiber-Optic Thermal Lensing Spectroscopy

  • 김성호;노영순
    • Bulletin of the Korean Chemical Society
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    • v.19 no.8
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    • pp.822-824
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    • 1998
  • The simple and convenient measurement of the dissociation constant of an indicator, thymol blue, was achieved by using a portable diode-laser/fiber-optic thermal lensing spectroscopy, which consisted of a visible diode laser, a photodiode, and an optical fiber. It gives comparable results to the cited value obtained from a conventional UV/VIS spectroscopy.

Synergistic Effect of Reductase and Keratinase for Facile Synthesis of Protein-Coated Gold Nanoparticles

  • Gupta, Sonali;Singh, Surinder P.;Singh, Rajni
    • Journal of Microbiology and Biotechnology
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    • v.25 no.5
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    • pp.612-619
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    • 2015
  • We have synthesized gold nanoparticles (GNPs) using chicken feathers (poultry waste) and Bacillus subtilis RSE163. Disulfide reductase and keratinase produced by Bacillus subtilis during the degradation of chicken feather has been used to reduce Au3+ from HAuCl4 precursor to produce gold nanoparticles. The synthesized biogenic GNPs were characterized by UV-visible spectroscopy, transmission electron microscopy (TEM), and zeta potential measurements. Fourier transform infrared (FTIR) spectroscopy indicated the presence of protein capping on synthesized GNPs, imparting multifunctionality to the GNP surface. Furthermore, the nontoxic nature of biogenic GNPs was insured by interaction with Escherichia coli (ATCC11103), where TEM images and enhancement of growth rate of E. coli in log phase signified their nontoxic nature. The results indicate that the synthesis of biocompatible GNPs using poultry waste may find potential applications in drug delivery and sensing.

Fabrication of Conductive ZnO Thin Filn Using UV-Enhanced Atomic Layer Deposition

  • Yang, Da-Som;Kim, Hong-Beom;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.373-373
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    • 2012
  • We fabricated conductive zinc oxide (ZnO) thin film at low temperature by UV-enhanced atomic layer deposition. The atomic layer deposition relies on alternate pulsing of the precursor gases onto the substrate surface and subsequent chemisorption of the precursors. In this experiment, diethylzinc (DEZ) and $H_2O$ were used as precursors with UV light. The UV light was very effective to improve the conductivity of the ZnO thin film. The thickness, transparency and resistivity were investigated by ellisometry, UV-visible spectroscopy and Four-point probe.

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Ag-modified BiOX (X=Cl, Br and I) Plates for Photocatalytic Dye Removal

  • Lee, Seung-Won;Choe, Yeong-In;Lee, Ju-Heon;Park, Yo-Han;Son, Yeong-Gu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.424.2-424.2
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    • 2014
  • Ag-modified BiOX (X=Cl, Br and I) nanoplates were synthesized by an ion-exchange reaction. We examined the fundamental properties by scanning electron microscopy (SEM), electron transmission microscopy (TEM), X-ray diffraction, UV-visible absorption, Fourier-transform infrared and photoluminescence spectroscopy. The adsorption and photocatalytic performances of the catalysts were tested with dyes under UV and visible light. A chemical scavenger method was employed to test the roles of active species (${\cdot}OH$, ${\cdot}O2-$ and h+) and understand photodegradation mechanism. Photoluminescence spectroscopy was used to examine ${\cdot}OH$ radical formation using terephthalic acid during photoirradiation.

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Photostabilization and Cure Kinetics of UV-Curable Optical Resins Containing Photostabilizers

  • Cho, Jung-Dae;Kim, Sung-Hwa;Chang, In-Cheol;Kim, Kwon-Seok;Hong, Jin-Who
    • Macromolecular Research
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    • v.15 no.6
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    • pp.560-564
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    • 2007
  • The photostabilization and cure kinetics of UV-curable, optical resins containing various formulations of photostabilizers were investigated to determine the system with the highest cure conversion and durability. Photo-DSC analysis revealed that increasing the concentration of a UV absorber (UVA) decreased both the crosslink density and the cure rate due to competition for the incident photons between the photoinitiator and the UVA, whereas including a hindered amine light stabilizer (HALS) hardly affected either the cure conversion or the cure rate due to its very low absorption of 365 nm. This result was confirmed by FTIR-ATR spectroscopy and UV-visible spectroscopy analyses. QUV ageing experiments showed that the cure conversion and durability were the highest for the UVA/HALS formulation at a ratio of 1 : 2, which is due to their synergistic action.

A study on the color analysis of the pigment by UV-Visible spectroscopy (분광분석기를 이용한 안료의 색상분석에 관한 연구)

  • Jung, Choong-Ho;Kang, Tae-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.515-521
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    • 2010
  • In this research, we were prepared the glazed ceramic samples by the change of the pigment content and investigated to reveal the standardized color. The chemical composition of the pigment was analyzed using a ICP-OES. XRF mapping and UV-Vis spectroscopy were used to evaluate the color property and surface homogeneity. The color development was observed as a result of analyzing the pigment content and change of the color. The pigment content and the spectral reflection showed the relation of the inverse proportion and the standardized color which could be revealed through analysis data.