• Title/Summary/Keyword: UV-spectrum

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${\prod}-A$ and UV-visible characteristics of N-docosylquinolium-(TCNQ) monolayer (N-docosylquinolium-(TCNQ) 단분자막의 ${\prod}-A$ 및 UV 특성)

  • Park, S.K.;Choi, K.H.;Choi, Y.S.;Kwon, Y.S.;Hong, E.S.;Kang, D.Y.
    • Proceedings of the KIEE Conference
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    • 1991.11a
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    • pp.333-335
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    • 1991
  • ${\prod}-A$ characteristics and UV-visible spectrum of N-docosylquinolium-TCNQ monolayers were investigated. ${\prod}-A$ characteristics of N-docosylquinolium-TCNQ monolayer were measured following variation. i > ${\prod}-A$ characteristics with a variation of spreading amount. ii > ${\prod}-A$ characteristics with a variation of subphase temperature. An optium surface pressure for a LB Film deposition was found to be a 30, 45 mN/m in pure water subphase(pH 5.4, $25^{\circ}C$). UV-visible spectrum Analysis of these LB film were investigated. As a result, we think two kinds of surface pressure had no effect the monolayer aggregation but monolayer density.

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Carotenoid, Color value, UV Spectrum, Organic Acid and Free Sugar Contents of Citrus Varieties Produced in Cheju (제주산 감귤 품종별 carotenoid, 색도, UV 스펙트럼, 유기산 및 유리당 함량)

  • 김병주;김효선
    • Food Science and Preservation
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    • v.3 no.1
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    • pp.23-32
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    • 1996
  • Total carotenoid contents, color values and spectrum characterization in the range of UV of fruit juice and organic acid and free sugar contents determined by HPLC were investigated on 10 varieties of Cheju citrus fruits. Carotenoid contents of juice were 0.47-9.20$\mu\textrm{g}$/ml which showed higher with Dangyooja while showed lowest content with Meiwa Kumquat. Lightness (L) of juice was highest in Meiwa Kumquat, and in the order of Sankyool, Navel orange and Hungjin. Redness(a) and yellowness(b) were in the order of Dangyooja, Natsudaidai, Sambokam and Kinkoji. The maximum absorption wavelengths if citrus Juices were variable at 269.5-285.5nm according to varieties and it was observed that were changed by mixing with Juices of other varieties. Major organic acids of citrus juice were citric and malic acid, and citric acid was 64.4-95.1% of total organic acids. Ascorbic acid was high in Navel orange, Sudachi and Dangyooja, and low in Meiwa Kumquat and Hungjin. Major free sugars were sucrose, glucose and fructose. Sucrose was 49.2-75.2% of total free sugars, and high in Sankyool and Meiwa Kumquat. Glucose and fructose were high in Meiwa Kumquat and Navel Orange.

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Electrochemical Behaviors of Copper-1-(2-pyridylazo)-2-naphthol Complex in Acetonitrile (아세토니트릴 용매 중에서 Copper-1-(2-pyridylazo)-2-naphthol 착물의 전기화학적 성질)

  • Zun-Ung Bae;Sang-O Oh;Hee-Bong Song;Tae-Myung Park
    • Journal of the Korean Chemical Society
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    • v.37 no.10
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    • pp.888-894
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    • 1993
  • The electrochemical behaviors of copper-1-(2-pyridylazo)-2-naphthol(Cu-PAN) complex in acetonitrile (AN) solution have been investigated by the use of cyclic voltammetry, DC-polarography, controlled potential coulometry and UV-Vis spectroscopy. Cu-PAN complex in acetonitrile exhibit three reduction waves at -1.27 V, -1.64 V and -2.08 V vs. Ag/AgNO$_3$(AN). The numbers of electron involved in each reduction step was calculated with controlled potential coulometry, and reduction product was identified with UV-Vis spectrum. As the result, we proposed the reduction mechanism of the Cu-PAN complex in acetonitrile.

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High Resolution Near Infrared Spectrum of NGC 7023

  • Le, Huynh Anh N.;Pak, Soojong;Lee, Hye-In;Lee, Jae-Joon;Nguyen-Luong, Quang;Kaplan, Kyle;Jaffe, Daniel T.
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.93.1-93.1
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    • 2014
  • The reflection nebula NGC 7023 is a typical example of a photodissociation region (PDR), which consists of high density molecular gas that is exposed to an intense UV radiation field. The source of the UV photons in NGC 7023 is the young pre-main-sequence Be star HD 200755. We present our near-infrared high-resolution (R ~ 40,000) spectrum of NGC 7023, covering a region of $1{\times}15$ arcseconds, observed during the commissioning runs of IGRINS (Immersion GRating near-INfrared Spectrometer). The spectrum shows many strong narrow emission lines that arise from the molecular rovibrational transitions of H2. From the intensity ratios between these H2 lines, we investigate physical conditions within the PDR such as the temperature, density, and pressure. The high spectral resolution of IGRINS allows us to resolve the velocity field of the PDR. In addition, we compare the IGRINS spectrum to Cloudy PDR model.

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Characterization of the ZnSe/ZnS Core Shell Quantum Dots Synthesized at Various Temperature Conditions and the Water Soluble ZnSe/ZnS Quantum Dot

  • Hwang, Cheong-Soo;Cho, Ill-Hee
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1776-1782
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    • 2005
  • ZnSe/ZnS, UV-blue luminescent core shell quantum dots, were synthesized via a thermal decomposition reaction of organometallic zinc and solvent coordinated Selenium (TOPSe) in a hot solvent mixture. The synthetic conditions of the core (ZnSe) and the shell (ZnS) were independently studied at various reaction temperature conditions. The obtained colloidal nanocrystals at corresponding temperatures were characterized for their optical properties by UV-vis, room temperature solution photoluminescence (PL) spectroscopy, and further obtained powders were characterized by XRD, TEM, and EDXS analyses. The synthetic temperature condition to obtain the best PL emission intensity for the ZnSe core was 300 ${^{\circ}C}$, and for the optimum shell capping, the temperature was 135 ${^{\circ}C}$. At this temperature, solution PL spectrum showed a narrow emission peak at 427 nm with a PL efficiency of 15%. In addition, the measured particle sizes for the ZnSe/ZnS nanocomposite via TEM were in the range of 5 to 12 nm. Furthermore, we have synthesized water-soluble ZnSe/ZnS nanoparticles by capping the ZnSe/ZnS hydrophobic surface with mercaptoacetate (MAA) molecules. For the obtained aqueous colloidal solution, the UV-vis spectrum showed an absorption peak at 250 nm, and the solution PL emission spectrum showed a peak at 425 nm, which is similar to that for hydrophobic quantum dot ZnSe/ZnS. However, the calculated PL efficiency was relatively low (0.1%) due to the luminescence quenching by water and MAA molecules. The capping ligand was also characterized by FT-IR spectroscopy, with the carbonyl stretching peak in the mercaptoacetate molecule appearing at 1575 $cm ^{-1}$. Finally, the particle sizes of the MAA capped ZnSe/ZnS were measured by TEM, showing a range of 12 to 17 nm.

Flavonoidal constituent in Korean Lactuca dentata Makino (한국산 씀바귀의 Flavonoid 성분에 관한 연구)

  • Chung, Kang-Hyun;Yoon, Kwang-Ro;Kim, Jun-Pyong
    • Journal of the Korean Society of Food Culture
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    • v.9 no.2
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    • pp.131-136
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    • 1994
  • The ethylacetate extract of Lactuca dentata Makino showed 6 flavonoidal components as detected by ferric chloride solution. The flavonoidal constituent of Lactuca dentata Makino was isolated and purified by the series of column chromatography. The chemical structure of one of the flavonoidal component named as compound E was identified by UV, IR and NMR spectrometry. The melting point range of compound E was $249.5^{\circ}C-251^{\circ}C$. The UV and IR spectra of purified compound E, and its genin were measured with the various shifting agents. The results of UV analysis showed the free state of hydroxy group at 3rd and 4th carbon and binding of sugar at the 7th carbon of compound. The sugar bound to the compound E was identified as glucose by TLC. The IR spectrum showed the presense of hydroxy group, conjugated carbonyl group and aromatic group. The analysis of NMR spectrum was done to the purified compound and its derivatives. The chemical shifts against hydrogen atom, hydroxy group, and the moiety of luteolin were observed in the NMR spectrum along with their position and number as well as type of sugar bound. The isolated and purified compound was identified as $luteolin-7-0-{\beta}-D-glucoside$.

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Physico-chemical Characteristics of the Inhibitory Substance on the Germination of Mung Bean (녹두 발아 조해물질(阻害物質)의 이화학적(理化學的) 성질(性質))

  • Kim, Kwang-Hyeon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.1
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    • pp.57-60
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    • 1985
  • The inhibitory substance on the growth of mung bean seedling was amorphous crystal that had a single spot on silica gel thin layer chromatography under ultra-violet irradiation in dark room. The Rf value was 0.85 in n-butanol-acetic acid-formic acid-water(15 : 12 : 3 : 10) system, and 0.92 in n-butanol-acetic acid-water(4 : 1 : 5) system, respectively. Biochemical reaction of the inhibitor was negative to $FeCl_3$, pyrimidine, ninhydrine, folin, fehling, Salkowski and Ehrlich reaction, but the inhibitor had a blue fluorescence from irradiation of ultra-violet rays and had maximum absorption at 252nm on UV spectrum. On IR spectrum, the Peaks of the inhibitor appeared at $3300{\sim}3500,\;2900{\sim}3000,\;1600{\sim}1700,\;and\;1400cm^{(-1)}$. The strain tested was identified to be similar Streptomyces iuteogriseus by morphorogical and physiological characteristics.

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Dyeing of Cotton Fabrics using Residual Parts of Cultivated Pteridium aquilinum (재배 고사리 부산물을 활용한 면직물의 염색)

  • Lee, Hyesun;Kang, Eunyoung
    • Textile Coloration and Finishing
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    • v.26 no.1
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    • pp.53-62
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    • 2014
  • This study examined the dyeability, color fastness and functionality of cotton fabrics dyed with residual parts of cultivated Pteridium aquilinum. UV-Vis absorption spectrum, TLC and FT-IR spectra analysis showed that colorants of Pteridium aquilinum are a mixture of pyrogallol tannin and catechol tannin. Optimum dyeing conditions was confirmed colorant concentration of 500% at $100^{\circ}C$ for 60 minutes. Color fastness followed to washing, rubbing, perspiration and light as 4-5, 5, 4-5(acidic), 3-4(alkaline) and 2, respectively. Deodorization rates of ammonia($NH_3$) and acetic acid ($CH_3COOH$) were analyzed 88.8% and 78.0%. UV protection rate was 94.2% of UV-A and 96.8% of UV-B. UV protection factor(UPF) was 27. Therefore residual parts of cultivated Pteridium aquilinum could be used for a new functional colorant.

The Trend of Foreign Sunscreen Products and Study of UV Protecting Effects (외국 자외선제품의 동향과 UV차단 효과 연구)

  • 우건희
    • Proceedings of the SCSK Conference
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    • 1992.09a
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    • pp.97-114
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    • 1992
  • In these days sun products are developed and produced by the cosmetic scientists in the world. Peoples need strongly to protect themselves from the hazardous UV rays dued to the destruction of ozone layer. Therfore, we, cosmetic scientists must have an effort to produce the more effective goods. In this article the market survey of sun-products as well as the currency of sunscreen agents was investigated. It was found that Benzophenone - 3 and Ocytyl methoxy cinnamate were widely used. The lotions, using Benzophenone - 3 as the chemical agents, and TiO$_2$and micro TiO$_2$ as the physical agents, were measured the UV-Spectrum in the Dilution and Application method. Photoprotective activity of chemical agents can usually be measured in solution state. However, that of the insoluble physical agents such as TiO$_2$is hardly measured in this state. Photoprotective ability of the insoluble physical agents was able to be measured by application of lotions to the surface of UV cells. It was found by this method that micro TiO$_2$showd stronger UV scattering effect than TiO$_2$in this method.

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Sterilization of Escherichia coli Based on Nd: YAG Resonator with a Pulsed Xenon Flashlamp

  • Kim, Hee-Je;Kim, Dong-Jo;Hong, Ji-Tae;Xu, Guo-Cheng;Lee, Dong-Gil
    • Journal of Electrical Engineering and Technology
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    • v.6 no.2
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    • pp.275-279
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    • 2011
  • Sterilization of Escherichia coli (E. coli) is examined using a unique pulsed ultra-violet (UV) elliptical reactor based on Nd:YAG laser resonator, UV radiation from a pulsed xenon flashlamp. The light from the discharge has a broadband emission spectrum extending from the UV to the infrared region with a rich UV contained. Sterilization method by using the UV light is fast, environment-friendly and it does not cause secondary pollution. A Nd:YAG laser resonator having elliptical shape has advantage of concentrating the radiation of the UV light at two foci as the quart sleeve filled with E. coli. The primary objective of this research is to determine the important parameters such as pulse per second (pps), the applied voltage for sterilizing E. coli by using an UV elliptical reactor. From the experiment result, the sterilization effect of UV elliptical reactor is better than that of UV cylindrical reactor, and it can be 99.9% of sterilization at 800V regardless of the pps within 10 minutes.