• Title/Summary/Keyword: UV-spectrophotometer

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The Synthesis of 9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt (9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt의 합성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.73-81
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    • 1996
  • In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium(inner salt) with triethyl orthobenzoate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that 9-phenyl-3,3'-bis(3-sulfopropyl)-4,5,4',5'-naphthothiazolo carbocyanine triethyl ammonium salt can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.

A Study on the Synthesis of Magenta Coupler for Color Photograph and Color Development (천연색 사진용 Magenta 발색제의 합성과 발색현상에 관한 연구)

  • Kim, Yeoung-Chan;Lee, Byung-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.92-97
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    • 2006
  • In this paper, magenta coupler was prepared by the reaction of 1-(2,4,6-Trichlorophenyl)-3-(5-amino-2-chloroanilino)-5-pyrazolone with 2,4-di-tert-pentyl-phenoxy butanoyl chloride in the presence of pyridine. The product was identified by using various analytical tools such as melting point, elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer and GC-mass spectrometer. The reaction of magenta coupler with CD-3 (color development agent) was shown magenta color.

Studies on the Synthesis of Yellow Coupler and Color Development (황색 발색제의 합성과 발색현상에 관한 연구)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.116-121
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    • 2012
  • In this paper, yellow coupler was prepared by the reaction of ${\alpha}$-pivaloyl- 2-chloro-5-aminoacetaniline hydrogen chloride with 1-hexadecane sulfonyl chloride in the presence of pyridine. The product was identified by using various analytical tools such as melting poin elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, mass spectrometer. The reaction of yellow coupler with CD-3(color development agent) was shown yellow color.

The Synthesis of Sensitizing Dye for Photographic Emulsion (사진유제용 증감색소의 합성)

  • Kim, Yeoung-Chan;Kang, Tai-Sung;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.5-11
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    • 1995
  • In the study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with ortho-ester in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^{1}H$-NMR spectrometer, TGA and DSC. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

The Synthesis of Green-Sensitizing Dye for Photographic Emulsion (사진유제용 Green-Sensitizing Dye의 합성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.2
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    • pp.57-64
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    • 1997
  • The symmetric naphthothiazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, green-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 502nm. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

Screening of Inhibitory Effect of Edible Mushrooms on Tyrosinase and Isolation of Active Component (한국산 식용버섯류의 Tyrosinase 활성 저해 검색 및 그 유효성분 분리)

  • 박영현;장성근
    • Journal of Food Hygiene and Safety
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    • v.12 no.3
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    • pp.195-199
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    • 1997
  • For the purpose of isolation and screening of tyrosinase inhibitory activity from edible mushrooms, Pleurotus ostreatus, Auricularia auricula-Judae, Umbilicaria esculenta, Agaricus bisporus, Flammuline velutipes, Lentinus edodes, Ganoderma lucidum, and Coriouls versicolor were examined by tracing inhibitory activities against tyrosinase, utilizing L-3,4-dihydroxyphenylalanine (L-DOPA) as a substrate. Among the eight edible mushrooms tested, Umbilicaria esculenta showed potent enzyme inhibitory activities above 7804% against tyrosinase in ethylacetate (EtOAc) extracts. Ganoderma lucidum and Agaricus bisporus showed inhibitory activities of 67.3% and 51.5% in water extracts. EtOAc extracts of Umbilicaria esculenta was fractionated from silicagel column chromatography and one fraction showed the most inhibitory activity of 60.9%. The three bands (Rf=0.38, 0.27, 0.19) were isolated from preparative TLC of the fraction for purification and identified as mixtures of orsellinate, methyl orsellinate, methyl lecanorate, and methyl gyrophorate by high pressure liquid chromatography (HPLC), ultravisible spectrophotometer (UV), mass spectrophotometer (Mass), nuclear magnetic resonance spectrometer (NMR).

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The Synthesis of Red-Sensitizing Dye for Color Photography (천연색 사진용 적감색소의 합성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.2
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    • pp.136-141
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    • 2001
  • Naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, red-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, Mass spectrometer, $^{1}H-NMR$ spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 573nm. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red0sensitizing dye for the spectral sensitization of photographic emulsion.

Synthesis of 9-Phenyl-5,5'-Diphenyl-3,3'-Bis(3-Sulfopropyl)-Benzoxazolo Carbocyanine Triethyl Ammonium Salt (9-Phenyl-5,5'-Diphenyl-3,3'-Bis(3-Sulfopropyl)-Benzoxazolo Carbocyanine Triethyl Ammonium Salt의 합성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.2
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    • pp.226-231
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    • 2008
  • In this study, benzoxazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization. Sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-benzoxazolium (inner salt) with triethyl orthobenzoate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 507 nm. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as sensitizing dye for the spectral sensitization of photographic emulsion and color cosmetics.

Synthesis of 9-Ethyl-3,3'-Bis(3-sulfopropyl)-4,5,4'5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt (9-Ethyl-3,3'-Bis(3-sulfopropyl)-4,5,4'5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt의 합성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.416-421
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    • 2014
  • Naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization. Sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium (inner salt) with triethyl orthopropionate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 578nm. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as sensitizing dye for the spectral sensitization of photographic emulsion and color cosmetics.

Study of the coloration factors of tinted lenses (착색렌즈의 색비율 정량화에 관한 연구)

  • Lim, Yong-Mu;Shim, Moon-Sik;Jung, Ju-Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.37-46
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    • 2001
  • In this study, We compared the properties of tinted and colored lenses with the standards m the ordinary optical properties, coloration, UV, IR and luminous transmittance, color acceptance for traffic signal, and chromaticity. The UV, lR and luminous transmittance was analysed in the range of 175 nm to 3000 nm by using a UV-Vis-IR spectrophotometer and was used in the synthesis of spectrum of various color lens. A experimental function was made from the slope obtained from the transmittance change as a function of coloration time. We could expect the ordinary optical properties and color acceptance for traffic signal of various color lenses with the requirements of US standard(ANSI Z-80.3).

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